铑/双膦配体催化均相内烯烃氢甲酰化反应的研究进展

烯烃氢甲酰化反应是工业上合成醛的重要方法.由于双膦配体良好的配位能力,形成的铑配合物有很好的催化活性,在内烯烃氢甲酰化反应中,可以有效地提高直链醛选择性.本文系统地综述了近年来双膦配体铑配合物催化均相内烯烃氢甲酰化反应的研究进展,讨论了双膦配体结构对催化剂活性和生成直链醛选择性的影响....

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Published inChinese journal of catalysis Vol. 30; no. 6; pp. 577 - 586
Main Author 刘雯静 袁茂林 付海燕 李瑞祥 陈华
Format Journal Article
LanguageChinese
Published 四川大学化学学院有机金属络合催化研究所,绿色化学与技术教育部重点实验室,四川成都,610064 2009
Subjects
内烯烃
双膦配体
氢甲酰化
铑
双膦配体
铑
内烯烃
氢甲酰化
Online AccessGet full text
ISSN0253-9837
1872-2067
DOI10.3321/j.issn:0253-9837.2009.06.019

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Abstract 烯烃氢甲酰化反应是工业上合成醛的重要方法.由于双膦配体良好的配位能力,形成的铑配合物有很好的催化活性,在内烯烃氢甲酰化反应中,可以有效地提高直链醛选择性.本文系统地综述了近年来双膦配体铑配合物催化均相内烯烃氢甲酰化反应的研究进展,讨论了双膦配体结构对催化剂活性和生成直链醛选择性的影响.
AbstractList 烯烃氢甲酰化反应是工业上合成醛的重要方法.由于双膦配体良好的配位能力,形成的铑配合物有很好的催化活性,在内烯烃氢甲酰化反应中,可以有效地提高直链醛选择性.本文系统地综述了近年来双膦配体铑配合物催化均相内烯烃氢甲酰化反应的研究进展,讨论了双膦配体结构对催化剂活性和生成直链醛选择性的影响.
O643; 烯烃氢甲酰化反应是工业上合成醛的重要方法.由于双膦配体良好的配位能力,形成的铑配合物有很好的催化活性,在内烯烃氢甲酰化反应中,可以有效地提高直链醛选择性.本文系统地综述了近年来双膦配体铑配合物催化均相内烯烃氢甲酰化反应的研究进展,讨论了双膦配体结构对催化剂活性和生成直链醛选择性的影响.
Author 刘雯静 袁茂林 付海燕 李瑞祥 陈华
AuthorAffiliation 四川大学化学学院有机金属络合催化研究所、绿色化学与技术教育部重点实验室,四川成都610064
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LI Ruixiang
CHEN Hua
LIU Wenjing
YUAN Maolin
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铑
内烯烃
氢甲酰化
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Publisher 四川大学化学学院有机金属络合催化研究所,绿色化学与技术教育部重点实验室,四川成都,610064
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Snippet 烯烃氢甲酰化反应是工业上合成醛的重要方法.由于双膦配体良好的配位能力,形成的铑配合物有很好的催化活性,在内烯烃氢甲酰化反应中,可以有效地提高直链醛选择性.本文系统地...
O643; 烯烃氢甲酰化反应是工业上合成醛的重要方法.由于双膦配体良好的配位能力,形成的铑配合物有很好的催化活性,在内烯烃氢甲酰化反应中,可以有效地提高直链醛选择性.本文...
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SubjectTerms 内烯烃
双膦配体
氢甲酰化
铑
Title 铑/双膦配体催化均相内烯烃氢甲酰化反应的研究进展
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