High-pressure synthesis and characterization of the non-centrosymmetric scandium borate ScB6O9(OH)3
The non-centrosymmetric scandium borate ScB (OH) was obtained through a high-pressure/high-temperature experiment at 6 GPa and 1473 K. Single-crystal X-ray diffraction revealed that the structure is isotypic to InB (OH) containing borate triple layers separated by scandium layers. The compound cryst...
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| Published in | Zeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 75; no. 6; pp. 597 - 603 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
De Gruyter
01.07.2020
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 0932-0776 1865-7117 |
| DOI | 10.1515/znb-2020-0070 |
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| Abstract | The non-centrosymmetric scandium borate ScB
(OH)
was obtained through a high-pressure/high-temperature experiment at 6 GPa and 1473 K. Single-crystal X-ray diffraction revealed that the structure is isotypic to InB
(OH)
containing borate triple layers separated by scandium layers. The compound crystallizes in the space group
2 with the lattice parameters
= 38.935(4),
= 4.4136(4), and
= 7.6342(6) Å. Powder X-ray diffraction and vibrational spectroscopy were used to further characterize the compound and verify the proposed structure solution. |
|---|---|
| AbstractList | The non-centrosymmetric scandium borate ScB
(OH)
was obtained through a high-pressure/high-temperature experiment at 6 GPa and 1473 K. Single-crystal X-ray diffraction revealed that the structure is isotypic to InB
(OH)
containing borate triple layers separated by scandium layers. The compound crystallizes in the space group
2 with the lattice parameters
= 38.935(4),
= 4.4136(4), and
= 7.6342(6) Å. Powder X-ray diffraction and vibrational spectroscopy were used to further characterize the compound and verify the proposed structure solution. |
| Author | Huppertz, Hubert Fuchs, Birgit |
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| Snippet | The non-centrosymmetric scandium borate ScB
(OH)
was obtained through a high-pressure/high-temperature experiment at 6 GPa and 1473 K. Single-crystal X-ray... |
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| SubjectTerms | crystal structure high-pressure chemistry scandium borate vibrational spectroscopy |
| Title | High-pressure synthesis and characterization of the non-centrosymmetric scandium borate ScB6O9(OH)3 |
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