放電加工によるTi3AlC2 セラミックスの機械的性質の変化に関する一考察

The effects of electrical discharge machining on the mechanical properties of MAX phase ceramics were investigated. Wire electrical discharge machining was performed on Ti3AlC2, a MAX phase ceramics, as a workpiece in deionized water or working oil. Mechanical properties were evaluated on the basis...

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Published in電気加工学会誌 Vol. 57; no. 146; p. 89
Main Authors 品田, 健陽, 南口, 誠, 金子, 健正, 郭, 妍伶, 山口, 直也
Format Journal Article
LanguageJapanese
Published 一般社団法人 電気加工学会 2023
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ISSN0387-754X
1881-0888
DOI10.2526/jseme.57.89

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Abstract The effects of electrical discharge machining on the mechanical properties of MAX phase ceramics were investigated. Wire electrical discharge machining was performed on Ti3AlC2, a MAX phase ceramics, as a workpiece in deionized water or working oil. Mechanical properties were evaluated on the basis of the Vickers hardness and 3-point bending strength of the electrical discharge machined surface. The Vickers hardness and bending strength were increased by electrical discharge machining in both working fluids. The cross-sectional observation of the machined surface by SEM showed that cracks were generated from the machined surface to the base material. In addition, the formation of a recast layer with a thickness of a few micro meters was observed on the machined surface. The elemental analysis of the machined surface by EDS revealed the presence of oxygen in deionized water machining. Furthermore, the ratio of Ti to Al changed in both working fluids. The component identification of the recast layer by XRD revealed peaks of Al2O3 and TiC, which have higher mechanical properties than the base material.
AbstractList The effects of electrical discharge machining on the mechanical properties of MAX phase ceramics were investigated. Wire electrical discharge machining was performed on Ti3AlC2, a MAX phase ceramics, as a workpiece in deionized water or working oil. Mechanical properties were evaluated on the basis of the Vickers hardness and 3-point bending strength of the electrical discharge machined surface. The Vickers hardness and bending strength were increased by electrical discharge machining in both working fluids. The cross-sectional observation of the machined surface by SEM showed that cracks were generated from the machined surface to the base material. In addition, the formation of a recast layer with a thickness of a few micro meters was observed on the machined surface. The elemental analysis of the machined surface by EDS revealed the presence of oxygen in deionized water machining. Furthermore, the ratio of Ti to Al changed in both working fluids. The component identification of the recast layer by XRD revealed peaks of Al2O3 and TiC, which have higher mechanical properties than the base material.
Author 郭, 妍伶
山口, 直也
南口, 誠
金子, 健正
品田, 健陽
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References 3) M. Radovic and M. W. Barsoum : MAX Phases : Bridging the Gap Between Metals and Ceramics, American Ceramics Society, Vol. 92, No. 3 (2013) pp. 20-27.
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References_xml – reference: 11) James F. Shackelford, William Alexander : CRC Materials Science and Engineering Handbook, , Third Edition, CRC Press, (2000) p. 471.
– reference: 2) M. W. Barsooum : The MN+1AXN phases : A New Class of Solids : Thermodynamically Stable Nanolaminates, Progress in Solid State Chemistry, Vol. 28 (2000) pp. 201-281.
– reference: 10) S. Li, G. Song, K. Kwakernaak, S. Zwaag and W. G. Sloof : Multiple Crack healing of a Ti2AlC Ceramic, Journal of the European Ceramic Society, Vol. 32, Issue 8 (2012) pp. 1813-1820.
– reference: 5) Z. Zhao, X. Li, X. Zeng, X. Zhang, Q. Yan : Preparation of Ti3AlC2 Bulk Ceramic via Aqueous Gelcasting Followed by Al-rich Pressureless Sintering, Journal of the European Ceramic Society, Vol. 40, Issue 8 (2020) pp. 2878-2886.
– reference: 6) J.M. Guo, Z.F. Dai, G.Y. Liu, J. Liu, K.X. Chen, H.P. Zhou : Study on Sintering of SHS Ti3AlC2 Powders by Hot Pressing, Rare Metal Materials and Engineering, Vol. 36 (2007) pp. 124-127.
– reference: 4) H. B. Zhang, Y. W. Bao, Y. C. Zhou : Current Status in Layered Ternary Carbide, Journal of Materials Science & Technology, Vol. 25 (2009) pp. 1-38.
– reference: 9) J. G. Julian : Processing of MAX Phases : From Synthesis to Applications : Journal of American Ceramic Society, Vol. 104 (2021) pp.659-690.
– reference: 3) M. Radovic and M. W. Barsoum : MAX Phases : Bridging the Gap Between Metals and Ceramics, American Ceramics Society, Vol. 92, No. 3 (2013) pp. 20-27.
– reference: 1) Z. M. Sun : Progress in research and development on MAX phases : a family of layered ternary compounds, International Materials Reviews, Vol. 56 (2011) pp. 143-166.
– reference: 7) X. Xie, X. Li, Q. Jia, C. Bai, J. Malzbender, Y. Cui, R. Yang : Mechanical Properties and Toughening Mechanisms of Highly Textured Ti3AlC2 Composite Material, Journal of the European Ceramic Society, Vol. 42, Issue 13 (2022) pp. 5493-5504.
– reference: 8) W. Zhou, B. Mei, J. Zhu : Fabrication of high-purity ternary carbide Ti3AlC2 by spark plasma sintering (SPS) technique, Ceramics International, Vol. 33, Issue 7 (2007) pp. 1399-1402.
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SubjectTerms bending strength
EDM
MAX phase ceramics
Ti3AlC2
Vickers hardness
Title 放電加工によるTi3AlC2 セラミックスの機械的性質の変化に関する一考察
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