高分散Ru/MMT催化剂的制备及其催化喹啉加氢性能

通过简单的离子交换法制备出高分散的蒙脱土（MMT）负载Ru催化剂,采用X射线衍射、X射线光电子能谱、程序升温还原和高分辨透射电子显微镜等手段对催化剂进行了表征.结果表明,金属Ru在蒙脱土层间高度分散,Ru的平均粒径约2nm.在喹啉加氢反应中,该催化剂显示出很高的反应活性和选择性.在2MPa和60℃的温和条件下,以水为溶剂时,Ru/MMT催化喹啉加氢生成1,2,3,4-四氢喹啉的选择性高于96.4%,喹啉转化率达99.2%.当温度升高到140℃、压力增加到3MPa时,不需要补加催化剂就可以将喹啉一步加氢生成十氢喹啉,选择性高达98.1%....

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Published in	Chinese journal of catalysis Vol. 31; no. 6; pp. 695 - 700
Main Author	周丽梅付海燕李强陈华李瑞祥李贤均
Format	Journal Article
Language	Chinese
Published	四川大学化学学院有机金属络合催化研究所,教育部绿色化学及技术重点实验室,四川,成都,610064 2010 西华师范大学化学化工学院,四川,南充,637002%四川大学化学学院有机金属络合催化研究所,教育部绿色化学及技术重点实验室,四川,成都,610064
Subjects	1,2,3,4-四氢喹啉加氢十氢喹啉喹啉多相催化蒙脱土钌多相催化 1,2,3,4-四氢喹啉蒙脱土加氢十氢喹啉喹啉钌
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ISSN	0253-9837 1872-2067
DOI	10.3724/SP.J.1088.2010.91206

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Abstract	通过简单的离子交换法制备出高分散的蒙脱土（MMT）负载Ru催化剂,采用X射线衍射、X射线光电子能谱、程序升温还原和高分辨透射电子显微镜等手段对催化剂进行了表征.结果表明,金属Ru在蒙脱土层间高度分散,Ru的平均粒径约2nm.在喹啉加氢反应中,该催化剂显示出很高的反应活性和选择性.在2MPa和60℃的温和条件下,以水为溶剂时,Ru/MMT催化喹啉加氢生成1,2,3,4-四氢喹啉的选择性高于96.4%,喹啉转化率达99.2%.当温度升高到140℃、压力增加到3MPa时,不需要补加催化剂就可以将喹啉一步加氢生成十氢喹啉,选择性高达98.1%.
AbstractList	通过简单的离子交换法制备出高分散的蒙脱土（MMT）负载Ru催化剂,采用X射线衍射、X射线光电子能谱、程序升温还原和高分辨透射电子显微镜等手段对催化剂进行了表征.结果表明,金属Ru在蒙脱土层间高度分散,Ru的平均粒径约2nm.在喹啉加氢反应中,该催化剂显示出很高的反应活性和选择性.在2MPa和60℃的温和条件下,以水为溶剂时,Ru/MMT催化喹啉加氢生成1,2,3,4-四氢喹啉的选择性高于96.4%,喹啉转化率达99.2%.当温度升高到140℃、压力增加到3MPa时,不需要补加催化剂就可以将喹啉一步加氢生成十氢喹啉,选择性高达98.1%. O643; 通过简单的离子交换法制备出高分散的蒙脱土(MMT)负载Ru催化剂,采用X射线衍射、X射线光电子能谱、程序升温还原和高分辨透射电子显微镜等手段对催化剂进行了表征,结果表明,金属Ru在蒙脱土层间高度分散,Ru的平均粒径约2 nm,在喹啉加氢反应中,该催化剂显示出很高的反应活性和选择性.在2 MPa和60 ℃的温和条件下,以水为溶剂时,Ru/MMT催化喹啉加氧生成1,2,3,4-四氢喹啉的选择性高于96.4%,喹啉转化率达99.2%.当温度升高到140 ℃、压力增加到3 MPa时,不需要补加催化剂就可以将喹啉一步加氢生成十氢喹啉,选择性高达98.1%.
Author	周丽梅付海燕李强陈华李瑞祥李贤均
AuthorAffiliation	四川大学化学学院有机金属络合催化研究所,教育部绿色化学及技术重点实验室,四川成都610064 西华师范大学化学化工学院,四川南充637002
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Author_FL	FU Haiyan LI Ruixiang LI Xianjun ZHOU Limei CHEN Hua LI Qiang
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Notes	decahydroquino-line O643 heterogeneous catalysis montmorillonite; ruthenium; heterogeneous catalysis; quinoline; hydrogenation; 1; 2; 3; 4-tetrahydroquinoline; decahydroquino-line 4-tetrahydroquinoline quinoline hydrogenation montmorillonite ruthenium 1 2 3 21-1195/O6
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Snippet	通过简单的离子交换法制备出高分散的蒙脱土（MMT）负载Ru催化剂,采用X射线衍射、X射线光电子能谱、程序升温还原和高分辨透射电子显微镜等手段对催化剂进行了表征.结果表明,... O643; 通过简单的离子交换法制备出高分散的蒙脱土(MMT)负载Ru催化剂,采用X射线衍射、X射线光电子能谱、程序升温还原和高分辨透射电子显微镜等手段对催化剂进行了表征,结果表...
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SubjectTerms	1,2,3,4-四氢喹啉加氢十氢喹啉喹啉多相催化蒙脱土钌
Title	高分散Ru/MMT催化剂的制备及其催化喹啉加氢性能
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