静水圧とシステイン添加によるアクリルアミドの生成抑制
100 MPa未満の静水圧がアクリルアミドの生成とメイラード反応に及ぼす効果を,pH 9.0の等モル濃度のアスパラギン–グルコース水溶液を用いて検討した.常圧,60または90 MPaの圧力下で70℃,72時間までの反応を行い,アクリルアミドの生成量,メラノイジンの生成量,反応後のpHを測定した.メラノイジンの生成との比較によって,アクリルアミドの生成は,圧力保持により相対的に抑制されることが明らかとなった.また,同試料にシステインを添加して90 MPaの圧力下で70℃,24時間反応させた場合,圧力保持の有無に関らず,アクリルアミド生成が著しく抑制された.上述の結果に基づいて,圧力保持とシステイ...
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          | Published in | Japan Journal of Food Engineering Vol. 22; no. 4; pp. 87 - 101 | 
|---|---|
| Main Authors | , , , , , | 
| Format | Journal Article | 
| Language | English | 
| Published | 
            一般社団法人 日本食品工学会
    
        15.12.2021
     | 
| Online Access | Get full text | 
| ISSN | 1345-7942 1884-5924  | 
| DOI | 10.11301/jsfe.21593 | 
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| Abstract | 100 MPa未満の静水圧がアクリルアミドの生成とメイラード反応に及ぼす効果を,pH 9.0の等モル濃度のアスパラギン–グルコース水溶液を用いて検討した.常圧,60または90 MPaの圧力下で70℃,72時間までの反応を行い,アクリルアミドの生成量,メラノイジンの生成量,反応後のpHを測定した.メラノイジンの生成との比較によって,アクリルアミドの生成は,圧力保持により相対的に抑制されることが明らかとなった.また,同試料にシステインを添加して90 MPaの圧力下で70℃,24時間反応させた場合,圧力保持の有無に関らず,アクリルアミド生成が著しく抑制された.上述の結果に基づいて,圧力保持とシステイン添加によるアクリルアミド生成抑制効果を,アクリルアミドを比較的多く含む黒糖(Non-centrifugal cane sugar,NCS)水溶液(pH 5.5)を用いて同様の加圧加熱反応により検証した.システイン添加は,NCS水溶液の含有するアクリルアミドを低減し,加熱反応に伴うアクリルアミド生成を抑制した.また,NCS水溶液の圧力保持はアクリルアミドの生成を促進したが,高濃度のシステイン共存下での圧力保持は,アクリルアミドの低減を促進した.これらの結果から,食品の加工で起こるアクリルアミド生成やメイラード反応は,静水圧やシステインの添加で制御できる可能性が示唆された. | 
    
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| AbstractList | 100MPa未満の静水圧がアクリルアミドの生成とメイラード反応に及ぼす効果を,pH9.0の等モル濃度のアスパラギン-グルコース水溶液を用いて検討した。常圧,60または90MPaの圧力下で70℃,72時間までの反応を行い,アクリルアミドの生成量,メラノイジンの生成量,反応後のpHを測定した。メラノイジンの生成との比較によって,アクリルアミドの生成は,圧力保持により相対的に抑制されることが明らかとなった。また,同試料にシステインを添加して90MPaの圧力下で70℃,24時間反応させた場合,圧力保持の有無に関らず,アクリルアミド生成が著しく抑制された。上述の結果に基づいて,圧力保持とシステイン添加によるアクリルアミド生成抑制効果を,アクリルアミドを比較的多く含む黒糖(Non-centrifugal cane sugar,NCS)水溶液(pH5.5)を用いて同様の加圧加熱反応により検証した。システイン添加は,NCS水溶液の含有するアクリルアミドを低減し,加熱反応に伴うアクリルアミド生成を抑制した。また,NCS水溶液の圧力保持はアクリルアミドの生成を促進したが,高濃度のシステイン共存下での圧力保持は,アクリルアミドの低減を促進した。これらの結果から,食品の加工で起こるアクリルアミド生成やメイラード反応は,静水圧やシステインの添加で制御できる可能性が示唆された。 100 MPa未満の静水圧がアクリルアミドの生成とメイラード反応に及ぼす効果を,pH 9.0の等モル濃度のアスパラギン–グルコース水溶液を用いて検討した.常圧,60または90 MPaの圧力下で70℃,72時間までの反応を行い,アクリルアミドの生成量,メラノイジンの生成量,反応後のpHを測定した.メラノイジンの生成との比較によって,アクリルアミドの生成は,圧力保持により相対的に抑制されることが明らかとなった.また,同試料にシステインを添加して90 MPaの圧力下で70℃,24時間反応させた場合,圧力保持の有無に関らず,アクリルアミド生成が著しく抑制された.上述の結果に基づいて,圧力保持とシステイン添加によるアクリルアミド生成抑制効果を,アクリルアミドを比較的多く含む黒糖(Non-centrifugal cane sugar,NCS)水溶液(pH 5.5)を用いて同様の加圧加熱反応により検証した.システイン添加は,NCS水溶液の含有するアクリルアミドを低減し,加熱反応に伴うアクリルアミド生成を抑制した.また,NCS水溶液の圧力保持はアクリルアミドの生成を促進したが,高濃度のシステイン共存下での圧力保持は,アクリルアミドの低減を促進した.これらの結果から,食品の加工で起こるアクリルアミド生成やメイラード反応は,静水圧やシステインの添加で制御できる可能性が示唆された.  | 
    
| Author | 小黒, 麻美 山﨑, 彬 五味川, 里子 小林, 篤 佐藤, 眞治 前川, 博史  | 
    
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| References_xml | – reference: 20) K. De Vleeschouwer, I. Van Der Plancken, A. Van Loey, M. E. Hendrickx; The effect of high pressure-high temperature processing conditions on acrylamide formation and other Maillard reaction compounds. J. Agric. Food Chem., 58, 11740-11748 (2010). – reference: 2) E. Tareke, P. Rydberg, P. Karlsson, S. Eriksson, M. Törnqvist; Analysis of acrylamide, a carcinogen formed in heated foodstuffs. J. Agric. Food Chem., 50, 4998-5006 (2002). – reference: 4) J. A. Rufián-Henares, F J. Morales; Functional properties of melanoidins: In vitro antioxidant, antimicrobial and antihypertensive activities. Food Res. Int., 40, 995–1002 (2007). – reference: 18) V. M. Hill, D.A. Ledward, J. M. Ames; Influence of high hydrostatic pressure and pH on the rate of Maillard browning in a glucose-lysine system. J. Agric. Food Chem., 44, 594-598 (1996). – reference: 3) T. Gomyo, M. Miura; “Melanoidin in Foods: Chemical and physiological aspects” (in Japanese). Journal of Japanese Society of Nutrition and Food Science, 36, 331-340 (1983). – reference: 12) A. Kobayashi, M. Kawamura, E. Ohara, M. Ogino, J. Hoshino; “Application of high-pressure treatment to sterilization of foods” (in Japanese). Rev. High Pressure Sci. Technol., 24, 48-51 (2014). – reference: 14) M. Ogino, T. Nishiumi; Control of the generation time of microorganisms by long-term application of hydrostatic pressure of 50 MPa or less. Food Sci. Technol. Res., 24, 289-298 (2018). – reference: 29) S. I. Martinez-Monteagudo, M. D. A. Saldaña; Chemical reaction in food systems at high hydrostatic pressure. Food Eng. Rev., 6, 150-127 (2014). – reference: 26) H. Nursten; “The Maillard Reaction: Chemistry, Biochemistry and Implications.” The Royal Society of Chemistry, Cambridge, UK, 2005, p. 2. – reference: 19) T. Tamaoka, N. Itoh, R. Hayashi; High pressure effect on Maillard reaction. Agric. Bio. Chem., 55, 2071-2074 (1991). – reference: 32) M. 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| Snippet | 100 MPa未満の静水圧がアクリルアミドの生成とメイラード反応に及ぼす効果を,pH 9.0の等モル濃度のアスパラギン–グルコース水溶液を用いて検討した.常圧,60または90... 100MPa未満の静水圧がアクリルアミドの生成とメイラード反応に及ぼす効果を,pH9.0の等モル濃度のアスパラギン-グルコース水溶液を用いて検討した。常圧,60または90MPaの...  | 
    
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| Title | 静水圧とシステイン添加によるアクリルアミドの生成抑制 | 
    
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