La3B6O13(OH): The First Acentric High‐Pressure Borate Displaying Edge‐Sharing BO4 Tetrahedra

La3B6O13(OH) was obtained by a high‐pressure/high‐temperature experiment at 6 GPa and 1673 K. The compound crystallizes in the space group P21 (no. 4) with the lattice parameters a=4.785(2), b=12.880(4), c=7.433(3) Å, and β=90.36(10)°, and is built up of corner‐ as well as edge‐sharing BO4 tetrahedr...

Full description

Saved in:
Bibliographic Details
Published inChemistry : a European journal Vol. 26; no. 30; pp. 6851 - 6861
Main Authors Fuchs, Birgit, Heymann, Gunter, Wang, Xuefei, Tudi, Abudukadi, Bayarjargal, Lkhamsuren, Siegel, Renée, Schmutzler, Adrian, Senker, Jürgen, Joachim‐Mrosko, Bastian, Saxer, Andreas, Yang, Zhihua, Pan, Shilie, Huppertz, Hubert
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 26.05.2020
John Wiley and Sons Inc
Subjects
Online AccessGet full text
ISSN0947-6539
1521-3765
1521-3765
DOI10.1002/chem.201905419

Cover

Abstract La3B6O13(OH) was obtained by a high‐pressure/high‐temperature experiment at 6 GPa and 1673 K. The compound crystallizes in the space group P21 (no. 4) with the lattice parameters a=4.785(2), b=12.880(4), c=7.433(3) Å, and β=90.36(10)°, and is built up of corner‐ as well as edge‐sharing BO4 tetrahedra. It represents the first acentric high‐pressure borate containing these B2O6 entities. The compound develops borate layers of „sechser“‐rings with the La3+ cations positioned between the layers. Single‐crystal and powder X‐ray diffraction, vibrational and MAS NMR spectroscopy, second‐harmonic generation (SHG) and thermoanalytical measurements, as well as computational methods were used to affirm the proposed structure and the B2O6 entities. Sharing is caring: La3B6O13(OH) was obtained via a high‐pressure/high‐temperature route at 6 GPa and 1673 K. The compound represents the first acentric borate displaying the rare feature of edge‐sharing BO4 tetrahedra. SHG measurements reveals a significant signal; further characterizations were carried out by NMR and vibrational spectroscopy, thermoanalytical analysis, and computational methods.
AbstractList La3B6O13(OH) was obtained by a high‐pressure/high‐temperature experiment at 6 GPa and 1673 K. The compound crystallizes in the space group P21 (no. 4) with the lattice parameters a=4.785(2), b=12.880(4), c=7.433(3) Å, and β=90.36(10)°, and is built up of corner‐ as well as edge‐sharing BO4 tetrahedra. It represents the first acentric high‐pressure borate containing these B2O6 entities. The compound develops borate layers of „sechser“‐rings with the La3+ cations positioned between the layers. Single‐crystal and powder X‐ray diffraction, vibrational and MAS NMR spectroscopy, second‐harmonic generation (SHG) and thermoanalytical measurements, as well as computational methods were used to affirm the proposed structure and the B2O6 entities. Sharing is caring: La3B6O13(OH) was obtained via a high‐pressure/high‐temperature route at 6 GPa and 1673 K. The compound represents the first acentric borate displaying the rare feature of edge‐sharing BO4 tetrahedra. SHG measurements reveals a significant signal; further characterizations were carried out by NMR and vibrational spectroscopy, thermoanalytical analysis, and computational methods.
La3B6O13(OH) was obtained by a high‐pressure/high‐temperature experiment at 6 GPa and 1673 K. The compound crystallizes in the space group P21 (no. 4) with the lattice parameters a=4.785(2), b=12.880(4), c=7.433(3) Å, and β=90.36(10)°, and is built up of corner‐ as well as edge‐sharing BO4 tetrahedra. It represents the first acentric high‐pressure borate containing these B2O6 entities. The compound develops borate layers of „sechser“‐rings with the La3+ cations positioned between the layers. Single‐crystal and powder X‐ray diffraction, vibrational and MAS NMR spectroscopy, second‐harmonic generation (SHG) and thermoanalytical measurements, as well as computational methods were used to affirm the proposed structure and the B2O6 entities.
Author Heymann, Gunter
Senker, Jürgen
Joachim‐Mrosko, Bastian
Schmutzler, Adrian
Yang, Zhihua
Bayarjargal, Lkhamsuren
Huppertz, Hubert
Wang, Xuefei
Siegel, Renée
Saxer, Andreas
Fuchs, Birgit
Tudi, Abudukadi
Pan, Shilie
AuthorAffiliation 1 Institut für Allgemeine, Anorganische und Theoretische Chemie Universität Innsbruck Innrain 80–82 6020 Innsbruck Austria
5 Institut für Mineralogie und Petrographie Universität Innsbruck Innrain 52 6020 Innsbruck Austria
6 Institut für Konstruktion und Materialwissenschaften Universität Innsbruck Technikerstraße 13 6020 Innsbruck Austria
3 Institut für Geowissenschaften Goethe-Universität Frankfurt am Main Altenhöferallee 1 60438 Frankfurt am Main Germany
4 Inorganic Chemistry III and Northern Bavarian NMR Center University of Bayreuth Universitätsstraße 30 95447 Bayreuth Germany
2 CAS Key Laboratory of Functional Materials, and Devices for Special Environment Xinjiang Technical Institute of Physics & Chemistry, CAS Xinjiang Key Laboratory of Electronic Information Materials and Devices 40-1 South Beijing Road 830011 Urumqi P. R. China
AuthorAffiliation_xml – name: 3 Institut für Geowissenschaften Goethe-Universität Frankfurt am Main Altenhöferallee 1 60438 Frankfurt am Main Germany
– name: 1 Institut für Allgemeine, Anorganische und Theoretische Chemie Universität Innsbruck Innrain 80–82 6020 Innsbruck Austria
– name: 2 CAS Key Laboratory of Functional Materials, and Devices for Special Environment Xinjiang Technical Institute of Physics & Chemistry, CAS Xinjiang Key Laboratory of Electronic Information Materials and Devices 40-1 South Beijing Road 830011 Urumqi P. R. China
– name: 6 Institut für Konstruktion und Materialwissenschaften Universität Innsbruck Technikerstraße 13 6020 Innsbruck Austria
– name: 5 Institut für Mineralogie und Petrographie Universität Innsbruck Innrain 52 6020 Innsbruck Austria
– name: 4 Inorganic Chemistry III and Northern Bavarian NMR Center University of Bayreuth Universitätsstraße 30 95447 Bayreuth Germany
Author_xml – sequence: 1
  givenname: Birgit
  surname: Fuchs
  fullname: Fuchs, Birgit
  organization: Universität Innsbruck
– sequence: 2
  givenname: Gunter
  surname: Heymann
  fullname: Heymann, Gunter
  organization: Universität Innsbruck
– sequence: 3
  givenname: Xuefei
  surname: Wang
  fullname: Wang, Xuefei
  organization: Xinjiang Key Laboratory of Electronic Information Materials and Devices
– sequence: 4
  givenname: Abudukadi
  surname: Tudi
  fullname: Tudi, Abudukadi
  organization: Xinjiang Key Laboratory of Electronic Information Materials and Devices
– sequence: 5
  givenname: Lkhamsuren
  surname: Bayarjargal
  fullname: Bayarjargal, Lkhamsuren
  organization: Goethe-Universität Frankfurt am Main
– sequence: 6
  givenname: Renée
  orcidid: 0000-0003-1412-5237
  surname: Siegel
  fullname: Siegel, Renée
  organization: University of Bayreuth
– sequence: 7
  givenname: Adrian
  surname: Schmutzler
  fullname: Schmutzler, Adrian
  organization: University of Bayreuth
– sequence: 8
  givenname: Jürgen
  orcidid: 0000-0002-7278-7952
  surname: Senker
  fullname: Senker, Jürgen
  organization: University of Bayreuth
– sequence: 9
  givenname: Bastian
  surname: Joachim‐Mrosko
  fullname: Joachim‐Mrosko, Bastian
  organization: Universität Innsbruck
– sequence: 10
  givenname: Andreas
  surname: Saxer
  fullname: Saxer, Andreas
  organization: Universität Innsbruck
– sequence: 11
  givenname: Zhihua
  surname: Yang
  fullname: Yang, Zhihua
  organization: Xinjiang Key Laboratory of Electronic Information Materials and Devices
– sequence: 12
  givenname: Shilie
  surname: Pan
  fullname: Pan, Shilie
  organization: Xinjiang Key Laboratory of Electronic Information Materials and Devices
– sequence: 13
  givenname: Hubert
  orcidid: 0000-0002-2098-6087
  surname: Huppertz
  fullname: Huppertz, Hubert
  email: hubert.huppertz@uibk.ac.at
  organization: Universität Innsbruck
BookMark eNqFUMFu00AQXaEimhaunC1xKQenO157N8uhUhISghQUJMJ5Gduz9laOna5tqtz4hH5jvwSHVFScmMtoNO-9efMu2Fnd1MTYW-Bj4Dy6zkrajSMOmicx6BdsBEkEoVAyOWMjrmMVykToc3bRtreccy2FeMXOBeg4jiM5Yj_WKGZyA-Jqs3r_IdiWFCydb7tgmlHdeZcFK1eUj78evnpq295TMGs8dhR8dO2-woOri2CRFzQgvpXoj-NsEwdb6jyWlHt8zV5arFp689Qv2fflYjtfhevNp8_z6ToshEx0CAhkrbQxn0wylUEOPMUIBEJmUyFVJmxmIZqkueZpomWU5IQWh1KW0gmIS3Z90u3rPR7usarM3rsd-oMBbo5ZmWNW5m9WA-PmxNj36Y7yP__iM6tBZ_7d1K40RfPTKAFKKTEIvHsS8M1dT21nbpve18OXJoq51MONhA8ofULdu4oO_zFl5qvFl2eLvwHbj5KG
ContentType Journal Article
Copyright 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
2020. This article is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
Copyright_xml – notice: 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
– notice: 2020. This article is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
DBID 24P
7SR
8BQ
8FD
JG9
K9.
5PM
ADTOC
UNPAY
DOI 10.1002/chem.201905419
DatabaseName Wiley Online Library Journals (Open Access)
Engineered Materials Abstracts
METADEX
Technology Research Database
Materials Research Database
ProQuest Health & Medical Complete (Alumni)
PubMed Central (Full Participant titles)
Unpaywall for CDI: Periodical Content
Unpaywall
DatabaseTitle Materials Research Database
ProQuest Health & Medical Complete (Alumni)
Engineered Materials Abstracts
Technology Research Database
METADEX
DatabaseTitleList

Materials Research Database
Database_xml – sequence: 1
  dbid: 24P
  name: Wiley Online Library Open Access
  url: https://authorservices.wiley.com/open-science/open-access/browse-journals.html
  sourceTypes: Publisher
– sequence: 2
  dbid: UNPAY
  name: Unpaywall
  url: https://proxy.k.utb.cz/login?url=https://unpaywall.org/
  sourceTypes: Open Access Repository
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1521-3765
EndPage 6861
ExternalDocumentID 10.1002/chem.201905419
PMC7317773
CHEM201905419
Genre article
GroupedDBID ---
-DZ
-~X
.3N
.GA
05W
0R~
10A
1L6
1OB
1OC
1ZS
24P
29B
33P
3SF
3WU
4.4
4ZD
50Y
50Z
51W
51X
52M
52N
52O
52P
52S
52T
52U
52W
52X
53G
5GY
5VS
66C
6J9
702
77Q
7PT
8-0
8-1
8-3
8-4
8-5
8UM
930
A03
AAESR
AAEVG
AAHQN
AAMNL
AANLZ
AAONW
AASGY
AAXRX
AAYCA
AAZKR
ABCQN
ABCUV
ABDBF
ABIJN
ABJNI
ABLJU
ABPVW
ACAHQ
ACCZN
ACGFS
ACIWK
ACNCT
ACPOU
ACUHS
ACXBN
ACXQS
ADBBV
ADEOM
ADIZJ
ADKYN
ADMGS
ADOZA
ADXAS
ADZMN
AEGXH
AEIGN
AEIMD
AEUYR
AEYWJ
AFBPY
AFFPM
AFGKR
AFRAH
AFWVQ
AFZJQ
AGHNM
AGYGG
AHBTC
AHMBA
AITYG
AIURR
AJXKR
ALAGY
ALMA_UNASSIGNED_HOLDINGS
ALVPJ
AMBMR
AMYDB
ATUGU
AUFTA
AZBYB
AZVAB
BAFTC
BDRZF
BFHJK
BHBCM
BMNLL
BMXJE
BNHUX
BROTX
BRXPI
BY8
CS3
D-E
D-F
DCZOG
DPXWK
DR2
DRFUL
DRSTM
EBD
EBS
F00
F01
F04
F5P
G-S
G.N
GNP
GODZA
H.T
H.X
HBH
HGLYW
HHY
HHZ
HZ~
IX1
J0M
JPC
KQQ
LATKE
LAW
LC2
LC3
LEEKS
LH4
LITHE
LOXES
LP6
LP7
LUTES
LYRES
MEWTI
MK4
MRFUL
MRSTM
MSFUL
MSSTM
MXFUL
MXSTM
N04
N05
N9A
NF~
NNB
O66
O9-
OIG
P2W
P2X
P4D
PQQKQ
Q.N
Q11
QB0
QRW
R.K
RNS
ROL
RX1
RYL
SUPJJ
TN5
TWZ
UB1
UPT
V2E
V8K
W8V
W99
WBFHL
WBKPD
WH7
WIB
WIH
WIK
WJL
WOHZO
WQJ
WXSBR
WYISQ
XG1
XPP
XV2
YZZ
ZZTAW
~IA
~WT
7SR
8BQ
8FD
JG9
K9.
5PM
.GJ
.Y3
186
31~
6TJ
9M8
AANHP
ABEML
ACBWZ
ACRPL
ACSCC
ACYXJ
ADNMO
ADTOC
AETEA
AGCDD
AGQPQ
AI.
ASPBG
AVWKF
AZFZN
BZBRT
EJD
FEDTE
HF~
HVGLF
H~9
LW6
MVM
PALCI
RIWAO
RJQFR
SAMSI
UNPAY
UQL
VH1
Y6R
ZGI
ID FETCH-LOGICAL-g3659-1a1eff6f4088c7c1d10ba213a1cfb367c3fcf128bd90b59625deafaaaa7feb813
IEDL.DBID DR2
ISSN 0947-6539
1521-3765
IngestDate Wed Oct 01 15:58:23 EDT 2025
Tue Sep 30 16:35:21 EDT 2025
Fri Jul 25 11:51:37 EDT 2025
Sun Jul 06 04:45:08 EDT 2025
IsDoiOpenAccess true
IsOpenAccess true
IsPeerReviewed true
IsScholarly true
Issue 30
Language English
License Attribution-NonCommercial-NoDerivs
This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-g3659-1a1eff6f4088c7c1d10ba213a1cfb367c3fcf128bd90b59625deafaaaa7feb813
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ORCID 0000-0003-1412-5237
0000-0002-2098-6087
0000-0002-7278-7952
OpenAccessLink https://proxy.k.utb.cz/login?url=https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201905419
PMID 31944426
PQID 2406919350
PQPubID 986340
PageCount 11
ParticipantIDs unpaywall_primary_10_1002_chem_201905419
pubmedcentral_primary_oai_pubmedcentral_nih_gov_7317773
proquest_journals_2406919350
wiley_primary_10_1002_chem_201905419_CHEM201905419
PublicationCentury 2000
PublicationDate May 26, 2020
PublicationDateYYYYMMDD 2020-05-26
PublicationDate_xml – month: 05
  year: 2020
  text: May 26, 2020
  day: 26
PublicationDecade 2020
PublicationPlace Weinheim
PublicationPlace_xml – name: Weinheim
– name: Hoboken
PublicationSubtitle A European Journal
PublicationTitle Chemistry : a European journal
PublicationYear 2020
Publisher Wiley Subscription Services, Inc
John Wiley and Sons Inc
Publisher_xml – name: Wiley Subscription Services, Inc
– name: John Wiley and Sons Inc
References 1995; 30
1985; 28
1970; 6
1993; 62
1989; 156
2015; 71
2019; 55
2019; 58
1973; 19
2010; 183
2016; 71
2015; 106
2005; 61
2014; 20
1996; 77
2017; 72
2010; 66
1990; 41
2010; 65
2009; 95
1991; 47
2005; 220
1960; 45
2013; 116
2010; 114
1995; 67
2003; 9
2019; 25
1993; 74
1954; 276
2008; 64
2004; 219
1966; 22
2006; 128
1970; 24
1995; 52
1990; 75
1982; 38
2009; 65
2009; 64
1960; 15
2011
1991; 76
1989; 6
2006; 8
2010 2010; 49 122
1953; 8
1985; 41
1977; 89
2017 2017; 56 129
2002
2001; 63
1970; 13
1998; 37
2017; 53
1987; 20
1976; 13
2004; 630
1968; 39
1983; 162
2002; 124
1997; 36
2007 2007; 46 119
1992; 28
2012; 45
References_xml – volume: 74
  start-page: 7014
  year: 1993
  end-page: 7015
  publication-title: J. Appl. Phys.
– volume: 53
  start-page: 2818
  year: 2017
  end-page: 2821
  publication-title: Chem. Commun.
– volume: 13
  start-page: 5188
  year: 1976
  end-page: 5192
  publication-title: Phys. Rev. B
– volume: 66
  year: 2010
  publication-title: Acta Crystallogr. Sect. E
– volume: 28
  start-page: 235
  year: 1985
  end-page: 243
  publication-title: Sci. Sin. Ser. B (Engl. Ed.)
– volume: 62
  start-page: 2614
  year: 1993
  end-page: 2615
  publication-title: Appl. Phys. Lett.
– volume: 30
  start-page: 209
  year: 1995
  end-page: 215
  publication-title: Mater. Res. Bull.
– volume: 95
  year: 2009
  publication-title: Appl. Phys. Lett.
– volume: 65
  start-page: 148
  year: 2009
  end-page: 155
  publication-title: Acta Crystallogr. Sect. D
– volume: 41
  start-page: 1227
  year: 1990
  end-page: 1230
  publication-title: Phys. Rev. B
– volume: 63
  year: 2001
  publication-title: Phys. Rev. B
– volume: 61
  start-page: i29
  year: 2005
  end-page: i31
  publication-title: Acta Crystallogr. Sect. C
– volume: 55
  start-page: 12737
  year: 2019
  end-page: 12748
  publication-title: Chem. Commun.
– volume: 219
  start-page: 330
  year: 2004
  end-page: 338
  publication-title: Z. Kristallogr.
– volume: 72
  start-page: 977
  year: 2017
  end-page: 982
  publication-title: Z. Naturforsch. Sect. B
– start-page: 4147
  year: 2011
  end-page: 4152
  publication-title: Eur. J. Inorg. Chem.
– volume: 71
  start-page: 3
  year: 2015
  end-page: 8
  publication-title: Acta Crystallogr. Sect. C
– start-page: 165
  year: 2002
  end-page: 196
– volume: 276
  start-page: 95
  year: 1954
  end-page: 112
  publication-title: Z. Anorg. Allg. Chem.
– volume: 220
  start-page: 567
  year: 2005
  end-page: 570
  publication-title: Z. Kristallogr.
– volume: 45
  start-page: 849
  year: 2012
  end-page: 854
  publication-title: J. Appl. Crystallogr.
– volume: 36
  start-page: L276
  year: 1997
  end-page: L279
  publication-title: Jpn. J. Appl. Phys.
– volume: 24
  start-page: 647
  year: 1970
  end-page: 656
  publication-title: Math. Comp.
– volume: 183
  start-page: 1970
  year: 2010
  end-page: 1979
  publication-title: J. Solid State Chem.
– volume: 64
  start-page: 112
  year: 2008
  end-page: 122
  publication-title: Acta Crystallogr. Sect. A
– volume: 38
  start-page: 1270
  year: 1982
  end-page: 1272
  publication-title: Acta Crystallogr. Sect. B
– volume: 19
  start-page: 111
  year: 1973
  end-page: 117
  publication-title: Phys. Status Solidi A
– volume: 75
  start-page: 1020
  year: 1990
  end-page: 1028
  publication-title: Am. Mineral.
– volume: 114
  start-page: 5119
  year: 2010
  end-page: 5131
  publication-title: J. Phys. Chem. A
– volume: 106
  year: 2015
  publication-title: Appl. Phys. Lett.
– volume: 128
  start-page: 14758
  year: 2006
  end-page: 14759
  publication-title: J. Am. Chem. Soc.
– volume: 56 129
  start-page: 3916 3974
  year: 2017 2017
  end-page: 3919 3977
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 65
  start-page: 1311
  year: 2010
  end-page: 1317
  publication-title: Z. Naturforsch. Sect. B
– volume: 89
  start-page: 327
  year: 1977
  end-page: 328
  publication-title: Angew. Chem.
– volume: 116
  start-page: 408
  year: 2013
  end-page: 417
  publication-title: Spectrochim. Acta Part A
– volume: 8
  start-page: 104
  year: 1953
  publication-title: Z. Naturforsch. B
– volume: 9
  start-page: 3623
  year: 2003
  end-page: 3633
  publication-title: Chem. Eur. J.
– volume: 52
  start-page: 14636
  year: 1995
  end-page: 14645
  publication-title: Phys. Rev. B
– volume: 49 122
  start-page: 4967 5087
  year: 2010 2010
  end-page: 4970 5090
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 13
  start-page: 317
  year: 1970
  end-page: 322
  publication-title: Comput. J.
– volume: 77
  start-page: 3865
  year: 1996
  end-page: 3868
  publication-title: Phys. Rev. Lett.
– volume: 25
  start-page: 11614
  year: 2019
  end-page: 11619
  publication-title: Chem. Eur. J.
– volume: 76
  start-page: 1092
  year: 1991
  end-page: 1100
  publication-title: Am. Mineral.
– volume: 156
  start-page: 105
  year: 1989
  end-page: 122
  publication-title: J. Less-Common Met.
– volume: 20
  start-page: 139
  year: 1987
  end-page: 143
  publication-title: J. Appl. Crystallogr.
– volume: 37
  start-page: 3208
  year: 1998
  end-page: 3218
  publication-title: Angew. Chem. Int. Ed.
– volume: 162
  start-page: 149
  year: 1983
  end-page: 150
  publication-title: Z. Kristallogr.
– volume: 71
  start-page: 535
  year: 2016
  end-page: 542
  publication-title: Z. Naturforsch. Sect. B
– volume: 6
  start-page: 76
  year: 1970
  end-page: 90
  publication-title: IMA J. Appl. Math.
– volume: 15
  start-page: 329
  year: 1960
  end-page: 337
  publication-title: J. Inorg. Nucl. Chem.
– volume: 45
  start-page: 334
  year: 1960
  end-page: 340
  publication-title: Am. Mineral.
– volume: 58
  start-page: 4085
  year: 2019
  end-page: 4088
  publication-title: Inorg. Chem.
– volume: 39
  start-page: 3798
  year: 1968
  end-page: 3813
  publication-title: J. Appl. Phys.
– volume: 24
  start-page: 23
  year: 1970
  end-page: 26
  publication-title: Math. Comp.
– volume: 6
  start-page: 616
  year: 1989
  end-page: 621
  publication-title: J. Opt. Soc. Am. B
– year: 2002
– volume: 22
  start-page: 1201
  year: 1966
  end-page: 1210
  publication-title: Spectrochim. Acta
– volume: 64
  start-page: 883
  year: 2009
  end-page: 890
  publication-title: Z. Naturforsch. Sect. B
– volume: 46 119
  start-page: 9097 9256
  year: 2007 2007
  end-page: 9100 9259
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 41
  start-page: 244
  year: 1985
  end-page: 247
  publication-title: Acta Crystallogr. Sect. B
– volume: 28
  start-page: 2057
  year: 1992
  end-page: 2074
  publication-title: IEEE J. Quantum Electron.
– volume: 128
  start-page: 7706
  year: 2006
  end-page: 7707
  publication-title: J. Am. Chem. Soc.
– volume: 630
  start-page: 2450
  year: 2004
  end-page: 2457
  publication-title: Z. Anorg. Allg. Chem.
– volume: 67
  start-page: 1818
  year: 1995
  end-page: 1820
  publication-title: Appl. Phys. Lett.
– volume: 55
  start-page: 1295
  year: 2019
  end-page: 1298
  publication-title: Chem. Commun.
– volume: 8
  start-page: 821
  year: 2006
  end-page: 829
  publication-title: Solid State Sci.
– volume: 128
  start-page: 6040
  year: 2006
  end-page: 6041
  publication-title: J. Am. Chem. Soc.
– volume: 124
  start-page: 9376
  year: 2002
  end-page: 9377
  publication-title: J. Am. Chem. Soc.
– volume: 47
  start-page: 192
  year: 1991
  end-page: 197
  publication-title: Acta Crystallogr. Sect. B
– volume: 20
  start-page: 17059
  year: 2014
  end-page: 17067
  publication-title: Chem. Eur. J.
SSID ssj0009633
Score 2.4279149
Snippet La3B6O13(OH) was obtained by a high‐pressure/high‐temperature experiment at 6 GPa and 1673 K. The compound crystallizes in the space group P21 (no. 4) with the...
SourceID unpaywall
pubmedcentral
proquest
wiley
SourceType Open Access Repository
Aggregation Database
Publisher
StartPage 6851
SubjectTerms Cations
Chemistry
Computer applications
Harmonic generations
high-pressure chemistry
lanthanum borate
Lattice parameters
Magnetic resonance spectroscopy
NMR
NMR spectroscopy
nonlinear optics
Nuclear magnetic resonance
Pressure
Tetrahedra
vibrational spectroscopy
SummonAdditionalLinks – databaseName: Unpaywall
  dbid: UNPAY
  link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9NAEB5V6aFcKE-RUtAeOJSDi9fr3Y25JW2jCKGGQyOVk9lnGxGZKE2E4MRP4Df2l3Rn_ZBSDiDh28rjlcYzs_PZO_MtwBsrtA1-4RLOnUtykdmkkCGuOJdqkPpC5TayfZ6LySz_cMkvd-C07YWp-SG6H24YGXG9xgBfWl-v883ufvYu6IXd5CGp8Ry5P3cFbjP1YHd2_mn4OdLs5TJB9tVIm5pRjCfecjf-McEWyrxfI7m3qZbqx3e1WGzj2JiIxvvgWhXq-pOvx5u1PjY_77E7_q-Oj-Bhg1TJsHatx7Djqiewd9IeEPcUvnxUbCSmlB1NJ2_fk-BwZDwPYJIMozZzQ7CI5PbX77oFceXICP3NkdP5zXKhsL-KnNkrFySQNhqHo2lOLlx4E9fOrtQzmI3PLk4mSXNgQ3LFBC8SqqjzXvg8LF1GGmppqlVGmaLGayakYd74kBC1LVKNx_5w65RX4ZLe6QFlz6FXfavcCyDee8qMUkwwkWsdMkrBAvQylg2C9zDbh8PWVGUTdTdlbONFwbQPcst85bLm7iiRTXv7TjW_jqzaMiApKVkfjjpDd0_V3M5ZibYoO1v0IYvG-4tYieQW3ejg3-d_CQ8y_LpPsQ7xEHrr1ca9ChBorV83Hn4HdJQE4g
  priority: 102
  providerName: Unpaywall
Title La3B6O13(OH): The First Acentric High‐Pressure Borate Displaying Edge‐Sharing BO4 Tetrahedra
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201905419
https://www.proquest.com/docview/2406919350
https://pubmed.ncbi.nlm.nih.gov/PMC7317773
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/chem.201905419
UnpaywallVersion publishedVersion
Volume 26
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
journalDatabaseRights – providerCode: PRVEBS
  databaseName: EBSCOhost Academic Search Ultimate
  customDbUrl: https://search.ebscohost.com/login.aspx?authtype=ip,shib&custid=s3936755&profile=ehost&defaultdb=asn
  eissn: 1521-3765
  dateEnd: 20241002
  omitProxy: true
  ssIdentifier: ssj0009633
  issn: 1521-3765
  databaseCode: ABDBF
  dateStart: 20120604
  isFulltext: true
  titleUrlDefault: https://search.ebscohost.com/direct.asp?db=asn
  providerName: EBSCOhost
– providerCode: PRVWIB
  databaseName: Wiley Online Library - Core collection (SURFmarket)
  issn: 1521-3765
  databaseCode: DR2
  dateStart: 19980101
  customDbUrl:
  isFulltext: true
  eissn: 1521-3765
  dateEnd: 99991231
  omitProxy: false
  ssIdentifier: ssj0009633
  providerName: Wiley-Blackwell
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LT9tAEB619EAv9EGrhkK0hx7gYPB6X3FvCSWKqoogRCQ4ufuEqJGJ8hBqT_0J_Y39JeyuE1NzqdT6tvKu5PV84_lsz3wD8MFwZTwubMKYtQnlmUly4f2KMSE7qcslNVHt85QPRvTzJbv8o4q_0oeoP7gFz4jP6-DgUs2PHkRD_Z5CJbkPaIxG3U9MWPxPe_6gH-XRVfWSpyIJGqxr1cY0O2oub_DLx9mRm8tyKr_fycmkyWBjCOq_ALm--Crz5NvhcqEO9Y9Huo7_s7uXsLXip6hbAeoVPLHla9g8XreF24avXyTp8SEm-8PBwUfkYYb6Y08hUTfuZKxRSB35_fNXVXg4s6gXUGbRp_F8OpGhqgqdmGvrZwSx6DDsDSm6sP4u3Fgzk29g1D-5OB4kqzYNyTXhLE-wxNY57qh_YGmhscGpkhkmEmunCBeaOO18GFQmT1Vo9sOMlU76QzirOpi8hY3ytrTvADnnMNFSEk44VcrHkZx4wqUN6XjMENOC3bWZipWvzYtYvBsmpi0QDdMV00qxowga2s0z5fgmamkLz5-EIC3Yr41cr6oUnbMi2KKobdGCLBruL9OKIGlRj3b-ZdF7eJ6Ft_s05CHuwsZitrR7ngItVBueZvSsHcHehmej07Pu1T1mfQQN
linkProvider Wiley-Blackwell
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1BT9swFLYmOHQXxNgmCoz5sEM5RI1jx252azuqbivtDq3ELdixDZWqUBUQ2o2fwG_kl_Be0gaFCxK5WXmWE7_37M_We98j5IeVxoJduCCOnQuEjGyQKPCrOFa6E_pEC1uwfY7lcCb-nMebaELMhSn5IaoLN_SMYr1GB8cL6fYLayj8FKaSw44WCyT-3IaRQjTsSPx74d2V62ryQgXIwrrhbQyjdr1_DWG-jo9s3OVL_f9eLxZ1DFtsQoNdsrNGj7RbqvsT-eDyPdLob4q2fSYXI817csJ4azI8-UnBCOhgDgCPdotR5hnFwI6nh8cyLXDlaA9twNFf85vlQmPOEz21lw4kkMoZm72JoFMHX3jl7Ep_IbPB6bQ_DNZFFIJLLuMkYJo576UXsJxkKmOWhUZHjGuWecOlyrjPPGxSxiahwVI8sXXaa3iUd6bD-FeylV_nbp9Q7z3jmdZccimMgVU-4QCHMss7oFFum-RoM4Xp2hNu0iK1FgXDJlG1aU2XJZ9GigzX9Tf5_KpgulaAbpTiTdKqFFD1KvmWoxTVmFZqbJKo0M8bYikSTlStg_d0-k4aw-nZKB39Hv89JB8jPIeHGDF4RLZuV3fuG4CVW3NcmOMzujHjrg
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Nb9NAEB2hIlEufCMCBfbAoRzcer3r3Zhb0zYKUDUItVJvZj_biMhEaSIEJ34Cv5FfwoyduLgXJPBt5V3J63mz82zNvAF45ZX1iIuQ5HkIiVSZTwqNfpXn2vTTWBjpa7XPYzU6le_O8rM_qvgbfYj2hxt5Rn1ek4PPfNy9Eg3FPVElOQa0XJLu502p8BOLaNHHKwEphFfTTF7qhERY17KNabbbXd8hmNfTIzeX1cx8-2qm0y6FrWPQ8C6Y9dM3qSefd5YLu-O-XxN2_J_t3YM7K4LK9hpE3YcboXoAm_vrvnAP4dOREQM15mJ7PHr9hiHO2HCCHJLt1TuZOEa5I79-_GwqD-eBDQhmgR1MLmdTQ2VV7NCfB5xBatE0HIwlOwn4Fi6Cn5tHcDo8PNkfJas-Dcm5UHmRcMNDjCpKPLGcdtzz1JqMC8NdtEJpJ6KLGAetL1JL3X5yH0w0eOkYbJ-Lx7BRfanCE2AxRi6cMUIJJa3FQFIIZFzOiz6CRvgebK3NVK6c7bKsq3dpYtoD3TFdOWskO0oS0e7eqSYXtZi2RgKltejBdmvkdlUj6ZyVZIuytUUPstpwf5lWkqZFO3r6L4tewq0PB8Py6O3x-2dwO6Mv_ZRyErdgYzFfhudIhxb2RY3430JgBFE
linkToUnpaywall http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9NAEB5V6aFcKE-RUtAeOJSDi9fr3Y25JW2jCKGGQyOVk9lnGxGZKE2E4MRP4Df2l3Rn_ZBSDiDh28rjlcYzs_PZO_MtwBsrtA1-4RLOnUtykdmkkCGuOJdqkPpC5TayfZ6LySz_cMkvd-C07YWp-SG6H24YGXG9xgBfWl-v883ufvYu6IXd5CGp8Ry5P3cFbjP1YHd2_mn4OdLs5TJB9tVIm5pRjCfecjf-McEWyrxfI7m3qZbqx3e1WGzj2JiIxvvgWhXq-pOvx5u1PjY_77E7_q-Oj-Bhg1TJsHatx7Djqiewd9IeEPcUvnxUbCSmlB1NJ2_fk-BwZDwPYJIMozZzQ7CI5PbX77oFceXICP3NkdP5zXKhsL-KnNkrFySQNhqHo2lOLlx4E9fOrtQzmI3PLk4mSXNgQ3LFBC8SqqjzXvg8LF1GGmppqlVGmaLGayakYd74kBC1LVKNx_5w65RX4ZLe6QFlz6FXfavcCyDee8qMUkwwkWsdMkrBAvQylg2C9zDbh8PWVGUTdTdlbONFwbQPcst85bLm7iiRTXv7TjW_jqzaMiApKVkfjjpDd0_V3M5ZibYoO1v0IYvG-4tYieQW3ejg3-d_CQ8y_LpPsQ7xEHrr1ca9ChBorV83Hn4HdJQE4g
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=La3B6O13%28OH%29%3A+The+First+Acentric+High%E2%80%90Pressure+Borate+Displaying+Edge%E2%80%90Sharing+BO4+Tetrahedra&rft.jtitle=Chemistry+%3A+a+European+journal&rft.au=Fuchs%2C+Birgit&rft.au=Heymann%2C+Gunter&rft.au=Wang%2C+Xuefei&rft.au=Tudi%2C+Abudukadi&rft.date=2020-05-26&rft.issn=0947-6539&rft.eissn=1521-3765&rft.volume=26&rft.issue=30&rft.spage=6851&rft.epage=6861&rft_id=info:doi/10.1002%2Fchem.201905419&rft.externalDBID=10.1002%252Fchem.201905419&rft.externalDocID=CHEM201905419
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0947-6539&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0947-6539&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0947-6539&client=summon