Zn-Feめっき層の組成および組織制御による改質に向けたスパッタリング成膜による検証
Improvement of the powdering resistance of galvannealed (GA) coatings is a key issue in automotive GA steel sheets. To make the relationship between powdering resistance and microstructure of GA layer, sputtering fabrication process was used to prepare Zn-Fe intermetallic films with various composit...
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| Published in | 鉄と鋼 Vol. 105; no. 7; pp. 724 - 732 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | Japanese |
| Published |
一般社団法人 日本鉄鋼協会
2019
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0021-1575 1883-2954 |
| DOI | 10.2355/tetsutohagane.TETSU-2018-164 |
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| Abstract | Improvement of the powdering resistance of galvannealed (GA) coatings is a key issue in automotive GA steel sheets. To make the relationship between powdering resistance and microstructure of GA layer, sputtering fabrication process was used to prepare Zn-Fe intermetallic films with various composition and microstructure in this study. Zn-Fe films with 1500 nm in thickness were deposited on an iron substrate by RF magnetron sputtering. Г+Г1 two-phase film (17.2~24.4 at.%Fe) was found to show a severe powdering by 3-point bending test, while Г1 (16.2 at.%Fe) or Г (34.3 at.%Fe) single-phase films showed much better powdering resistance. These results indicate that Г/Г1 interfaces boundaries have a low interfacial strength compared to that of Г/iron or Г1/iron interfaces. To improve the low powdering resistance of the Г+Г1 two-phase film, we investigated the effect of grain size refinement by B addition on the powdering resistance. It was found that the grain size refinement by B addition drastically improves the powdering resistance of Г+Г1 two-phase film. The decrease in the fracture toughness of Г+Г1 two-phase film by grain refinement was suggested to cause the improvement of its powdering resistance. |
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| AbstractList | Improvement of the powdering resistance of galvannealed (GA) coatings is a key issue in automotive GA steel sheets. To make the relationship between powdering resistance and microstructure of GA layer, sputtering fabrication process was used to prepare Zn-Fe intermetallic films with various composition and microstructure in this study. Zn-Fe films with 1500 nm in thickness were deposited on an iron substrate by RF magnetron sputtering. Г+Г1 two-phase film (17.2~24.4 at.%Fe) was found to show a severe powdering by 3-point bending test, while Г1 (16.2 at.%Fe) or Г (34.3 at.%Fe) single-phase films showed much better powdering resistance. These results indicate that Г/Г1 interfaces boundaries have a low interfacial strength compared to that of Г/iron or Г1/iron interfaces. To improve the low powdering resistance of the Г+Г1 two-phase film, we investigated the effect of grain size refinement by B addition on the powdering resistance. It was found that the grain size refinement by B addition drastically improves the powdering resistance of Г+Г1 two-phase film. The decrease in the fracture toughness of Г+Г1 two-phase film by grain refinement was suggested to cause the improvement of its powdering resistance. |
| Author | 須藤, 祐司 小池, 淳一 川崎, 浩平 内山, 愛文 安藤, 大輔 |
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| References | 4) J. Inoue, S. Miwa and T. Koseki: Tetsu-to-Hagané, 100(2014), 383 (in Japanese). 7) N. Okamoto, D. Kashioka, M. Inomoto, H. Inui, H. Takebayashi and S. Yamaguchi: Scr. Mater., 69(2013), 307. 16) M.M. Hamasha, K. Alzoubi, J.C. Switzer III, S. Lu, S.B. Desu and M. Poliks: Thins Solid Films, 519(2011), 7918. 2) J. Machida and T. Takasugi: Tetsu-to-Hagané, 93(2007), 33 (in Japanese). 11) T. Toki, M. Araki, Y. Adachi, T. Nakamori and M. Hori: Tetsu-to-Hagané, 89(2003), 46 (in Japanese). 18) M. Mori, T. Shibayanagi, M. Maeda and M. Naka: Scr. Mater., 44(2001), 2035. 3) Nippon Steel Corporation: Nippon Steel Monthly, 129(2003), 9. 15) A. Matsumuro, D. Morino, T. Suzuki, S. Kotake and K. Sato: J. Jpn. Soc. Precis. Eng., 69(2003), 1774 (in Japanese). 20) L. Yang, K. Zhang, M. Wen, Z. Hou, C. Gong, X. Liu, C. Hu, X. Cui and W. Zheng: Sci. Rep., 7(2017), 9353. 17) Y. Yoshinari and T. Takasugi: ISIJ Int., 43(2003), 454. 10) 早稲田嘉夫，松原英一郎:X線構造解析，内田老鶴圃，東京，(1998), 121. 6) M. Sakurai, L. Wei, Y. Tajiri and T. Kondo:Tetsu-to-Hagané, 77(1991), 979 (in Japanese). 5) C. Sudo, T. Nakamori and M. Nishihara: Tetsu-to-Hagané, 66(1980), 73 (in Japanese). 13) N. Kyokuta, M. Koba, T. Araki, S. Nambu, J. Inoue and T. Koseki: J. Jpn. Inst. Met., 76(2012), 272 (in Japanese). 1) T. Masuda, L. Wang, T. Kobayashi and H. Umehara: Tetsu-to-Hagané, 91(2005), 313 (in Japanese). 12) A.T. Alpas and J. Inagaki: ISIJ Int., 40(2000), 172. 19) H. Shang, B. Ma, K. Shi, R. Li and G. Li: Mater. Lett., 192(2017), 104. 8) M.H. Hong and H. Saka: Scr. Mater., 36(1997), 1423. 14) J.S. Wang, Y. Sugiyama, A.G. Evans and W.K. Tredway: Thin Solid Films, 325(1998), 163. 9) T. Nakamura: CAMP-ISIJ, 28(2015), 342, CD-ROM (in Japanese). |
| References_xml | – reference: 17) Y. Yoshinari and T. Takasugi: ISIJ Int., 43(2003), 454. – reference: 3) Nippon Steel Corporation: Nippon Steel Monthly, 129(2003), 9. – reference: 15) A. Matsumuro, D. Morino, T. Suzuki, S. Kotake and K. Sato: J. Jpn. Soc. Precis. Eng., 69(2003), 1774 (in Japanese). – reference: 9) T. Nakamura: CAMP-ISIJ, 28(2015), 342, CD-ROM (in Japanese). – reference: 20) L. Yang, K. Zhang, M. Wen, Z. Hou, C. Gong, X. Liu, C. Hu, X. Cui and W. Zheng: Sci. Rep., 7(2017), 9353. – reference: 1) T. Masuda, L. Wang, T. Kobayashi and H. Umehara: Tetsu-to-Hagané, 91(2005), 313 (in Japanese). – reference: 7) N. Okamoto, D. Kashioka, M. Inomoto, H. Inui, H. Takebayashi and S. Yamaguchi: Scr. Mater., 69(2013), 307. – reference: 11) T. Toki, M. Araki, Y. Adachi, T. Nakamori and M. Hori: Tetsu-to-Hagané, 89(2003), 46 (in Japanese). – reference: 4) J. Inoue, S. Miwa and T. Koseki: Tetsu-to-Hagané, 100(2014), 383 (in Japanese). – reference: 5) C. Sudo, T. Nakamori and M. Nishihara: Tetsu-to-Hagané, 66(1980), 73 (in Japanese). – reference: 10) 早稲田嘉夫，松原英一郎:X線構造解析，内田老鶴圃，東京，(1998), 121. – reference: 8) M.H. Hong and H. Saka: Scr. Mater., 36(1997), 1423. – reference: 13) N. Kyokuta, M. Koba, T. Araki, S. Nambu, J. Inoue and T. Koseki: J. Jpn. Inst. Met., 76(2012), 272 (in Japanese). – reference: 12) A.T. Alpas and J. Inagaki: ISIJ Int., 40(2000), 172. – reference: 18) M. Mori, T. Shibayanagi, M. Maeda and M. Naka: Scr. Mater., 44(2001), 2035. – reference: 16) M.M. Hamasha, K. Alzoubi, J.C. Switzer III, S. Lu, S.B. Desu and M. Poliks: Thins Solid Films, 519(2011), 7918. – reference: 19) H. Shang, B. Ma, K. Shi, R. Li and G. Li: Mater. Lett., 192(2017), 104. – reference: 2) J. Machida and T. Takasugi: Tetsu-to-Hagané, 93(2007), 33 (in Japanese). – reference: 14) J.S. Wang, Y. Sugiyama, A.G. Evans and W.K. Tredway: Thin Solid Films, 325(1998), 163. – reference: 6) M. Sakurai, L. Wei, Y. Tajiri and T. Kondo:Tetsu-to-Hagané, 77(1991), 979 (in Japanese). |
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| Snippet | Improvement of the powdering resistance of galvannealed (GA) coatings is a key issue in automotive GA steel sheets. To make the relationship between powdering... |
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| SubjectTerms | galvannealed coating grain refinement powdering resistance Zn-Fe layer |
| Title | Zn-Feめっき層の組成および組織制御による改質に向けたスパッタリング成膜による検証 |
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