三亲性二嵌段共聚物共混体系的自组装行为

O631; 选用聚乙二醇(PEG)、聚苯乙烯(PS)和聚甲基丙烯酸八氟戊酯(POFPMA)分别作为亲水、亲油和亲氟段,通过原子转移自由基聚合(ATRP)和单电子转移自由基聚合(SET-LRP)分别制备PEG-PS和PEG-POFPMA共聚物,并构建三亲性二嵌段共聚物共混体系PEG-PS/PEG-POFPMA,同时探讨了嵌段聚合度和浓度对组装体形貌的影响.结果 表明:改变疏水段聚合度,可以得到球形、多孔球形、囊泡形、纺锤状和蠕虫状胶束等多种形貌的自组装体,形貌在低浓度时较易调控,相图可用于指导聚合前靶向预定的纳米组装体....

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Published in华东理工大学学报（自然科学版） Vol. 46; no. 2; pp. 197 - 207
Main Authors 刘静, 丁艳玲, 刘小云, 谭正, 庄启昕
Format Journal Article
LanguageChinese
Published 华东理工大学材料科学与工程学院,特种功能高分子材料及相关技术教育部重点实验室,上海200237 30.04.2020
Subjects
含氟共聚物
三亲
共混
自组装
Online AccessGet full text
ISSN1006-3080
DOI10.14135/j.cnki.1006-3080.20190220001

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Abstract O631; 选用聚乙二醇(PEG)、聚苯乙烯(PS)和聚甲基丙烯酸八氟戊酯(POFPMA)分别作为亲水、亲油和亲氟段,通过原子转移自由基聚合(ATRP)和单电子转移自由基聚合(SET-LRP)分别制备PEG-PS和PEG-POFPMA共聚物,并构建三亲性二嵌段共聚物共混体系PEG-PS/PEG-POFPMA,同时探讨了嵌段聚合度和浓度对组装体形貌的影响.结果 表明:改变疏水段聚合度,可以得到球形、多孔球形、囊泡形、纺锤状和蠕虫状胶束等多种形貌的自组装体,形貌在低浓度时较易调控,相图可用于指导聚合前靶向预定的纳米组装体.
AbstractList O631; 选用聚乙二醇(PEG)、聚苯乙烯(PS)和聚甲基丙烯酸八氟戊酯(POFPMA)分别作为亲水、亲油和亲氟段,通过原子转移自由基聚合(ATRP)和单电子转移自由基聚合(SET-LRP)分别制备PEG-PS和PEG-POFPMA共聚物,并构建三亲性二嵌段共聚物共混体系PEG-PS/PEG-POFPMA,同时探讨了嵌段聚合度和浓度对组装体形貌的影响.结果 表明:改变疏水段聚合度,可以得到球形、多孔球形、囊泡形、纺锤状和蠕虫状胶束等多种形貌的自组装体,形貌在低浓度时较易调控,相图可用于指导聚合前靶向预定的纳米组装体.
Author 刘静
丁艳玲
刘小云
谭正
庄启昕
AuthorAffiliation 华东理工大学材料科学与工程学院,特种功能高分子材料及相关技术教育部重点实验室,上海200237
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Author_FL ZHUANG Qixin
LIU Jing
LIU Xiaoyun
DING Yanling
TAN Zheng
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三亲
共混
自组装
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Snippet O631; 选用聚乙二醇(PEG)、聚苯乙烯(PS)和聚甲基丙烯酸八氟戊酯(POFPMA)分别作为亲水、亲油和亲氟段,通过原子转移自由基聚合(ATRP)和单电子转移自由基聚合(SET-LRP)分别制...
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Title 三亲性二嵌段共聚物共混体系的自组装行为
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