双性イオン部位を有するランダム共重合体の合成と電解質としての評価

Methacryloyl oligo(ethylene oxide) (MEO)とp-chloromethylstyrene (CMS)をラジカル重合法により共重合し[P(MEO-co-CMS)]，これをイミダゾール誘導体と反応させることで双性イオン部位を有するランダム共重合体[P(MEO-co-Zw)]を得た．P(MEO-co-CMS)の質量平均モル質量は200,000 g mol－1程度であり，P(MEO-co-Zw)はフィルム形成能を示した．P(MEO-co-Zw)/LiTFSA複合体は－70°Cと－10°C付近に二つのガラス転移温度を示した．P(MEO-co-Zw)/LiTFSA複合体...

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Published in高分子論文集 Vol. 72; no. 10; pp. 624 - 629
Main Authors 竹岡, 裕子, 藤田, 正博, 島田, 健佑, 陸川, 政弘
Format Journal Article
LanguageJapanese
Published 公益社団法人 高分子学会 2015
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ISSN0386-2186
1881-5685
DOI10.1295/koron.2015-0028

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Abstract Methacryloyl oligo(ethylene oxide) (MEO)とp-chloromethylstyrene (CMS)をラジカル重合法により共重合し[P(MEO-co-CMS)]，これをイミダゾール誘導体と反応させることで双性イオン部位を有するランダム共重合体[P(MEO-co-Zw)]を得た．P(MEO-co-CMS)の質量平均モル質量は200,000 g mol－1程度であり，P(MEO-co-Zw)はフィルム形成能を示した．P(MEO-co-Zw)/LiTFSA複合体は－70°Cと－10°C付近に二つのガラス転移温度を示した．P(MEO-co-Zw)/LiTFSA複合体のイオン伝導度およびリチウムイオン輸率は高塩濃度領域においても低下せず，従来のポリエーテル系電解質とは異なる傾向を示した．
AbstractList Methacryloyl oligo(ethylene oxide) (MEO)とp-chloromethylstyrene (CMS)をラジカル重合法により共重合し[P(MEO-co-CMS)]，これをイミダゾール誘導体と反応させることで双性イオン部位を有するランダム共重合体[P(MEO-co-Zw)]を得た．P(MEO-co-CMS)の質量平均モル質量は200,000 g mol－1程度であり，P(MEO-co-Zw)はフィルム形成能を示した．P(MEO-co-Zw)/LiTFSA複合体は－70°Cと－10°C付近に二つのガラス転移温度を示した．P(MEO-co-Zw)/LiTFSA複合体のイオン伝導度およびリチウムイオン輸率は高塩濃度領域においても低下せず，従来のポリエーテル系電解質とは異なる傾向を示した．
Author 竹岡, 裕子
藤田, 正博
島田, 健佑
陸川, 政弘
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Snippet Methacryloyl oligo(ethylene oxide) (MEO)とp-chloromethylstyrene (CMS)をラジカル重合法により共重合し[P(MEO-co-CMS)]，これをイミダゾール誘導体と反応させることで...
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Title 双性イオン部位を有するランダム共重合体の合成と電解質としての評価
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