Rational design of mechanically robust Ni-rich cathode materials via concentration gradient strategy
Mechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle stability for Ni-rich cathode materials of Li-ion batteries. Indeed, the detrimental effects generated from the crack formation are not yet entirely...
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| Published in | Nature communications Vol. 12; no. 1; pp. 6024 - 10 |
|---|---|
| Main Authors | , , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
15.10.2021
Nature Publishing Group Nature Portfolio |
| Subjects | |
| Online Access | Get full text |
| ISSN | 2041-1723 2041-1723 |
| DOI | 10.1038/s41467-021-26290-z |
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| Abstract | Mechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle stability for Ni-rich cathode materials of Li-ion batteries. Indeed, the detrimental effects generated from the crack formation are not yet entirely addressed. Here, applying physicochemical and electrochemical ex situ and in situ characterizations, the effect of Co and Mn on the mechanical properties of the Ni-rich material are thoroughly investigated. As a result, we successfully mitigate the particle cracking issue in Ni-rich cathodes via rational concentration gradient design without sacrificing the electrode capacity. Our result reveals that the Co-enriched surface design in Ni-rich particles benefits from its low stiffness, which can effectively suppress the formation of particle cracking. Meanwhile, the Mn-enriched core limits internal expansion and improve structural integrity. The concentration gradient design also promotes morphological stability and cycling performances in Li metal coin cell configuration.
Mechanical integrity issues are one of the main causes of limited long-term cycle stability for Ni-rich cathode materials. Here the authors analyse the roles of cobalt and manganese and utilise a concentration gradient design to mitigate these issues. |
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| AbstractList | Mechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle stability for Ni-rich cathode materials of Li-ion batteries. Indeed, the detrimental effects generated from the crack formation are not yet entirely addressed. Here, applying physicochemical and electrochemical ex situ and in situ characterizations, the effect of Co and Mn on the mechanical properties of the Ni-rich material are thoroughly investigated. As a result, we successfully mitigate the particle cracking issue in Ni-rich cathodes via rational concentration gradient design without sacrificing the electrode capacity. Our result reveals that the Co-enriched surface design in Ni-rich particles benefits from its low stiffness, which can effectively suppress the formation of particle cracking. Meanwhile, the Mn-enriched core limits internal expansion and improve structural integrity. The concentration gradient design also promotes morphological stability and cycling performances in Li metal coin cell configuration.
Mechanical integrity issues are one of the main causes of limited long-term cycle stability for Ni-rich cathode materials. Here the authors analyse the roles of cobalt and manganese and utilise a concentration gradient design to mitigate these issues. Mechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle stability for Ni-rich cathode materials of Li-ion batteries. Indeed, the detrimental effects generated from the crack formation are not yet entirely addressed. Here, applying physicochemical and electrochemical ex situ and in situ characterizations, the effect of Co and Mn on the mechanical properties of the Ni-rich material are thoroughly investigated. As a result, we successfully mitigate the particle cracking issue in Ni-rich cathodes via rational concentration gradient design without sacrificing the electrode capacity. Our result reveals that the Co-enriched surface design in Ni-rich particles benefits from its low stiffness, which can effectively suppress the formation of particle cracking. Meanwhile, the Mn-enriched core limits internal expansion and improve structural integrity. The concentration gradient design also promotes morphological stability and cycling performances in Li metal coin cell configuration.Mechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle stability for Ni-rich cathode materials of Li-ion batteries. Indeed, the detrimental effects generated from the crack formation are not yet entirely addressed. Here, applying physicochemical and electrochemical ex situ and in situ characterizations, the effect of Co and Mn on the mechanical properties of the Ni-rich material are thoroughly investigated. As a result, we successfully mitigate the particle cracking issue in Ni-rich cathodes via rational concentration gradient design without sacrificing the electrode capacity. Our result reveals that the Co-enriched surface design in Ni-rich particles benefits from its low stiffness, which can effectively suppress the formation of particle cracking. Meanwhile, the Mn-enriched core limits internal expansion and improve structural integrity. The concentration gradient design also promotes morphological stability and cycling performances in Li metal coin cell configuration. Mechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle stability for Ni-rich cathode materials of Li-ion batteries. Indeed, the detrimental effects generated from the crack formation are not yet entirely addressed. Here, applying physicochemical and electrochemical ex situ and in situ characterizations, the effect of Co and Mn on the mechanical properties of the Ni-rich material are thoroughly investigated. As a result, we successfully mitigate the particle cracking issue in Ni-rich cathodes via rational concentration gradient design without sacrificing the electrode capacity. Our result reveals that the Co-enriched surface design in Ni-rich particles benefits from its low stiffness, which can effectively suppress the formation of particle cracking. Meanwhile, the Mn-enriched core limits internal expansion and improve structural integrity. The concentration gradient design also promotes morphological stability and cycling performances in Li metal coin cell configuration. AbstractMechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle stability for Ni-rich cathode materials of Li-ion batteries. Indeed, the detrimental effects generated from the crack formation are not yet entirely addressed. Here, applying physicochemical and electrochemical ex situ and in situ characterizations, the effect of Co and Mn on the mechanical properties of the Ni-rich material are thoroughly investigated. As a result, we successfully mitigate the particle cracking issue in Ni-rich cathodes via rational concentration gradient design without sacrificing the electrode capacity. Our result reveals that the Co-enriched surface design in Ni-rich particles benefits from its low stiffness, which can effectively suppress the formation of particle cracking. Meanwhile, the Mn-enriched core limits internal expansion and improve structural integrity. The concentration gradient design also promotes morphological stability and cycling performances in Li metal coin cell configuration. Mechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle stability for Ni-rich cathode materials of Li-ion batteries. Indeed, the detrimental effects generated from the crack formation are not yet entirely addressed. Here, applying physicochemical and electrochemical ex situ and in situ characterizations, the effect of Co and Mn on the mechanical properties of the Ni-rich material are thoroughly investigated. As a result, we successfully mitigate the particle cracking issue in Ni-rich cathodes via rational concentration gradient design without sacrificing the electrode capacity. Our result reveals that the Co-enriched surface design in Ni-rich particles benefits from its low stiffness, which can effectively suppress the formation of particle cracking. Meanwhile, the Mn-enriched core limits internal expansion and improve structural integrity. The concentration gradient design also promotes morphological stability and cycling performances in Li metal coin cell configuration.Mechanical integrity issues are one of the main causes of limited long-term cycle stability for Ni-rich cathode materials. Here the authors analyse the roles of cobalt and manganese and utilise a concentration gradient design to mitigate these issues. Mechanical integrity issues are one of the main causes of limited long-term cycle stability for Ni-rich cathode materials. Here the authors analyse the roles of cobalt and manganese and utilise a concentration gradient design to mitigate these issues. |
| ArticleNumber | 6024 |
| Author | Ren, Yang Arslan, Ilke Zhou, Tao Holt, Martin V. Liu, Tongchao Yu, Lei Dai, Alvin Huang, Xiaojing Amine, Khalil Wen, Jianguo Gim, Jihyeon Lu, Jun Chu, Yong S. Cai, Zhonghou Xiao, Xianghui |
| Author_xml | – sequence: 1 givenname: Tongchao surname: Liu fullname: Liu, Tongchao organization: Chemical Sciences and Engineering Division, Argonne National Laboratory – sequence: 2 givenname: Lei surname: Yu fullname: Yu, Lei organization: Center for Nanoscale Materials, Argonne National Laboratory – sequence: 3 givenname: Jun orcidid: 0000-0003-0858-8577 surname: Lu fullname: Lu, Jun email: junlu@anl.gov organization: Chemical Sciences and Engineering Division, Argonne National Laboratory – sequence: 4 givenname: Tao surname: Zhou fullname: Zhou, Tao organization: Center for Nanoscale Materials, Argonne National Laboratory – sequence: 5 givenname: Xiaojing surname: Huang fullname: Huang, Xiaojing organization: National Synchrotron Light Source II, Brookhaven National Laboratory – sequence: 6 givenname: Zhonghou surname: Cai fullname: Cai, Zhonghou organization: X-ray Science Division, Advanced Photon Sources, Argonne National Laboratory – sequence: 7 givenname: Alvin surname: Dai fullname: Dai, Alvin organization: Chemical Sciences and Engineering Division, Argonne National Laboratory – sequence: 8 givenname: Jihyeon orcidid: 0000-0002-4171-3707 surname: Gim fullname: Gim, Jihyeon organization: Chemical Sciences and Engineering Division, Argonne National Laboratory – sequence: 9 givenname: Yang orcidid: 0000-0001-9831-6035 surname: Ren fullname: Ren, Yang organization: X-ray Science Division, Advanced Photon Sources, Argonne National Laboratory – sequence: 10 givenname: Xianghui orcidid: 0000-0002-7142-3452 surname: Xiao fullname: Xiao, Xianghui organization: National Synchrotron Light Source II, Brookhaven National Laboratory – sequence: 11 givenname: Martin V. orcidid: 0000-0003-2640-7100 surname: Holt fullname: Holt, Martin V. organization: Center for Nanoscale Materials, Argonne National Laboratory – sequence: 12 givenname: Yong S. surname: Chu fullname: Chu, Yong S. organization: National Synchrotron Light Source II, Brookhaven National Laboratory – sequence: 13 givenname: Ilke surname: Arslan fullname: Arslan, Ilke organization: Center for Nanoscale Materials, Argonne National Laboratory – sequence: 14 givenname: Jianguo orcidid: 0000-0002-3755-0044 surname: Wen fullname: Wen, Jianguo email: jwen@anl.gov organization: Center for Nanoscale Materials, Argonne National Laboratory – sequence: 15 givenname: Khalil orcidid: 0000-0001-9206-3719 surname: Amine fullname: Amine, Khalil email: amine@anl.gov organization: Chemical Sciences and Engineering Division, Argonne National Laboratory, Material Science and Engineering, Stanford University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/34654811$$D View this record in MEDLINE/PubMed https://www.osti.gov/servlets/purl/1828322$$D View this record in Osti.gov |
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| Snippet | Mechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle... AbstractMechanical integrity issues such as particle cracking are considered one of the leading causes of structural deterioration and limited long-term cycle... Mechanical integrity issues are one of the main causes of limited long-term cycle stability for Ni-rich cathode materials. Here the authors analyse the roles... |
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| SubjectTerms | 147/143 639/301/299/161 639/301/299/891 639/4077/4079/891 639/638/675 Cathodes Cobalt Concentration gradient Design Electrochemistry Electrode materials Electrolytes Humanities and Social Sciences Investigations Laboratories Lithium-ion batteries Manganese MATERIALS SCIENCE Mechanical properties Morphology multidisciplinary Nickel Phase transitions Rechargeable batteries Science Science (multidisciplinary) Stability analysis Stiffness Structural integrity |
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| Title | Rational design of mechanically robust Ni-rich cathode materials via concentration gradient strategy |
| URI | https://link.springer.com/article/10.1038/s41467-021-26290-z https://www.ncbi.nlm.nih.gov/pubmed/34654811 https://www.proquest.com/docview/2582276444 https://www.proquest.com/docview/2582814331 https://www.osti.gov/servlets/purl/1828322 https://pubmed.ncbi.nlm.nih.gov/PMC8520018 https://doaj.org/article/c7c1c3287cc74766b3ec7f00038e0c40 |
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