Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework
Metal–organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensin...
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Published in | Nature communications Vol. 8; no. 1; pp. 2139 - 8 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
London
Nature Publishing Group UK
15.12.2017
Nature Publishing Group Nature Portfolio |
Subjects | |
Online Access | Get full text |
ISSN | 2041-1723 2041-1723 |
DOI | 10.1038/s41467-017-02215-7 |
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Abstract | Metal–organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semiconductivity and its control is still rare. The use and fabrication of electronic devices with MOF-based components has not been widely explored, despite significant progress of these components made in recent years. Here we report the synthesis and properties of a new highly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an efficient electrical semiconductor and has a broad absorption spectrum, from 300 to 2500 nm. Its semiconductivity was determined by direct voltage bias using a four-point device, and it features a wavelength dependant photoconductive–photoresistive dual behaviour, with a very high responsivity of 2.5 × 10
5
A W
−1
.
Photoactive and semiconducting metal-organic frameworks are desirable for electrical and photoelectrical devices, but remain rare. Here Demets and co-workers design a naphthalene diimide and cobalt based MOF with anisotropic electrical semiconductivity and a high responsivity of 2.5 × 10
5
A W
−1
. |
---|---|
AbstractList | Photoactive and semiconducting metal-organic frameworks are desirable for electrical and photoelectrical devices, but remain rare. Here Demets and co-workers design a naphthalene diimide and cobalt based MOF with anisotropic electrical semiconductivity and a high responsivity of 2.5 × 105 A W−1. Metal–organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semiconductivity and its control is still rare. The use and fabrication of electronic devices with MOF-based components has not been widely explored, despite significant progress of these components made in recent years. Here we report the synthesis and properties of a new highly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an efficient electrical semiconductor and has a broad absorption spectrum, from 300 to 2500 nm. Its semiconductivity was determined by direct voltage bias using a four-point device, and it features a wavelength dependant photoconductive–photoresistive dual behaviour, with a very high responsivity of 2.5 × 10 5 A W −1 . Photoactive and semiconducting metal-organic frameworks are desirable for electrical and photoelectrical devices, but remain rare. Here Demets and co-workers design a naphthalene diimide and cobalt based MOF with anisotropic electrical semiconductivity and a high responsivity of 2.5 × 10 5 A W −1 . Metal–organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semiconductivity and its control is still rare. The use and fabrication of electronic devices with MOF-based components has not been widely explored, despite significant progress of these components made in recent years. Here we report the synthesis and properties of a new highly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an efficient electrical semiconductor and has a broad absorption spectrum, from 300 to 2500 nm. Its semiconductivity was determined by direct voltage bias using a four-point device, and it features a wavelength dependant photoconductive–photoresistive dual behaviour, with a very high responsivity of 2.5 × 105 A W−1. Metal–organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semiconductivity and its control is still rare. The use and fabrication of electronic devices with MOF-based components has not been widely explored, despite significant progress of these components made in recent years. Here we report the synthesis and properties of a new highly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an efficient electrical semiconductor and has a broad absorption spectrum, from 300 to 2500 nm. Its semiconductivity was determined by direct voltage bias using a four-point device, and it features a wavelength dependant photoconductive–photoresistive dual behaviour, with a very high responsivity of 2.5 × 10 5 A W −1 . Metal-organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semiconductivity and its control is still rare. The use and fabrication of electronic devices with MOF-based components has not been widely explored, despite significant progress of these components made in recent years. Here we report the synthesis and properties of a new highly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an efficient electrical semiconductor and has a broad absorption spectrum, from 300 to 2500 nm. Its semiconductivity was determined by direct voltage bias using a four-point device, and it features a wavelength dependant photoconductive-photoresistive dual behaviour, with a very high responsivity of 2.5 × 105 A W-1.Metal-organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semiconductivity and its control is still rare. The use and fabrication of electronic devices with MOF-based components has not been widely explored, despite significant progress of these components made in recent years. Here we report the synthesis and properties of a new highly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an efficient electrical semiconductor and has a broad absorption spectrum, from 300 to 2500 nm. Its semiconductivity was determined by direct voltage bias using a four-point device, and it features a wavelength dependant photoconductive-photoresistive dual behaviour, with a very high responsivity of 2.5 × 105 A W-1. Metal-organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components according to desired applications. Despite the wide interest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and drug delivery, electrical semiconductivity and its control is still rare. The use and fabrication of electronic devices with MOF-based components has not been widely explored, despite significant progress of these components made in recent years. Here we report the synthesis and properties of a new highly crystalline, electrochemically active, cobalt and naphthalene diimide-based MOF that is an efficient electrical semiconductor and has a broad absorption spectrum, from 300 to 2500 nm. Its semiconductivity was determined by direct voltage bias using a four-point device, and it features a wavelength dependant photoconductive-photoresistive dual behaviour, with a very high responsivity of 2.5 × 10 A W . |
ArticleNumber | 2139 |
Author | Silva, S. Ravi P. Demets, Grégoire Jean-François Cox, David C. Walton, Richard I. Clarkson, Guy J. Imalka Jayawardena, K. D. G. Le-Quang, Long Chauvin, Jerôme Castaldelli, Evandro |
Author_xml | – sequence: 1 givenname: Evandro orcidid: 0000-0003-2946-8697 surname: Castaldelli fullname: Castaldelli, Evandro email: evandro.castaldelli@gmail.com organization: Departamento de Química, FFCLRP, Universidade de São Paulo, Advanced Technology Institute, University of Surrey – sequence: 2 givenname: K. D. G. surname: Imalka Jayawardena fullname: Imalka Jayawardena, K. D. G. organization: Advanced Technology Institute, University of Surrey – sequence: 3 givenname: David C. surname: Cox fullname: Cox, David C. organization: Advanced Technology Institute, University of Surrey – sequence: 4 givenname: Guy J. orcidid: 0000-0003-3076-3191 surname: Clarkson fullname: Clarkson, Guy J. organization: Department of Chemistry, University of Warwick – sequence: 5 givenname: Richard I. surname: Walton fullname: Walton, Richard I. organization: Department of Chemistry, University of Warwick – sequence: 6 givenname: Long surname: Le-Quang fullname: Le-Quang, Long organization: CIRE/DCM Université de Grenoble Alpes – sequence: 7 givenname: Jerôme surname: Chauvin fullname: Chauvin, Jerôme organization: CIRE/DCM Université de Grenoble Alpes – sequence: 8 givenname: S. Ravi P. orcidid: 0000-0002-0356-1319 surname: Silva fullname: Silva, S. Ravi P. email: s.silva@surrey.ac.uk organization: Advanced Technology Institute, University of Surrey – sequence: 9 givenname: Grégoire Jean-François orcidid: 0000-0001-7152-1266 surname: Demets fullname: Demets, Grégoire Jean-François email: greg@usp.br organization: Departamento de Química, FFCLRP, Universidade de São Paulo |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29247248$$D View this record in MEDLINE/PubMed |
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Snippet | Metal–organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components... Metal-organic frameworks (MOFs) have emerged as an exciting class of porous materials that can be structurally designed by choosing particular components... Photoactive and semiconducting metal-organic frameworks are desirable for electrical and photoelectrical devices, but remain rare. Here Demets and co-workers... |
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SubjectTerms | 639/301/1005/1007 639/638/298/921 639/638/911 Absorption spectra Catalysis Cobalt Diimide Drug delivery Drug delivery systems Electronic devices Electronic equipment Fabrication Humanities and Social Sciences Metal-organic frameworks multidisciplinary Naphthalene Porous materials Science Science (multidisciplinary) Semiconduction Semiconductivity |
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Title | Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework |
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