流通式装置を用いた超臨界二酸化炭素中のトリオレインの溶解度の測定と圧力, 温度, 密度条件との相関
超臨界二酸化炭素に対するトリオレインの溶解度を温度 (313, 323, 333 and 343K) および圧力 (15, 20 and 25MPa) の範囲で実測した. 溶解度測定には流通式抽出装置を用い, 圧力ならびに温度による溶解度の変化を求めるとともに既往の研究結果と比較検討を行った. 溶解度は圧力の上昇に伴って増大した. 圧力15MPaでは溶解度は温度 (343-313K) が低下するにしたがって約100倍上昇した. 一方, 25MPaの条件下では溶解度に対する温度の影響は少なくなった. 一定の圧力条件下では溶解度は温度上昇とともに低下した. また, Bender (1971) の提...
Saved in:
| Published in | 化学工学論文集 Vol. 26; no. 6; pp. 887 - 891 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | Japanese |
| Published |
公益社団法人 化学工学会
2000
|
| Online Access | Get full text |
| ISSN | 0386-216X 1349-9203 |
| DOI | 10.1252/kakoronbunshu.26.887 |
Cover
| Abstract | 超臨界二酸化炭素に対するトリオレインの溶解度を温度 (313, 323, 333 and 343K) および圧力 (15, 20 and 25MPa) の範囲で実測した. 溶解度測定には流通式抽出装置を用い, 圧力ならびに温度による溶解度の変化を求めるとともに既往の研究結果と比較検討を行った. 溶解度は圧力の上昇に伴って増大した. 圧力15MPaでは溶解度は温度 (343-313K) が低下するにしたがって約100倍上昇した. 一方, 25MPaの条件下では溶解度に対する温度の影響は少なくなった. 一定の圧力条件下では溶解度は温度上昇とともに低下した. また, Bender (1971) の提案にしたがって推算した超臨界二酸化炭素の推算密度と実測された溶解度は良好な相関を示した. |
|---|---|
| AbstractList | 超臨界二酸化炭素に対するトリオレインの溶解度を温度 (313, 323, 333 and 343K) および圧力 (15, 20 and 25MPa) の範囲で実測した. 溶解度測定には流通式抽出装置を用い, 圧力ならびに温度による溶解度の変化を求めるとともに既往の研究結果と比較検討を行った. 溶解度は圧力の上昇に伴って増大した. 圧力15MPaでは溶解度は温度 (343-313K) が低下するにしたがって約100倍上昇した. 一方, 25MPaの条件下では溶解度に対する温度の影響は少なくなった. 一定の圧力条件下では溶解度は温度上昇とともに低下した. また, Bender (1971) の提案にしたがって推算した超臨界二酸化炭素の推算密度と実測された溶解度は良好な相関を示した. |
| Author | 増田, 康 今井, 正直 陶, 慧 鈴木, 功 |
| Author_xml | – sequence: 1 fullname: 陶, 慧 organization: 日本大学生物資源科学部 食品科学工学科 – sequence: 1 fullname: 鈴木, 功 organization: 日本大学生物資源科学部 食品科学工学科 – sequence: 1 fullname: 増田, 康 organization: 日本大学生物資源科学部 食品科学工学科 – sequence: 1 fullname: 今井, 正直 organization: 日本大学生物資源科学部 食品科学工学科 |
| BookMark | eNpVUMtKw0AAXETBWv0DD36AqZvdZLN7FPEFFS8K3sKmSe1DW0n04M20VkULgmgPPvCJVtF6UEuo-jXbNO1fGFEELzPDzDCH6QPduXzOAmBQhjEZqWgky7N5O58z1nJOai2GSIxSrQtEZKwwiSGIu0EEYkokJJOFXjDgOGkDQqRQBTMaAXutN7ezcex_7LevS8FnTRQOgsOqcDeFe96ul9rb1eCo3GyUOyXPL1eCwlPwetH0noRbE8UdUXwQhQdRfBSFG1F8Cc1Wo96-u_Ybt9_ae_Rrx8Kt-qd3_u7J8FDLuw-T4SH_eSvk1tll870exmE1OPE6lat-0JPkS4418MtRMD8xPjc2JcVnJ6fHRuNSRqYQShSbSUZMYjFNoRhzggyiKphCE5nc5IglODU1lXPDgAmZGUmmUahhbKk8iTTDwlEw87ObcVb5oqWv2Ollbq_r3F5NJ5Ys_d-jMtNUHRGd_EB47l8vkeK2nuH4C6XSqrw |
| ContentType | Journal Article |
| Copyright | 社）化学工学会 |
| Copyright_xml | – notice: 社）化学工学会 |
| DOI | 10.1252/kakoronbunshu.26.887 |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1349-9203 |
| EndPage | 891 |
| ExternalDocumentID | article_kakoronbunshu1975_26_6_26_6_887_article_char_ja |
| GroupedDBID | .LE 5GY ACGFO AENEX ALMA_UNASSIGNED_HOLDINGS CS3 EBS EJD HH5 JSF P2P RJT |
| ID | FETCH-LOGICAL-j1800-83df96d6e974833a62b654380d2dada29ca8d75aabb0c19bf9780733e5af27be3 |
| ISSN | 0386-216X |
| IngestDate | Wed Sep 03 06:30:16 EDT 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 6 |
| Language | Japanese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-j1800-83df96d6e974833a62b654380d2dada29ca8d75aabb0c19bf9780733e5af27be3 |
| OpenAccessLink | https://www.jstage.jst.go.jp/article/kakoronbunshu1975/26/6/26_6_887/_article/-char/ja |
| PageCount | 5 |
| ParticipantIDs | jstage_primary_article_kakoronbunshu1975_26_6_26_6_887_article_char_ja |
| PublicationCentury | 2000 |
| PublicationDate | 20000000 |
| PublicationDateYYYYMMDD | 2000-01-01 |
| PublicationDate_xml | – year: 2000 text: 20000000 |
| PublicationDecade | 2000 |
| PublicationTitle | 化学工学論文集 |
| PublicationTitleAlternate | 化学工学論文集 |
| PublicationYear | 2000 |
| Publisher | 公益社団法人 化学工学会 |
| Publisher_xml | – name: 公益社団法人 化学工学会 |
| References | Chrastil, J; “Solubility of Solids and Liquids in Supercritical Gases, ” J. Phys. Chem., 86, 3016-3021 (1982) Nilsson, W.B., E.J. Gauglitz Jr. and J.K. Hudson; “Solubility of Simple and Mixed Triacylglycerols in Supercritical CO2, ” JAOCS., 70, 749-754 (1993) Yoon, S.H., H. Nakaya, O. Ito, O. Miyawaki, K.H. Park and K. Nakamura; “Effects of Substrate Solubility in Interesterification with Triolein by Immobilized Lipase in Supercritical Carbon Dioxide, ”Biosci. Biotech. Biochem., 62, 170-172 (1998) Nakaya, H., O. Miyawaki and K. Nakamura; “Solubilities of Behenic Acid and Ethylbehenate in Supercritical Carbon Dioxide, ” Kagaku Kogaku Ronbunshu, 25, 237-239 (1999) Nilsson, W.B., E.J. Gauglitz Jr. and J.K. Hudson; “Solubilities of Methyl Oleate, Oleic Acid, Oleyl Glycerols, and Oleyl Glycerol Mixtures in Supercritical Carbon Dioxide, ” JAOCS., 68, 87-91 (1991) Bender, E.; “Equation of State Exactly Representing The Phase Behaviors of Pure Substances, ” Proc. 5th Symposium on Thermophysical Properties, Am. Soc. of Mech. Eng., 227-235, New York, USA (1970) Brunetti, L., A. Daghetta, E. Fedeli, I. Kikic and L. Zanderighi; “Deacidification of Olive Oils by Supercritical Carbon Dioxide, ” JAOCS., 66, 209-217 (1989) Ribeiro, M.A. and M.G. Bernardo-Gil; “Solubilities of Triolein in Supercritical CO2, ” J. Chem. Eng. Data, 40, 1188-1192 (1995) Johannsen, M. and G. Brunner; “Solubility of The Fat-Soluble Vitamins A, D, E, and K in Supercritical Carbon Dioxide, ” J. Chem. Eng. Data, 42, 106-111 (1997) Johannsen, M. and G. Brunner; “Solubility of The Xanthines Caffeine, Theophylline and Theobromine in Supercritical Carbon Dioxide, ” Fluid Phase Equilibria, 95, 215-226 (1994) Li, S, G.S., Varadarajan and S. Harland; “Solubility of Theobromine and Caffeine in Supercritical Carbon Dioxide: Correlation with Density-Based Models, ” Fluid Phase Equilibria, 68, 263-280 (1991) Sakaki, K.; “Solubility of β-Carotene in Dense Carbon Dioxide and Nitrous Oxide from 308 to 323 from 9.6 to 30MPa, ” J. Chem. Eng. Data, 37, 249-251 (1992) |
| References_xml | – reference: Li, S, G.S., Varadarajan and S. Harland; “Solubility of Theobromine and Caffeine in Supercritical Carbon Dioxide: Correlation with Density-Based Models, ” Fluid Phase Equilibria, 68, 263-280 (1991) – reference: Yoon, S.H., H. Nakaya, O. Ito, O. Miyawaki, K.H. Park and K. Nakamura; “Effects of Substrate Solubility in Interesterification with Triolein by Immobilized Lipase in Supercritical Carbon Dioxide, ”Biosci. Biotech. Biochem., 62, 170-172 (1998) – reference: Nakaya, H., O. Miyawaki and K. Nakamura; “Solubilities of Behenic Acid and Ethylbehenate in Supercritical Carbon Dioxide, ” Kagaku Kogaku Ronbunshu, 25, 237-239 (1999) – reference: Bender, E.; “Equation of State Exactly Representing The Phase Behaviors of Pure Substances, ” Proc. 5th Symposium on Thermophysical Properties, Am. Soc. of Mech. Eng., 227-235, New York, USA (1970) – reference: Chrastil, J; “Solubility of Solids and Liquids in Supercritical Gases, ” J. Phys. Chem., 86, 3016-3021 (1982) – reference: Nilsson, W.B., E.J. Gauglitz Jr. and J.K. Hudson; “Solubilities of Methyl Oleate, Oleic Acid, Oleyl Glycerols, and Oleyl Glycerol Mixtures in Supercritical Carbon Dioxide, ” JAOCS., 68, 87-91 (1991) – reference: Brunetti, L., A. Daghetta, E. Fedeli, I. Kikic and L. Zanderighi; “Deacidification of Olive Oils by Supercritical Carbon Dioxide, ” JAOCS., 66, 209-217 (1989) – reference: Johannsen, M. and G. Brunner; “Solubility of The Xanthines Caffeine, Theophylline and Theobromine in Supercritical Carbon Dioxide, ” Fluid Phase Equilibria, 95, 215-226 (1994) – reference: Ribeiro, M.A. and M.G. Bernardo-Gil; “Solubilities of Triolein in Supercritical CO2, ” J. Chem. Eng. Data, 40, 1188-1192 (1995) – reference: Johannsen, M. and G. Brunner; “Solubility of The Fat-Soluble Vitamins A, D, E, and K in Supercritical Carbon Dioxide, ” J. Chem. Eng. Data, 42, 106-111 (1997) – reference: Nilsson, W.B., E.J. Gauglitz Jr. and J.K. Hudson; “Solubility of Simple and Mixed Triacylglycerols in Supercritical CO2, ” JAOCS., 70, 749-754 (1993) – reference: Sakaki, K.; “Solubility of β-Carotene in Dense Carbon Dioxide and Nitrous Oxide from 308 to 323 from 9.6 to 30MPa, ” J. Chem. Eng. Data, 37, 249-251 (1992) |
| SSID | ssib002484398 ssj0035378 ssib020472865 ssib000961565 ssib031741082 |
| Score | 1.5462989 |
| Snippet | 超臨界二酸化炭素に対するトリオレインの溶解度を温度 (313, 323, 333 and 343K) および圧力 (15, 20 and 25MPa) の範囲で実測した. 溶解度測定には流通式抽出装置を用い,... |
| SourceID | jstage |
| SourceType | Publisher |
| StartPage | 887 |
| Title | 流通式装置を用いた超臨界二酸化炭素中のトリオレインの溶解度の測定と圧力, 温度, 密度条件との相関 |
| URI | https://www.jstage.jst.go.jp/article/kakoronbunshu1975/26/6/26_6_887/_article/-char/ja |
| Volume | 26 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| ispartofPNX | 化学工学論文集, 2000/11/10, Vol.26(6), pp.887-891 |
| journalDatabaseRights | – providerCode: PRVFSB databaseName: Free Full-Text Journals in Chemistry customDbUrl: eissn: 1349-9203 dateEnd: 20001231 omitProxy: true ssIdentifier: ssj0035378 issn: 0386-216X databaseCode: HH5 dateStart: 19750101 isFulltext: true titleUrlDefault: http://abc-chemistry.org/ providerName: ABC ChemistRy |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrR1Nb9MwNJrGBQ6IT_GtHfAJAqkdO_bR6VJNHDhtErcqbdLDkAZC24UT3RggmISEgAMD8bGJDcTGAZiqAb8m67r9C95z3C4VO4wJqUqd5_f93Po5ip8d5yL144Yn6p4r4zhwfUXrrkxY6kqZevU0YbgowbctrouRMf_aDX5jYHCx8NbS1GTtSv3urvtK9hNVgEFccZfsP0S2xxQA0Ib4whUiDNc9xZhEgoQckkESKfPKgiYRJ2GZyAqJJNGMSE6igITDREckgltKFEWI8omWBlIi0rcNZahCYagkkYHBAWQQUSaRT0JtGgoRQomy4FYJxAHOetjIAs6eQZYGYjhb6fCRtqG11cc2AFLuQnwLCVmBXKB00A3tCtA0tFQTLfpxpOHD8VbpbpdRVZWREHXWRIU4tLoEaoeXgQJ1hUhRkCCIAheWjFmh0aLHuCc8QK7oFYUu0bSY9hdcxdErOmcOdvACBFQJDY7AK7gfWYVE9h6eGoBC-VZ7iIMOir3gXwgAMiijdtYctLiygwZEMA4COw5Cr4uGDi5wM7YCaR54GARWKGrLuvb6fY-NvN5P3IjlJhgGEfkEGNowMsEIDQ-BMQbOuYhQX9qbo3wc40oXJjEmhUtL5rRKyDfySZb5ylXUY8VZOK-bYP9tilOqtAmZzc7ys93-mvgpx0LCN-ObWPejNjWBJ25QcaVH3FdS3f5gq33oJRXwKhVVkV-AstrFww2Q1XFYhR2gAeSzZvrvewhQ4qKvSKBfKKpJsR6r3OmHhN0vebJX5I5xlueLXU_ZDb5g0dXd7IFUeRwWjt2XTk0ePHrEOWwXsEM6V_qoMzAeH3MOFcqaHneebP5obt971f71dGthtvN7NZt-1nm-nDXvZ823W2uzWw-XOy_mNtbntmdb7bmXnemVzvd3G62VrLmazTzKZj5n05-zmS_Z9GI28w2Am-trW0sL7fWP2G59aa--yprL7ddL7cfzl4c2W5-g5_JQ--sD-N58837j5xp0A2pnvrX98sMJZ6wSjZZHXHvoiztegsWrK1nSUCIRqQp8yVgsaA23v0svoUmcxFTVY5kEPI5rNa9eUrUGllALGEt53KBBLWUnncGJWxPpKWcoYTTFAzR5rCAGvpApLB950vASzupS1E87ldyT1dt5ZZ_qPgfGmf_F6KxzMC_1gY94zzmDk3em0vOw6JmsXTBj7g8Mfy0Y |
| linkProvider | ABC ChemistRy |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E6%B5%81%E9%80%9A%E5%BC%8F%E8%A3%85%E7%BD%AE%E3%82%92%E7%94%A8%E3%81%84%E3%81%9F%E8%B6%85%E8%87%A8%E7%95%8C%E4%BA%8C%E9%85%B8%E5%8C%96%E7%82%AD%E7%B4%A0%E4%B8%AD%E3%81%AE%E3%83%88%E3%83%AA%E3%82%AA%E3%83%AC%E3%82%A4%E3%83%B3%E3%81%AE%E6%BA%B6%E8%A7%A3%E5%BA%A6%E3%81%AE%E6%B8%AC%E5%AE%9A%E3%81%A8%E5%9C%A7%E5%8A%9B%2C+%E6%B8%A9%E5%BA%A6%2C+%E5%AF%86%E5%BA%A6%E6%9D%A1%E4%BB%B6%E3%81%A8%E3%81%AE%E7%9B%B8%E9%96%A2&rft.jtitle=%E5%8C%96%E5%AD%A6%E5%B7%A5%E5%AD%A6%E8%AB%96%E6%96%87%E9%9B%86&rft.au=%E9%99%B6%2C+%E6%85%A7&rft.au=%E9%88%B4%E6%9C%A8%2C+%E5%8A%9F&rft.au=%E5%A2%97%E7%94%B0%2C+%E5%BA%B7&rft.au=%E4%BB%8A%E4%BA%95%2C+%E6%AD%A3%E7%9B%B4&rft.date=2000&rft.pub=%E5%85%AC%E7%9B%8A%E7%A4%BE%E5%9B%A3%E6%B3%95%E4%BA%BA+%E5%8C%96%E5%AD%A6%E5%B7%A5%E5%AD%A6%E4%BC%9A&rft.issn=0386-216X&rft.eissn=1349-9203&rft.volume=26&rft.issue=6&rft.spage=887&rft.epage=891&rft_id=info:doi/10.1252%2Fkakoronbunshu.26.887&rft.externalDocID=article_kakoronbunshu1975_26_6_26_6_887_article_char_ja |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0386-216X&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0386-216X&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0386-216X&client=summon |