Cover Picture: Well‐Controlled Living Polymerization of N‐Propargylamides and Their Derivatives by Rhodium Catalysis (Angew. Chem. Int. Ed. 17/2022)

Well‐controlled polymerization of non‐conjugated acetylenes is a challenging subject. In their Research Article (e202117234), Tsuyoshi Taniguchi, Katsuhiro Maeda et al. report that unique heptaaryl‐1,3,5‐hexatrienylrhodium(I) complexes induce living polymerization of non‐conjugated acetylenes such a...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 61; no. 17
Main Authors Ito, Kosuke, Taniguchi, Tsuyoshi, Nishimura, Tatsuya, Maeda, Katsuhiro
Format Journal Article
LanguageEnglish
Published 19.04.2022
Subjects
Alkynes
Insertion
Polymerization
Polymers
Rhodium
Online AccessGet full text
ISSN1433-7851
1521-3773
DOI10.1002/anie.202204055

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Summary:Well‐controlled polymerization of non‐conjugated acetylenes is a challenging subject. In their Research Article (e202117234), Tsuyoshi Taniguchi, Katsuhiro Maeda et al. report that unique heptaaryl‐1,3,5‐hexatrienylrhodium(I) complexes induce living polymerization of non‐conjugated acetylenes such as N‐propargylamides. This method enables controlling the molecular weights of the resultant polymers and the synthesis of telechelic polymers and block copolymers based on poly(N‐propargylamide)s.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202204055