PPh3修饰介孔泡沫材料负载的Rh催化剂用于固定床氢甲酰化反应

CO插入反应，例如烯烃氢甲酰化反应，可以作为研究均相催化和多相催化之间关联的模型反应．均相催化氢甲酰化反应存在的主要问题是反应结束后催化剂难于同产物分离，而且所采用的有机溶剂大多对环境有污染．这些问题严重地阻碍了均相催化在工业生产中的广泛应用．到目前为止，人们的研究兴趣普遍集中在开发有效的均相固载化催化剂．由于多相催化剂的催化活性和选择性比均相催化剂低得多，...

Full description

Saved in:
Bibliographic Details
Published inChinese journal of catalysis Vol. 27; no. 1; pp. 1 - 3
Main Author 严丽 丁云杰 朱何俊 尹红梅 焦桂平 赵东元 林励吾
Format Journal Article
LanguageChinese
Published 中国科学院大连化学物理研究所,辽宁,大连,116023 2006
中国科学院研究生院,北京,100049%中国科学院大连化学物理研究所,辽宁,大连,116023%复旦大学化学系,上海,200433
Subjects
三苯基膦
丙烯
介孔泡沫材料
氢甲酰化
负载型催化剂
铑
铑
介孔泡沫材料
三苯基膦
负载型催化剂
氢甲酰化
丙烯
Online AccessGet full text
ISSN0253-9837
1872-2067
DOI10.3321/j.issn:0253-9837.2006.01.001

Cover

Abstract CO插入反应，例如烯烃氢甲酰化反应，可以作为研究均相催化和多相催化之间关联的模型反应．均相催化氢甲酰化反应存在的主要问题是反应结束后催化剂难于同产物分离，而且所采用的有机溶剂大多对环境有污染．这些问题严重地阻碍了均相催化在工业生产中的广泛应用．到目前为止，人们的研究兴趣普遍集中在开发有效的均相固载化催化剂．由于多相催化剂的催化活性和选择性比均相催化剂低得多，
AbstractList O643
CO插入反应，例如烯烃氢甲酰化反应，可以作为研究均相催化和多相催化之间关联的模型反应．均相催化氢甲酰化反应存在的主要问题是反应结束后催化剂难于同产物分离，而且所采用的有机溶剂大多对环境有污染．这些问题严重地阻碍了均相催化在工业生产中的广泛应用．到目前为止，人们的研究兴趣普遍集中在开发有效的均相固载化催化剂．由于多相催化剂的催化活性和选择性比均相催化剂低得多，
Author 严丽 丁云杰 朱何俊 尹红梅 焦桂平 赵东元 林励吾
AuthorAffiliation 中国科学院大连化学物理研究所,辽宁大连116023 中国科学院研究生院,北京100049 复旦大学化学系,上海200433
AuthorAffiliation_xml – name: 中国科学院大连化学物理研究所,辽宁,大连,116023;中国科学院研究生院,北京,100049%中国科学院大连化学物理研究所,辽宁,大连,116023%复旦大学化学系,上海,200433
Author_FL YAN Li
YIN Hongmei
ZHU Hejun
LIN Liwu
JIAO Guiping
ZHAO Dongyuan
DING Yunjie
Author_FL_xml – sequence: 1
  fullname: YAN Li
– sequence: 2
  fullname: DING Yunjie
– sequence: 3
  fullname: ZHU Hejun
– sequence: 4
  fullname: YIN Hongmei
– sequence: 5
  fullname: JIAO Guiping
– sequence: 6
  fullname: ZHAO Dongyuan
– sequence: 7
  fullname: LIN Liwu
Author_xml – sequence: 1
  fullname: 严丽 丁云杰 朱何俊 尹红梅 焦桂平 赵东元 林励吾
BookMark eNo9kMtKw0AARQepYFv9CXHjInEezUziToovKFil-zKZJE1qSdFQdF104dtFKFgRURAEtZTqKlL8mU7a_oUpFVd3cQ_3wsmAlF_3bQCWEFQJwWilqnpB4K9CrBHF0AlTMYRUhUiFEM2ANNIZVjCkLAXS_8wcyARBFUJiMETTYLdYdMngpzN-6Q6-L-RHGH8-xb23-OE2bt2Nvh5H_f6wfbLnyua7vGzJs-YwfB1E1_I-kp22jM7j7vMw7I1Pu5P25kpG4TyYdXgtsBf-MgtKG-ul_JZS2Nnczq8VFEERUmwhNCpMZAqRc5hhCptjipllWUijLEeQxZkuLMMxdIGpCQnROeQiZ1qMQYdaJAuWp7NH3He4XylX641DPzksi4bnNvixOZEBUaIiYRenrHDrfuXAS2iTi33Hq9lljDA2sKaTXxmnfmc
ClassificationCodes O643
ContentType Journal Article
Copyright Copyright © Wanfang Data Co. Ltd. All Rights Reserved.
Copyright_xml – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved.
DBID 2RA
92L
CQIGP
W94
~WA
2B.
4A8
92I
93N
PSX
TCJ
DOI 10.3321/j.issn:0253-9837.2006.01.001
DatabaseName 维普期刊资源整合服务平台
中文科技期刊数据库-CALIS站点
维普中文期刊数据库
中文科技期刊数据库-自然科学
中文科技期刊数据库- 镜像站点
Wanfang Data Journals - Hong Kong
WANFANG Data Centre
Wanfang Data Journals
万方数据期刊 - 香港版
China Online Journals (COJ)
China Online Journals (COJ)
DatabaseTitleList

DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
DocumentTitleAlternate Continuous Fixed-Bed Gas-Phase Hydroformylation over PPh3-Modified Mesostructured Cellular Foam-Supported Rh Catalyst
DocumentTitle_FL Continuous Fixed-Bed Gas-Phase Hydroformylation over PPh3-Modified Mesostructured Cellular Foam-Supported Rh Catalyst
EISSN 1872-2067
EndPage 3
ExternalDocumentID cuihuaxb200601001
21229258
GrantInformation_xml – fundername: 中国科学院资助项目; 科技部科研项目
  funderid: (20073046); (G2003CB615803)
GroupedDBID --K
--M
-02
-SB
.~1
0R~
1B1
1~.
1~5
29B
2B.
2C.
2RA
4.4
457
4G.
5GY
5VS
5XA
5XC
7-5
71M
8P~
92E
92I
92L
AABNK
AACTN
AAEDT
AAIAV
AAIKJ
AAKOC
AALMO
AALRI
AAOAW
AAQFI
AAXUO
ABMAC
ABNUV
ABPIF
ABXDB
ABYKQ
ACDAQ
ACGFS
ACRLP
ADALY
ADBBV
ADEWK
ADEZE
AEBSH
AEKER
AENEX
AFKWA
AFTJW
AGHFR
AGUBO
AGYEJ
AHPOS
AIEXJ
AIKHN
AITUG
AJBFU
AJOXV
AKURH
ALMA_UNASSIGNED_HOLDINGS
AMFUW
AMRAJ
AXJTR
BKOJK
BLXMC
CAJEB
CAJUS
CCEZO
CDRFL
CDYEO
CLXHM
CQIGP
CS3
CW9
DU5
EBS
EFJIC
EJD
ENUVR
EO9
EP2
EP3
FDB
FEDTE
FIRID
FNPLU
FYGXN
GBLVA
HVGLF
HZ~
IPNFZ
J1W
KOM
M41
MO0
N9A
O-L
O9-
OAUVE
OZT
P-8
P-9
PC.
Q--
Q38
RIG
ROL
SDC
SDF
SDG
SES
SPC
SPCBC
SSG
SSZ
T5K
TCJ
TGP
U1G
U5L
W94
~G-
~WA
-S~
4A8
93N
AAEDW
AATTM
AAXKI
AAYWO
ABJNI
ABWVN
ACRPL
ADMUD
ADNMO
AEIPS
AFXIZ
AGCQF
AGRNS
AIIUN
AKRWK
ANKPU
APXCP
BNPGV
PSX
SSH
UY8
ID FETCH-LOGICAL-c611-ecc56cb1bcc4f79bcea2627ddd1567431da78cd9f98c26b0338a0ac4bd770f6d3
ISSN 0253-9837
IngestDate Thu May 29 04:06:06 EDT 2025
Fri Nov 25 11:14:09 EST 2022
IsPeerReviewed true
IsScholarly true
Issue 1
Keywords 铑
介孔泡沫材料
三苯基膦
负载型催化剂
氢甲酰化
丙烯
Language Chinese
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c611-ecc56cb1bcc4f79bcea2627ddd1567431da78cd9f98c26b0338a0ac4bd770f6d3
Notes propylene
O643
triphenyl phosphine; rhodium ; mesostructured cellular foam; supported catalyst ; propylene; hydroformylation
supported catalyst
triphenyl phosphine
hydroformylation
mesostructured cellular foam
21-1195/O6
rhodium
PageCount 3
ParticipantIDs wanfang_journals_cuihuaxb200601001
chongqing_backfile_21229258
PublicationCentury 2000
PublicationDate 2006
PublicationDateYYYYMMDD 2006-01-01
PublicationDate_xml – year: 2006
  text: 2006
PublicationDecade 2000
PublicationTitle Chinese journal of catalysis
PublicationTitleAlternate Chinese Journal of Catalysis
PublicationTitle_FL CHINESE JOURNAL OF CATALYSIS
PublicationYear 2006
Publisher 中国科学院大连化学物理研究所,辽宁,大连,116023
中国科学院研究生院,北京,100049%中国科学院大连化学物理研究所,辽宁,大连,116023%复旦大学化学系,上海,200433
Publisher_xml – name: 中国科学院大连化学物理研究所,辽宁,大连,116023
– name: 中国科学院研究生院,北京,100049%中国科学院大连化学物理研究所,辽宁,大连,116023%复旦大学化学系,上海,200433
SSID ssj0039716
ssib002258342
ssib001104832
ssib050169534
ssib051367559
Score 1.7515652
Snippet CO插入反应，例如烯烃氢甲酰化反应，可以作为研究均相催化和多相催化之间关联的模型反应．均相催化氢甲酰化反应存在的主要问题是反应结束后催化剂难于同产物分离，而且所...
O643
SourceID wanfang
chongqing
SourceType Aggregation Database
Publisher
StartPage 1
SubjectTerms 三苯基膦
丙烯
介孔泡沫材料
氢甲酰化
负载型催化剂
铑
Title PPh3修饰介孔泡沫材料负载的Rh催化剂用于固定床氢甲酰化反应
URI http://lib.cqvip.com/qk/93027X/20061/21229258.html
https://d.wanfangdata.com.cn/periodical/cuihuaxb200601001
Volume 27
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
journalDatabaseRights – providerCode: PRVESC
  databaseName: Elsevier SD Complete Freedom Collection [SCCMFC]
  customDbUrl:
  eissn: 1872-2067
  dateEnd: 99991231
  omitProxy: true
  ssIdentifier: ssj0039716
  issn: 0253-9837
  databaseCode: ACRLP
  dateStart: 20060101
  isFulltext: true
  titleUrlDefault: https://www.sciencedirect.com
  providerName: Elsevier
– providerCode: PRVESC
  databaseName: Elsevier SD Freedom Collection
  customDbUrl:
  eissn: 1872-2067
  dateEnd: 99991231
  omitProxy: true
  ssIdentifier: ssj0039716
  issn: 0253-9837
  databaseCode: .~1
  dateStart: 20060101
  isFulltext: true
  titleUrlDefault: https://www.sciencedirect.com
  providerName: Elsevier
– providerCode: PRVESC
  databaseName: ScienceDirect Freedom Collection Journals
  customDbUrl:
  eissn: 1872-2067
  dateEnd: 99991231
  omitProxy: true
  ssIdentifier: ssj0039716
  issn: 0253-9837
  databaseCode: AIKHN
  dateStart: 20060101
  isFulltext: true
  titleUrlDefault: https://www.sciencedirect.com
  providerName: Elsevier
– providerCode: PRVLSH
  databaseName: Elsevier Journals
  customDbUrl:
  mediaType: online
  eissn: 1872-2067
  dateEnd: 99991231
  omitProxy: true
  ssIdentifier: ssj0039716
  issn: 0253-9837
  databaseCode: AKRWK
  dateStart: 20060101
  isFulltext: true
  providerName: Library Specific Holdings
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnR1da9RAMNQK6ov4ibUqRbqPqcnma9e3TS5HEZRaTuhbSTaXnghX1B5IH3wo-uC3D0fBioiCIKilVJ9Oij_Cv9Bc23_hzCa5O_UeqhCWyezu7OzMJjvZzcxq2iR8ISdmnHI9opDYScr0WKZUT6UBX9gykZZyCrt6zZ2-YV-Zc-ZGDvwc-GuptRRPyeWhfiX_o1XAgV7RS_YfNNsjCgiAQb-QgoYh3ZeOZ2YaFglt4leJCEnIiXCIbyiMT5hPQoeICuE2CV3iW0SYCqBE-AhwyDIUABcnISO-TXhVARW8Qo9wQZg920BKDOoFCgiwBgIckVjKJoKpZqF4iFncRxjbD5EGAJglVPsGEWUt4AW4ZjnXg5SrhFWKWvnpxKUBPZwT6KVwkTg0IZxyECmOGAolB_zKHznMLJjmZiEQ3-gXAURA_LwIiMopJM1Ev4hi3OfYG6CC3XIxzY8H6i-m9AZ-yVGllJESsvAUA71ucFQHEgOMjbmokSrh4bA-e6gGoVgAbTKFEYZSuod4P5cLx19aaKBIhapdpRuQAA2GNEQD03SN3Ee7mCeoY-mc5bFzykktD7jw28Obz1DmgKljDZtDLYvmcygSh_HeI1_s3Jm4ede3Hnr_dMrWzUYruhdTFeLHQJ_KgxQXyWCSmbo_GGMQTzEY2MqnDrPs3r2D4YGcfsxCB2MKqq3z3LyyMOaZWjgt2DqkTRZcX8p5vjyUY4yd0lhsLtwGi1A56DXTqLkwYEvWjmlHi4_ACZE_0ce1keXGCe1wUJ69eFK7jk_29o_1vQ8b29-fZF_a3a_vupufum9edldf7X57u7u1tbP2YLaRrXzOnq5mj1Z22h-3O8-z151sfS3rPO5uvN9pb-493MDcF8-yTvuUVquGtWBaLw4_0aVrmjq8WR1XxmYspZ16PJb1iLrUS5LEdNBvyEwij8mEp5xJ6saGZbHIiKQdJ55npG5indZGm4vN-hltwgEL1LDTSNny9ciOcEnHrddtHpmJy-SYNt6TDNjO8hZGhJsHk5ZyUM2YdrGQ1Xzx5rs7_5eqz-6n0Lh2pL9-eU4bXbrTqp8Hi34pvqBGyC8uPMIJ
linkProvider Elsevier
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=PPh3%E4%BF%AE%E9%A5%B0%E4%BB%8B%E5%AD%94%E6%B3%A1%E6%B2%AB%E6%9D%90%E6%96%99%E8%B4%9F%E8%BD%BD%E7%9A%84Rh%E5%82%AC%E5%8C%96%E5%89%82%E7%94%A8%E4%BA%8E%E5%9B%BA%E5%AE%9A%E5%BA%8A%E6%B0%A2%E7%94%B2%E9%85%B0%E5%8C%96%E5%8F%8D%E5%BA%94&rft.jtitle=%E5%82%AC%E5%8C%96%E5%AD%A6%E6%8A%A5&rft.au=%E4%B8%A5%E4%B8%BD&rft.au=%E4%B8%81%E4%BA%91%E6%9D%B0&rft.au=%E6%9C%B1%E4%BD%95%E4%BF%8A&rft.au=%E5%B0%B9%E7%BA%A2%E6%A2%85&rft.date=2006&rft.pub=%E4%B8%AD%E5%9B%BD%E7%A7%91%E5%AD%A6%E9%99%A2%E5%A4%A7%E8%BF%9E%E5%8C%96%E5%AD%A6%E7%89%A9%E7%90%86%E7%A0%94%E7%A9%B6%E6%89%80%2C%E8%BE%BD%E5%AE%81%2C%E5%A4%A7%E8%BF%9E%2C116023&rft.issn=0253-9837&rft.volume=27&rft.issue=1&rft.spage=1&rft.epage=3&rft_id=info:doi/10.3321%2Fj.issn%3A0253-9837.2006.01.001&rft.externalDocID=cuihuaxb200601001
thumbnail_s http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F93027X%2F93027X.jpg
http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fcuihuaxb%2Fcuihuaxb.jpg