Photodissociation Dynamics of CF2I2 in CCl4 Solution Probed by Femtosecond Infrared Spectroscopy

Dynamics of photodissociation of CF2I2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately rebinds to form reactant or isomer that rapidly releases I2 molecule producing CF2, which bimolecularly reacts to produce C2F4.

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Bibliographic Details
Published inBulletin of the Korean Chemical Society Vol. 41; no. 10; pp. 966 - 968
Main Authors Park, Seongchul, Shin, Juhyang, Yoon, Hojeong, Lim, Manho
Format Journal Article
LanguageEnglish
Published Weinheim Wiley‐VCH Verlag GmbH & Co. KGaA 01.10.2020
대한화학회
Subjects
Geminate rebinding
isoHalomethane
Reaction in solution
Solvent cage
Solvent‐assisted reaction
Time‐resolved infrared spectroscopy
화학
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ISSN1229-5949
0253-2964
1229-5949
DOI10.1002/bkcs.12096

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Summary:Dynamics of photodissociation of CF2I2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately rebinds to form reactant or isomer that rapidly releases I2 molecule producing CF2, which bimolecularly reacts to produce C2F4.
Bibliography:https://onlinelibrary.wiley.com/doi/abs/10.1002/bkcs.12096
ISSN:1229-5949
0253-2964
1229-5949
DOI:10.1002/bkcs.12096