50 μLから測定可能なpH電極用応答ガラスの作製
In the present work, pH response glasses with excellent chemical durability and small resistance were fabricated, the when lithium concentration in a glass membrane increased, and rare earth metal (Sc, Y and La) oxides were added in the glass. We tried to construct a pH electrode with fabricated pH...
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| Published in | Bunseki kagaku Vol. 68; no. 2; pp. 103 - 108 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | Japanese |
| Published |
Tokyo
公益社団法人 日本分析化学会
05.02.2019
Japan Science and Technology Agency |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0525-1931 |
| DOI | 10.2116/bunsekikagaku.68.103 |
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| Abstract | In the present work, pH response glasses with excellent chemical durability and small resistance were fabricated, the when lithium concentration in a glass membrane increased, and rare earth metal (Sc, Y and La) oxides were added in the glass. We tried to construct a pH electrode with fabricated pH response glasses, and to evaluate it for the sensitivity, linearity, alkali error and response of tap water. Next, we prepared pH electrode capable of measuring a micro volume (50 μL) by using the optimum pH response glasses. The performance results of the developed pH electrode for a micro volume that satisfied the standard JIS. The developed pH electrode may become commercially available. |
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| AbstractList | In the present work, pH response glasses with excellent chemical durability and small resistance were fabricated, the when lithium concentration in a glass membrane increased, and rare earth metal (Sc, Y and La) oxides were added in the glass. We tried to construct a pH electrode with fabricated pH response glasses, and to evaluate it for the sensitivity, linearity, alkali error and response of tap water. Next, we prepared pH electrode capable of measuring a micro volume (50 μL) by using the optimum pH response glasses. The performance results of the developed pH electrode for a micro volume that satisfied the standard JIS. The developed pH electrode may become commercially available. |
| Author | 西尾, 友志 金子, 聡 古川, 真衣 勝又, 英之 立石, 一希 |
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| Copyright | 2019 The Japan Society for Analytical Chemistry Copyright Japan Science and Technology Agency 2019 |
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| References | 10) 玉手徳太郎 : 横河技報，8, 18 (1979). 11) British Standard, 60746–1 (2003). 7) 西尾友志，岩本恵和，勝又英之，鈴木 透，金子 聡 : 分析化学 (Bunseki Kagaku), 64, 519 (2015). 6) 西尾友志，岩本恵和，勝又英之，鈴木 透，金子 聡 : 科学・技術研究，4, 47 (2015 3) F. Scholz : J. Solid State Electrochem., 15, 5 (2011). 8) 西尾友志，岩本恵和，古川真衣，勝又英之，鈴木 透，金子 聡 : 分析化学 (Bunseki Kagaku), 65, 267 (2016). 1) M. Cremer : Z. f. Biology, 47, 652 (1906 9) 西尾友志，古川真衣，立石一希，勝又英之，鈴木 透，金子 聡 : 科学・技術研究，7, 35 (2018). 12) 宮川雅恵 : 分析化学 (Bunseki Kagaku), 43, 57 (1994). 2) A. Belyustin : J. Solid. State. Electrochem., 15, 47 (2011 4) M. Yuqing, C. Jianrong, F. Keming : J. Biochem. Biophys. Methods, 63, 1 (2015). 5) Y. Nishio, Y. Iwamoto, M. Furukawa, H. Katsumata, T. Suzuki, S. Kaneco : Study Sci. Technol., 4, 183 (2015). |
| References_xml | – reference: 1) M. Cremer : Z. f. Biology, 47, 652 (1906) – reference: 4) M. Yuqing, C. Jianrong, F. Keming : J. Biochem. Biophys. Methods, 63, 1 (2015). – reference: 10) 玉手徳太郎 : 横河技報，8, 18 (1979). – reference: 9) 西尾友志，古川真衣，立石一希，勝又英之，鈴木 透，金子 聡 : 科学・技術研究，7, 35 (2018). – reference: 2) A. Belyustin : J. Solid. State. Electrochem., 15, 47 (2011) – reference: 6) 西尾友志，岩本恵和，勝又英之，鈴木 透，金子 聡 : 科学・技術研究，4, 47 (2015) – reference: 3) F. Scholz : J. Solid State Electrochem., 15, 5 (2011). – reference: 8) 西尾友志，岩本恵和，古川真衣，勝又英之，鈴木 透，金子 聡 : 分析化学 (Bunseki Kagaku), 65, 267 (2016). – reference: 5) Y. Nishio, Y. Iwamoto, M. Furukawa, H. Katsumata, T. Suzuki, S. Kaneco : Study Sci. Technol., 4, 183 (2015). – reference: 11) British Standard, 60746–1 (2003). – reference: 7) 西尾友志，岩本恵和，勝又英之，鈴木 透，金子 聡 : 分析化学 (Bunseki Kagaku), 64, 519 (2015). – reference: 12) 宮川雅恵 : 分析化学 (Bunseki Kagaku), 43, 57 (1994). |
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| SubjectTerms | Drinking water Electrodes Error detection Glass Linearity Lithium Organic chemistry pH Rare earth elements Sensitivity analysis Yttrium |
| Title | 50 μLから測定可能なpH電極用応答ガラスの作製 |
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