Synthesis of Heterodinuclear Cobalt(III)/Silver(I) Complexes and Their Catalytic Exploration for Ring-Opening Copolymerization of Carbon Dioxide with Terminal Epoxides

The utilization of a hexadentate imidazole-based phenolate ligand for the preparation of heterobimetallic cobalt­(III)/silver­(I) complexes was reported. These newly synthesized Co/Ag complexes were shown to be efficient single-component catalysts for ring-opening copolymerization of CO2 with termin...

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Published inInorganic chemistry Vol. 64; no. 21; pp. 10341 - 10346
Main Authors Ye, Nian-Yi, Liu, Guan-Lin, Ko, Bao-Tsan
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 02.06.2025
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ISSN0020-1669
1520-510X
1520-510X
DOI10.1021/acs.inorgchem.4c05287

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Abstract The utilization of a hexadentate imidazole-based phenolate ligand for the preparation of heterobimetallic cobalt­(III)/silver­(I) complexes was reported. These newly synthesized Co/Ag complexes were shown to be efficient single-component catalysts for ring-opening copolymerization of CO2 with terminal epoxides, generating CO2-based polycarbonates with high product selectivity and excellent carbonate repeated units.
AbstractList The utilization of a hexadentate imidazole-based phenolate ligand for the preparation of heterobimetallic cobalt(III)/silver(I) complexes was reported. These newly synthesized Co/Ag complexes were shown to be efficient single-component catalysts for ring-opening copolymerization of CO with terminal epoxides, generating CO -based polycarbonates with high product selectivity and excellent carbonate repeated units.
The utilization of a hexadentate imidazole-based phenolate ligand for the preparation of heterobimetallic cobalt­(III)/silver­(I) complexes was reported. These newly synthesized Co/Ag complexes were shown to be efficient single-component catalysts for ring-opening copolymerization of CO2 with terminal epoxides, generating CO2-based polycarbonates with high product selectivity and excellent carbonate repeated units.
The utilization of a hexadentate imidazole-based phenolate ligand for the preparation of heterobimetallic cobalt(III)/silver(I) complexes was reported. These newly synthesized Co/Ag complexes were shown to be efficient single-component catalysts for ring-opening copolymerization of CO2 with terminal epoxides, generating CO2-based polycarbonates with high product selectivity and excellent carbonate repeated units.The utilization of a hexadentate imidazole-based phenolate ligand for the preparation of heterobimetallic cobalt(III)/silver(I) complexes was reported. These newly synthesized Co/Ag complexes were shown to be efficient single-component catalysts for ring-opening copolymerization of CO2 with terminal epoxides, generating CO2-based polycarbonates with high product selectivity and excellent carbonate repeated units.
Author Ye, Nian-Yi
Ko, Bao-Tsan
Liu, Guan-Lin
AuthorAffiliation Department of Chemistry
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Snippet The utilization of a hexadentate imidazole-based phenolate ligand for the preparation of heterobimetallic cobalt­(III)/silver­(I) complexes was reported. These...
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