环境土壤样品中^99Tc的分析方法研究进展

随着核能的开发及核医学诊断的发展,^99Tc的研究日益受到重视。^99Tc具有半衰期长、裂变产额高和迁移性强等特点,在核废物的地质处置、环境安全评价及生物效应方面倍受关注,准确测定环境土壤样品中^99Tc的含量显得至关重要。本文在文献调研的基础上较详细总结了Tc的化学性质,并对^99Tc分析流程中样品的预处理、化学分离纯化、制源及测量等过程中涉及的主要方法进行了综述,指出了现今分析方法中存在的主要瓶颈,并对环境样品中^99Tc的分析做了展望。...

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Published in核化学与放射化学 Vol. 39; no. 5; pp. 321 - 335
Main Author 孙雪杰 李润 杨军强 史克亮 吴王锁
Format Journal Article
LanguageChinese
Published 兰州大学核科学与技术学院放射化学与核环境研究所,甘肃兰州,730000%兰州大学核科学与技术学院放射化学与核环境研究所,甘肃兰州730000 2017
兰州大学特殊功能材料与结构设计教育部重点实验室,甘肃兰州 730000
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ISSN0253-9950
DOI10.7538/hhx.2017.39.05.0321

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Abstract 随着核能的开发及核医学诊断的发展,^99Tc的研究日益受到重视。^99Tc具有半衰期长、裂变产额高和迁移性强等特点,在核废物的地质处置、环境安全评价及生物效应方面倍受关注,准确测定环境土壤样品中^99Tc的含量显得至关重要。本文在文献调研的基础上较详细总结了Tc的化学性质,并对^99Tc分析流程中样品的预处理、化学分离纯化、制源及测量等过程中涉及的主要方法进行了综述,指出了现今分析方法中存在的主要瓶颈,并对环境样品中^99Tc的分析做了展望。
AbstractList 随着核能的开发及核医学诊断的发展,^99Tc的研究日益受到重视。^99Tc具有半衰期长、裂变产额高和迁移性强等特点,在核废物的地质处置、环境安全评价及生物效应方面倍受关注,准确测定环境土壤样品中^99Tc的含量显得至关重要。本文在文献调研的基础上较详细总结了Tc的化学性质,并对^99Tc分析流程中样品的预处理、化学分离纯化、制源及测量等过程中涉及的主要方法进行了综述,指出了现今分析方法中存在的主要瓶颈,并对环境样品中^99Tc的分析做了展望。
TL277; 随着核能的开发及核医学诊断的发展,99Tc的研究日益受到重视.99Tc具有半衰期长、裂变产额高和迁移性强等特点,在核废物的地质处置、环境安全评价及生物效应方面倍受关注,准确测定环境土壤样品中99Tc的含量显得至关重要.本文在文献调研的基础上较详细总结了Tc的化学性质,并对99Tc分析流程中样品的预处理、化学分离纯化、制源及测量等过程中涉及的主要方法进行了综述,指出了现今分析方法中存在的主要瓶颈,并对环境样品中99Tc的分析做了展望.
Abstract_FL With the exploiting of nuclear energy and the development of nuclear medical diagnosis,the research of 99Tc is becoming more and more important.Because of the long halflife,high fission yield,and high mobility,99Tc has caused widely attention in disposing nuclear waste,environmental safety assessment and biological effect,consequently it is essential to determine the accurate concentration of 99Tc in environmental soil samples.This article reviews the chemical properties of Tc and compares the developed analytical methods of 99Tc in environmental samples.The procedures contain four steps:sample pre-treatment,chemical separation and purification,source preparation and 99Tc measurement.The work illustrates the major bottlenecks of analytical methods reported and makes the prospect of 99Tc analysis in the future.
Author 孙雪杰 李润 杨军强 史克亮 吴王锁
AuthorAffiliation 兰州大学核科学与技术学院放射化学与核环境研究所,甘肃兰州730000 兰州大学特殊功能材料与结构设计教育部重点实验室,甘肃兰州730000
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Author_FL SHI Ke-liang
LI Run
SUN Xue-jie
YANG Jun-qiang
WU Wang-suo
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DocumentTitleAlternate Advances in Analytical Methods of ^99Tc in Environmental Soil Samples
DocumentTitle_FL Advances in Analytical Methods of 99Tc in Environmental Soil Samples
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Keywords 99Tc
review
chemistry properties
化学性质
environmental soil sample
综述
环境土壤样品
analytical procedures
分析流程
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Notes With the exploiting of nuclear energy and the development of nuclear medical diagnosis,the research of ^99Tc is becoming more and more important.Because of the long halflife,high fission yield,and high mobility,^99Tc has caused widely attention in disposing nuclear waste,environmental safety assessment and biological effect,consequently it is essential to determine the accurate concentration of ^99Tc in environmental soil samples.This article reviews the chemical properties of Tc and compares the developed analytical methods of ^99Tc in environmental samples.The procedures contain four steps:sample pre-treatment,chemical separation and purification,source preparation and ^99Tc measurement.The work illustrates the major bottlenecks of analytical methods reported and makes the prospect of ^99Tc analysis in the future.
11-2045/TL
99Tc ; environmental soil sample; chemistry properties; analytical procedures; review
SUN Xue-jie1,LI Run1,YANG Jun-qiang1,SHI Ke-liang1,2,WU Wang-suo1,2(1. Radiochemistry Lab? School of N
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PublicationTitle 核化学与放射化学
PublicationTitleAlternate Journal of Nuclear and Radiochemistry
PublicationTitle_FL Journal of Nuclear and Radiochemistry
PublicationYear 2017
Publisher 兰州大学核科学与技术学院放射化学与核环境研究所,甘肃兰州,730000%兰州大学核科学与技术学院放射化学与核环境研究所,甘肃兰州730000
兰州大学特殊功能材料与结构设计教育部重点实验室,甘肃兰州 730000
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Snippet 随着核能的开发及核医学诊断的发展,^99Tc的研究日益受到重视。^99Tc具有半衰期长、裂变产额高和迁移性强等特点,在核废物的地质处置、环境安全评价及生物效应方面倍受关注,准...
TL277; 随着核能的开发及核医学诊断的发展,99Tc的研究日益受到重视.99Tc具有半衰期长、裂变产额高和迁移性强等特点,在核废物的地质处置、环境安全评价及生物效应方面倍受关...
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SubjectTerms 99Tc
分析流程
化学性质
环境土壤样品
综述
Title 环境土壤样品中^99Tc的分析方法研究进展
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