Sub-Picosecond Singlet Exciton Fission in Cyano-Substituted Diaryltetracenes
Thin films of 5,11‐dicyano‐6,12‐diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T1)−E(S1)=−0.17 eV), where S1 an...
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| Published in | Angewandte Chemie International Edition Vol. 54; no. 30; pp. 8679 - 8683 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
20.07.2015
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1433-7851 1521-3773 1521-3773 |
| DOI | 10.1002/anie.201501355 |
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| Abstract | Thin films of 5,11‐dicyano‐6,12‐diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T1)−E(S1)=−0.17 eV), where S1 and T1 are singlet and triplet excitons, respectively. As a result of tuning the triplet‐state energy, SF is faster in TcCN relative to the corresponding endoergic process in tetracene. SF proceeds with two time constants in the film samples (τ=0.8±0.2 ps and τ=23±3 ps), which is attributed to structural disorder within the film giving rise to one population with a favorable interchromophore geometry, which undergoes rapid SF, and a second population in which the initially formed singlet exciton must diffuse to a site at which this favorable geometry exists. A triplet yield analysis using transient absorption spectra indicates the formation of 1.6±0.3 triplets per initial excited state.
Divide and conquer: Transient absorption measurements reveal sub‐picosecond singlet exciton fission in thin films of a cyano‐substituted diaryltetracene. A triplet yield analysis of the transient absorption data set indicates the formation of 1.6±0.3 triplet excitons per singlet exciton, as a result of rapid and efficient singlet fission. |
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| AbstractList | Thin films of 5,11-dicyano-6,12-diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T1)-E(S1)=-0.17eV), where S1 and T1 are singlet and triplet excitons, respectively. As a result of tuning the triplet-state energy, SF is faster in TcCN relative to the corresponding endoergic process in tetracene. SF proceeds with two time constants in the film samples (τ=0.8±0.2ps and τ=23±3ps), which is attributed to structural disorder within the film giving rise to one population with a favorable interchromophore geometry, which undergoes rapid SF, and a second population in which the initially formed singlet exciton must diffuse to a site at which this favorable geometry exists. A triplet yield analysis using transient absorption spectra indicates the formation of 1.6±0.3 triplets per initial excited state. Thin films of 5,11‐dicyano‐6,12‐diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T1)−E(S1)=−0.17 eV), where S1 and T1 are singlet and triplet excitons, respectively. As a result of tuning the triplet‐state energy, SF is faster in TcCN relative to the corresponding endoergic process in tetracene. SF proceeds with two time constants in the film samples (τ=0.8±0.2 ps and τ=23±3 ps), which is attributed to structural disorder within the film giving rise to one population with a favorable interchromophore geometry, which undergoes rapid SF, and a second population in which the initially formed singlet exciton must diffuse to a site at which this favorable geometry exists. A triplet yield analysis using transient absorption spectra indicates the formation of 1.6±0.3 triplets per initial excited state. Divide and conquer: Transient absorption measurements reveal sub‐picosecond singlet exciton fission in thin films of a cyano‐substituted diaryltetracene. A triplet yield analysis of the transient absorption data set indicates the formation of 1.6±0.3 triplet excitons per singlet exciton, as a result of rapid and efficient singlet fission. Thin films of 5,11‐dicyano‐6,12‐diphenyltetracene ( TcCN ) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T 1 )−E(S 1 )=−0.17 eV), where S 1 and T 1 are singlet and triplet excitons, respectively. As a result of tuning the triplet‐state energy, SF is faster in TcCN relative to the corresponding endoergic process in tetracene. SF proceeds with two time constants in the film samples (τ=0.8±0.2 ps and τ=23±3 ps), which is attributed to structural disorder within the film giving rise to one population with a favorable interchromophore geometry, which undergoes rapid SF, and a second population in which the initially formed singlet exciton must diffuse to a site at which this favorable geometry exists. A triplet yield analysis using transient absorption spectra indicates the formation of 1.6±0.3 triplets per initial excited state. Thin films of 5,11-dicyano-6,12-diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T1)-E(S1)=-0.17 eV), where S1 and T1 are singlet and triplet excitons, respectively. As a result of tuning the triplet-state energy, SF is faster in TcCN relative to the corresponding endoergic process in tetracene. SF proceeds with two time constants in the film samples (τ=0.8±0.2 ps and τ=23±3 ps), which is attributed to structural disorder within the film giving rise to one population with a favorable interchromophore geometry, which undergoes rapid SF, and a second population in which the initially formed singlet exciton must diffuse to a site at which this favorable geometry exists. A triplet yield analysis using transient absorption spectra indicates the formation of 1.6±0.3 triplets per initial excited state.Thin films of 5,11-dicyano-6,12-diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T1)-E(S1)=-0.17 eV), where S1 and T1 are singlet and triplet excitons, respectively. As a result of tuning the triplet-state energy, SF is faster in TcCN relative to the corresponding endoergic process in tetracene. SF proceeds with two time constants in the film samples (τ=0.8±0.2 ps and τ=23±3 ps), which is attributed to structural disorder within the film giving rise to one population with a favorable interchromophore geometry, which undergoes rapid SF, and a second population in which the initially formed singlet exciton must diffuse to a site at which this favorable geometry exists. A triplet yield analysis using transient absorption spectra indicates the formation of 1.6±0.3 triplets per initial excited state. Thin films of 5,11-dicyano-6,12-diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T1)-E(S1)=-0.17 eV), where S1 and T1 are singlet and triplet excitons, respectively. As a result of tuning the triplet-state energy, SF is faster in TcCN relative to the corresponding endoergic process in tetracene. SF proceeds with two time constants in the film samples (τ=0.8±0.2 ps and τ=23±3 ps), which is attributed to structural disorder within the film giving rise to one population with a favorable interchromophore geometry, which undergoes rapid SF, and a second population in which the initially formed singlet exciton must diffuse to a site at which this favorable geometry exists. A triplet yield analysis using transient absorption spectra indicates the formation of 1.6±0.3 triplets per initial excited state. Thin films of 5,11-dicyano-6,12-diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T sub(1))-E(S sub(1))= -0.17eV), where S sub(1) and T sub(1) are singlet and triplet excitons, respectively. As a result of tuning the triplet-state energy, SF is faster in TcCN relative to the corresponding endoergic process in tetracene. SF proceeds with two time constants in the film samples ( tau =0.8 plus or minus 0.2ps and tau =23 plus or minus 3ps), which is attributed to structural disorder within the film giving rise to one population with a favorable interchromophore geometry, which undergoes rapid SF, and a second population in which the initially formed singlet exciton must diffuse to a site at which this favorable geometry exists. A triplet yield analysis using transient absorption spectra indicates the formation of 1.6 plus or minus 0.3 triplets per initial excited state. Divide and conquer: Transient absorption measurements reveal sub-picosecond singlet exciton fission in thin films of a cyano-substituted diaryltetracene. A triplet yield analysis of the transient absorption data set indicates the formation of 1.6 plus or minus 0.3 triplet excitons per singlet exciton, as a result of rapid and efficient singlet fission. |
| Author | Wasielewski, Michael R. Margulies, Eric A. Schaller, Richard D. Wu, Yi-Lin Shoer, Leah E. Diederich, François Gawel, Przemyslaw Miller, Stephen A. |
| Author_xml | – sequence: 1 givenname: Eric A. surname: Margulies fullname: Margulies, Eric A. organization: Department of Chemistry and Argonne-Northwestern Solar Energy Research (ANSER) Center, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (USA) – sequence: 2 givenname: Yi-Lin surname: Wu fullname: Wu, Yi-Lin organization: Department of Chemistry and Argonne-Northwestern Solar Energy Research (ANSER) Center, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (USA) – sequence: 3 givenname: Przemyslaw surname: Gawel fullname: Gawel, Przemyslaw organization: Laboratorium für Organische Chemie, ETH Zürich, Vladimir-Prelog-Weg 3, HCI, 8093 Zürich (Switzerland) – sequence: 4 givenname: Stephen A. surname: Miller fullname: Miller, Stephen A. organization: Department of Chemistry and Argonne-Northwestern Solar Energy Research (ANSER) Center, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (USA) – sequence: 5 givenname: Leah E. surname: Shoer fullname: Shoer, Leah E. organization: Department of Chemistry and Argonne-Northwestern Solar Energy Research (ANSER) Center, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (USA) – sequence: 6 givenname: Richard D. surname: Schaller fullname: Schaller, Richard D. organization: Department of Chemistry, Northwestern University and Center for Nanoscale Materials, Argonne National Laboratory, Argonne, IL 60439 (USA) – sequence: 7 givenname: François surname: Diederich fullname: Diederich, François email: diederich@org.chem.ethz.ch organization: Laboratorium für Organische Chemie, ETH Zürich, Vladimir-Prelog-Weg 3, HCI, 8093 Zürich (Switzerland) – sequence: 8 givenname: Michael R. surname: Wasielewski fullname: Wasielewski, Michael R. email: m-wasielewski@northwestern.edu organization: Department of Chemistry and Argonne-Northwestern Solar Energy Research (ANSER) Center, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (USA) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26097009$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1021/cr1002613 10.1021/ar300286s 10.1002/anie.201402299 10.1038/nmat4097 10.1351/pac196511030371 10.1063/1.4867696 10.1021/ja300504t 10.1126/science.1232994 10.1038/nchem.1436 10.1016/0009-2614(69)80122-3 10.1063/1.4876600 10.1063/1.1674702 10.1063/1.555770 10.1021/ja501337b 10.1063/1.3664630 10.1021/ja408854u 10.1038/ncomms3679 10.1038/nmat4093 10.1021/jz2015346 10.1002/ange.201402299 10.1021/ja301683w 10.1039/c2cp40449d 10.1063/1.2717561 10.1021/jp208063h 10.1103/PhysRevB.84.193203 10.1063/1.2356795 10.1021/ja073173y 10.1063/1.3495764 10.1038/nchem.1945 |
| ContentType | Journal Article |
| Copyright | 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Keywords | time-resolved spectroscopy chromophores photophysics tetracene derivatives singlet fission |
| Language | English |
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| Notes | Swiss National Science Foundation Office of Basic Energy Sciences, U.S. Department of Energy (DOE) - No. DE-FG02-99ER14999 National Science Foundation - No. DMR-1121262 This work was supported by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, U.S. Department of Energy (DOE), under Grant No. DE-FG02-99ER14999 (M.R.W.), the Swiss National Science Foundation, and the ERC Advanced Grant No. 246637 ("OPTELOMAC"). This work was performed, in part, at the Center for Nanoscale Materials, a U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences User Facility under Contract No. DE-AC02-06CH11357. This work made use of the J. B. Cohen X-ray Diffraction Facility at the Materials Research Center of Northwestern University supported by the National Science Foundation MRSEC program (DMR-1121262). We thank Dr. Matthew Krzyaniak and Dr. Samuel Eaton for help with data analysis, acquiring time-resolved fluorescence data, and helpful discussions. ArticleID:ANIE201501355 ERC - No. 246637 ark:/67375/WNG-22NKPWXL-7 istex:848979D32E438E7CBF70DB5CEAC27F187B0F6448 This work was supported by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, U.S. Department of Energy (DOE), under Grant No. DE‐FG02‐99ER14999 (M.R.W.), the Swiss National Science Foundation, and the ERC Advanced Grant No. 246637 (“OPTELOMAC”). This work was performed, in part, at the Center for Nanoscale Materials, a U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences User Facility under Contract No. DE‐AC02‐06CH11357. This work made use of the J. B. Cohen X‐ray Diffraction Facility at the Materials Research Center of Northwestern University supported by the National Science Foundation MRSEC program (DMR‐1121262). We thank Dr. Matthew Krzyaniak and Dr. Samuel Eaton for help with data analysis, acquiring time‐resolved fluorescence data, and helpful discussions. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
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| References | M. B. Smith, J. Michl, Chem. Rev. 2010, 110, 6891-6936. J. J. Burdett, C. J. Bardeen, J. Am. Chem. Soc. 2012, 134, 8597-8607 L. Ma, K. Zhang, C. Kloc, H. Sun, M. E. Michel-Beyerle, G. G. Gurzadyan, Phys. Chem. Chem. Phys. 2012, 14, 8307-8312 I. Carmichael, G. L. Hug, J. Phys. Chem. Ref. Data 1986, 15, 1-250. P. Gawel, C. Dengiz, A. D. Finke, N. Trapp, C. Boudon, J.-P. Gisselbrecht, F. Diederich, Angew. Chem. Int. Ed. 2014, 53, 4341-4345 A. Ryasnyanskiy, I. Biaggio, Phys. Rev. B 2011, 84, 193203. J. J. Burdett, A. M. Müller, D. Gosztola, C. J. Bardeen, J. Chem. Phys. 2010, 133, 144506 M. W. B. Wilson, A. Rao, K. Johnson, S. Gélinas, R. di Pietro, J. Clark, R. H. Friend, J. Am. Chem. Soc. 2013, 135, 16680-16688 J. N. Schrauben, J. L. Ryerson, J. Michl, J. C. Johnson, J. Am. Chem. Soc. 2014, 136, 7363-7373. M. Kytka, A. Gerlach, F. Schreiber, J. Kováč, Appl. Phys. Lett. 2007, 90, 131911. R. E. Merrifield, P. Avakian, R. P. Groff, Chem. Phys. Lett. 1969, 3, 155-157 S. T. Roberts, R. E. McAnally, J. N. Mastron, D. H. Webber, M. T. Whited, R. L. Brutchey, M. E. Thompson, S. E. Bradforth, J. Am. Chem. Soc. 2012, 134, 6388-6400 Y.-F. Chang, Z.-Y. Lu, L.-J. An, J.-P. Zhang, J. Phys. Chem. C 2011, 116, 1195-1199. W.-L. Chan, T. C. Berkelbach, M. R. Provorse, N. R. Monahan, J. R. Tritsch, M. S. Hybertsen, D. R. Reichman, J. Gao, X. Y. Zhu, Acc. Chem. Res. 2013, 46, 1321-1329 W.-L. Chan, M. Ligges, X. Y. Zhu, Nat. Chem. 2012, 4, 840-845. J. J. Burdett, D. Gosztola, C. J. Bardeen, J. Chem. Phys. 2011, 135, 214508 S. R. Yost, J. Lee, M. W. B. Wilson, T. Wu, D. P. McMahon, R. R. Parkhurst, N. J. Thompson, D. N. Congreve, A. Rao, K. Johnson, M. Y. Sfeir, M. G. Bawendi, T. M. Swager, R. H. Friend, M. A. Baldo, T. Van Voorhis, Nat. Chem. 2014, 6, 492-497. T. C. Wu, N. J. Thompson, D. N. Congreve, E. Hontz, S. R. Yost, T. Van Voorhis, M. A. Baldo, Appl. Phys. Lett. 2014, 104, 193901. J. R. Tritsch, W.-L. Chan, X. Wu, N. R. Monahan, X.-Y. Zhu, Nat. Commun. 2013, 4, 2679 D. N. Congreve, J. Lee, N. J. Thompson, E. Hontz, S. R. Yost, P. D. Reusswig, M. E. Bahlke, S. Reineke, T. Van Voorhis, M. A. Baldo, Science 2013, 340, 334-337. M. Tabachnyk, B. Ehrler, S. Gélinas, M. L. Böhm, B. J. Walker, K. P. Musselman, N. C. Greenham, R. H. Friend, A. Rao, Nat. Mater. 2014, 13, 1033-1038 Z. Birech, M. Schwoerer, T. Schmeiler, J. Pflaum, H. Schwoerer, J. Chem. Phys. 2014, 140, 114501 M. Kasha, H. R. Rawls, M. A. El-Bayoumi, Pure Appl. Chem. 1965, 11, 371-392. T. Minami, M. Nakano, J. Phys. Chem. Lett. 2011, 3, 145-150. M. C. Hanna, A. J. Nozik, J. Appl. Phys. 2006, 100, 074510. N. J. Thompson, M. W. B. Wilson, D. N. Congreve, P. R. Brown, J. M. Scherer, T. S. Bischof, M. Wu, N. Geva, M. Welborn, T. V. Voorhis, V. Bulović, M. G. Bawendi, M. A. Baldo, Nat. Mater. 2014, 13, 1039-1043. A. M. Müller, Y. S. Avlasevich, W. W. Schoeller, K. Müllen, C. J. Bardeen, J. Am. Chem. Soc. 2007, 129, 14240-14250 Y. Tomkiewicz, R. P. Groff, P. Avakian, J. Chem. Phys. 1971, 54, 4504-4507 Angew. Chem. 2014, 126, 4430-4434. 2011; 116 2014 2014; 53 126 2011; 135 2007; 129 1965; 11 2013; 4 2013; 46 2011; 84 1986; 15 2007; 90 2013; 340 2012; 14 2011; 3 2014; 136 1971; 54 2012; 134 1969; 3 2010; 110 2010; 133 2014; 13 2013; 135 2014; 140 2012; 4 2014; 6 2006; 100 2014; 104 e_1_2_2_3_2 e_1_2_2_24_2 e_1_2_2_4_2 e_1_2_2_23_2 e_1_2_2_5_2 e_1_2_2_22_2 e_1_2_2_6_2 e_1_2_2_21_2 e_1_2_2_20_2 e_1_2_2_1_2 e_1_2_2_2_2 e_1_2_2_29_2 e_1_2_2_7_2 e_1_2_2_8_2 e_1_2_2_28_2 e_1_2_2_27_2 e_1_2_2_24_4 e_1_2_2_26_2 e_1_2_2_9_2 e_1_2_2_24_3 e_1_2_2_25_2 e_1_2_2_13_2 e_1_2_2_12_2 e_1_2_2_11_2 e_1_2_2_10_2 e_1_2_2_19_2 e_1_2_2_30_2 e_1_2_2_18_2 e_1_2_2_31_2 e_1_2_2_17_2 e_1_2_2_16_2 e_1_2_2_15_2 e_1_2_2_14_2 |
| References_xml | – reference: J. N. Schrauben, J. L. Ryerson, J. Michl, J. C. Johnson, J. Am. Chem. Soc. 2014, 136, 7363-7373. – reference: W.-L. Chan, T. C. Berkelbach, M. R. Provorse, N. R. Monahan, J. R. Tritsch, M. S. Hybertsen, D. R. Reichman, J. Gao, X. Y. Zhu, Acc. Chem. Res. 2013, 46, 1321-1329; – reference: P. Gawel, C. Dengiz, A. D. Finke, N. Trapp, C. Boudon, J.-P. Gisselbrecht, F. Diederich, Angew. Chem. Int. Ed. 2014, 53, 4341-4345; – reference: A. Ryasnyanskiy, I. Biaggio, Phys. Rev. B 2011, 84, 193203. – reference: S. R. Yost, J. Lee, M. W. B. Wilson, T. Wu, D. P. McMahon, R. R. Parkhurst, N. J. Thompson, D. N. Congreve, A. Rao, K. Johnson, M. Y. Sfeir, M. G. Bawendi, T. M. Swager, R. H. Friend, M. A. Baldo, T. Van Voorhis, Nat. Chem. 2014, 6, 492-497. – reference: M. W. B. Wilson, A. Rao, K. Johnson, S. Gélinas, R. di Pietro, J. Clark, R. H. Friend, J. Am. Chem. Soc. 2013, 135, 16680-16688; – reference: M. B. Smith, J. Michl, Chem. Rev. 2010, 110, 6891-6936. – reference: J. J. Burdett, A. M. Müller, D. Gosztola, C. J. Bardeen, J. Chem. Phys. 2010, 133, 144506; – reference: R. E. Merrifield, P. Avakian, R. P. Groff, Chem. Phys. Lett. 1969, 3, 155-157; – reference: Y.-F. Chang, Z.-Y. Lu, L.-J. An, J.-P. Zhang, J. Phys. Chem. C 2011, 116, 1195-1199. – reference: I. Carmichael, G. L. Hug, J. Phys. Chem. Ref. Data 1986, 15, 1-250. – reference: M. C. Hanna, A. J. Nozik, J. Appl. Phys. 2006, 100, 074510. – reference: N. J. Thompson, M. W. B. Wilson, D. N. Congreve, P. R. Brown, J. M. Scherer, T. S. Bischof, M. Wu, N. Geva, M. Welborn, T. V. Voorhis, V. Bulović, M. G. Bawendi, M. A. Baldo, Nat. Mater. 2014, 13, 1039-1043. – reference: T. C. Wu, N. J. Thompson, D. N. Congreve, E. Hontz, S. R. Yost, T. Van Voorhis, M. A. Baldo, Appl. Phys. Lett. 2014, 104, 193901. – reference: D. N. Congreve, J. Lee, N. J. Thompson, E. Hontz, S. R. Yost, P. D. Reusswig, M. E. Bahlke, S. Reineke, T. Van Voorhis, M. A. Baldo, Science 2013, 340, 334-337. – reference: T. Minami, M. Nakano, J. Phys. Chem. Lett. 2011, 3, 145-150. – reference: Y. Tomkiewicz, R. P. Groff, P. Avakian, J. Chem. Phys. 1971, 54, 4504-4507; – reference: M. Tabachnyk, B. Ehrler, S. Gélinas, M. L. Böhm, B. J. Walker, K. P. Musselman, N. C. Greenham, R. H. Friend, A. Rao, Nat. Mater. 2014, 13, 1033-1038; – reference: J. R. Tritsch, W.-L. Chan, X. Wu, N. R. Monahan, X.-Y. Zhu, Nat. Commun. 2013, 4, 2679; – reference: A. M. Müller, Y. S. Avlasevich, W. W. Schoeller, K. Müllen, C. J. Bardeen, J. Am. Chem. Soc. 2007, 129, 14240-14250; – reference: M. Kytka, A. Gerlach, F. Schreiber, J. Kováč, Appl. Phys. Lett. 2007, 90, 131911. – reference: Angew. Chem. 2014, 126, 4430-4434. – reference: M. Kasha, H. R. Rawls, M. A. El-Bayoumi, Pure Appl. Chem. 1965, 11, 371-392. – reference: J. J. Burdett, C. J. Bardeen, J. Am. Chem. Soc. 2012, 134, 8597-8607; – reference: L. Ma, K. Zhang, C. Kloc, H. Sun, M. E. Michel-Beyerle, G. G. Gurzadyan, Phys. Chem. Chem. Phys. 2012, 14, 8307-8312; – reference: J. J. Burdett, D. Gosztola, C. J. Bardeen, J. Chem. Phys. 2011, 135, 214508; – reference: W.-L. Chan, M. Ligges, X. Y. Zhu, Nat. Chem. 2012, 4, 840-845. – reference: S. T. Roberts, R. E. McAnally, J. N. Mastron, D. H. Webber, M. T. Whited, R. L. Brutchey, M. E. Thompson, S. E. Bradforth, J. Am. Chem. Soc. 2012, 134, 6388-6400; – reference: Z. Birech, M. Schwoerer, T. Schmeiler, J. Pflaum, H. Schwoerer, J. Chem. Phys. 2014, 140, 114501; – volume: 116 start-page: 1195 year: 2011 end-page: 1199 publication-title: J. Phys. Chem. C – volume: 104 start-page: 193901 year: 2014 publication-title: Appl. Phys. Lett. – volume: 133 start-page: 144506 year: 2010 publication-title: J. Chem. Phys. – volume: 100 start-page: 074510 year: 2006 publication-title: J. Appl. Phys. – volume: 15 start-page: 1 year: 1986 end-page: 250 publication-title: J. Phys. Chem. Ref. Data – volume: 134 start-page: 8597 year: 2012 end-page: 8607 publication-title: J. Am. Chem. Soc. – volume: 6 start-page: 492 year: 2014 end-page: 497 publication-title: Nat. Chem. – volume: 3 start-page: 155 year: 1969 end-page: 157 publication-title: Chem. Phys. Lett. – volume: 3 start-page: 145 year: 2011 end-page: 150 publication-title: J. Phys. Chem. Lett. – volume: 4 start-page: 2679 year: 2013 publication-title: Nat. Commun. – volume: 4 start-page: 840 year: 2012 end-page: 845 publication-title: Nat. Chem. – volume: 11 start-page: 371 year: 1965 end-page: 392 publication-title: Pure Appl. Chem. – volume: 129 start-page: 14240 year: 2007 end-page: 14250 publication-title: J. Am. Chem. Soc. – volume: 140 start-page: 114501 year: 2014 publication-title: J. Chem. Phys. – volume: 84 start-page: 193203 year: 2011 publication-title: Phys. Rev. B – volume: 13 start-page: 1039 year: 2014 end-page: 1043 publication-title: Nat. Mater. – volume: 136 start-page: 7363 year: 2014 end-page: 7373 publication-title: J. Am. Chem. Soc. – volume: 110 start-page: 6891 year: 2010 end-page: 6936 publication-title: Chem. Rev. – volume: 54 start-page: 4504 year: 1971 end-page: 4507 publication-title: J. Chem. Phys. – volume: 135 start-page: 214508 year: 2011 publication-title: J. Chem. Phys. – volume: 14 start-page: 8307 year: 2012 end-page: 8312 publication-title: Phys. Chem. Chem. Phys. – volume: 13 start-page: 1033 year: 2014 end-page: 1038 publication-title: Nat. Mater. – volume: 134 start-page: 6388 year: 2012 end-page: 6400 publication-title: J. Am. Chem. Soc. – volume: 46 start-page: 1321 year: 2013 end-page: 1329 publication-title: Acc. Chem. Res. – volume: 53 126 start-page: 4341 4430 year: 2014 2014 end-page: 4345 4434 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 135 start-page: 16680 year: 2013 end-page: 16688 publication-title: J. Am. Chem. Soc. – volume: 340 start-page: 334 year: 2013 end-page: 337 publication-title: Science – volume: 90 start-page: 131911 year: 2007 publication-title: Appl. Phys. Lett. – ident: e_1_2_2_1_2 doi: 10.1021/cr1002613 – ident: e_1_2_2_17_2 doi: 10.1021/ar300286s – ident: e_1_2_2_24_2 doi: 10.1002/anie.201402299 – ident: e_1_2_2_28_2 – ident: e_1_2_2_5_2 doi: 10.1038/nmat4097 – ident: e_1_2_2_27_2 doi: 10.1351/pac196511030371 – ident: e_1_2_2_20_2 doi: 10.1063/1.4867696 – ident: e_1_2_2_16_2 doi: 10.1021/ja300504t – ident: e_1_2_2_3_2 – ident: e_1_2_2_6_2 doi: 10.1126/science.1232994 – ident: e_1_2_2_26_2 doi: 10.1038/nchem.1436 – ident: e_1_2_2_10_2 doi: 10.1016/0009-2614(69)80122-3 – ident: e_1_2_2_21_2 doi: 10.1063/1.4876600 – ident: e_1_2_2_9_2 – ident: e_1_2_2_24_4 – ident: e_1_2_2_11_2 doi: 10.1063/1.1674702 – ident: e_1_2_2_31_2 doi: 10.1063/1.555770 – ident: e_1_2_2_30_2 doi: 10.1021/ja501337b – ident: e_1_2_2_14_2 doi: 10.1063/1.3664630 – ident: e_1_2_2_18_2 doi: 10.1021/ja408854u – ident: e_1_2_2_19_2 doi: 10.1038/ncomms3679 – ident: e_1_2_2_4_2 doi: 10.1038/nmat4093 – ident: e_1_2_2_8_2 doi: 10.1021/jz2015346 – ident: e_1_2_2_24_3 doi: 10.1002/ange.201402299 – ident: e_1_2_2_15_2 doi: 10.1021/ja301683w – ident: e_1_2_2_29_2 doi: 10.1039/c2cp40449d – ident: e_1_2_2_22_2 doi: 10.1063/1.2717561 – ident: e_1_2_2_23_2 doi: 10.1021/jp208063h – ident: e_1_2_2_25_2 doi: 10.1103/PhysRevB.84.193203 – ident: e_1_2_2_2_2 doi: 10.1063/1.2356795 – ident: e_1_2_2_12_2 doi: 10.1021/ja073173y – ident: e_1_2_2_13_2 doi: 10.1063/1.3495764 – ident: e_1_2_2_7_2 doi: 10.1038/nchem.1945 |
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| Snippet | Thin films of 5,11‐dicyano‐6,12‐diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of... Thin films of 5,11‐dicyano‐6,12‐diphenyltetracene ( TcCN ) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of... Thin films of 5,11-dicyano-6,12-diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of... |
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| SubjectTerms | chromophores Diffusion Disorders Excitation Excitation spectra Fission Formations photophysics singlet fission tetracene derivatives Thin films time-resolved spectroscopy Tuning |
| Title | Sub-Picosecond Singlet Exciton Fission in Cyano-Substituted Diaryltetracenes |
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