Synthesis of Heterodinuclear Cobalt(III)/Silver(I) Complexes and Their Catalytic Exploration for Ring-Opening Copolymerization of Carbon Dioxide with Terminal Epoxides

The utilization of a hexadentate imidazole-based phenolate ligand for the preparation of heterobimetallic cobalt(III)/silver(I) complexes was reported. These newly synthesized Co/Ag complexes were shown to be efficient single-component catalysts for ring-opening copolymerization of CO2 with termin...

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Published in	Inorganic chemistry Vol. 64; no. 21; pp. 10341 - 10346
Main Authors	Ye, Nian-Yi, Liu, Guan-Lin, Ko, Bao-Tsan
Format	Journal Article
Language	English
Published	United States American Chemical Society 02.06.2025
Online Access	Get full text
ISSN	0020-1669 1520-510X 1520-510X
DOI	10.1021/acs.inorgchem.4c05287

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Summary:	The utilization of a hexadentate imidazole-based phenolate ligand for the preparation of heterobimetallic cobalt(III)/silver(I) complexes was reported. These newly synthesized Co/Ag complexes were shown to be efficient single-component catalysts for ring-opening copolymerization of CO2 with terminal epoxides, generating CO2-based polycarbonates with high product selectivity and excellent carbonate repeated units.
Bibliography:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	0020-1669 1520-510X 1520-510X
DOI:	10.1021/acs.inorgchem.4c05287