纳米金刚石改性LLDPE的非等温结晶动力学
采用X射线衍射（XRD）、偏光显微镜（POM）以及差示扫描量热（DSC）法,考察了纳米金刚石（Nano-diamond）对线型低密度聚乙烯（LLDPE）的结晶形态以及非等温结晶行为的影响。通过Jeziorny法和莫志深法研究了复合材料的非等温结晶动力学,并利用Kissinger方程计算了LLDPE/Nano-diamond复合材料的非等温结晶活化能。结果表明：Nano-diamond是一种有效的成核剂,为LLDPE结晶提供了更多的活化晶核,起到了异相成核的作用,既提高了LLDPE的结晶起始温度To、结晶峰值温度Tp和结晶速率，又降低了球晶的尺寸，使得球晶的分布更为均匀致密；添加Nano-dia...
Saved in:
| Published in | 航空材料学报 Vol. 34; no. 5; pp. 55 - 62 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
河南理工大学材料科学与工程学院,河南焦作,454000
2014
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1005-5053 |
| DOI | 10.11868/j.issn.1005-5053.2014.5.009 |
Cover
| Abstract | 采用X射线衍射（XRD）、偏光显微镜（POM）以及差示扫描量热（DSC）法,考察了纳米金刚石（Nano-diamond）对线型低密度聚乙烯（LLDPE）的结晶形态以及非等温结晶行为的影响。通过Jeziorny法和莫志深法研究了复合材料的非等温结晶动力学,并利用Kissinger方程计算了LLDPE/Nano-diamond复合材料的非等温结晶活化能。结果表明：Nano-diamond是一种有效的成核剂,为LLDPE结晶提供了更多的活化晶核,起到了异相成核的作用,既提高了LLDPE的结晶起始温度To、结晶峰值温度Tp和结晶速率，又降低了球晶的尺寸，使得球晶的分布更为均匀致密；添加Nano-diamond使得复合材料的结晶迁移活化能降低，当Nano-diamond含量为1％时，复合材料结晶活化能达到最小值。 |
|---|---|
| AbstractList | TQ320.1%TQ315.14; 采用X射线衍射(XRD)、偏光显微镜(POM)以及差示扫描量热(DSC)法,考察了纳米金刚石(Nano-diamond)对线型低密度聚乙烯(LLDPE)的结晶形态以及非等温结晶行为的影响.通过Jeziorny法和莫志深法研究了复合材料的非等温结晶动力学,并利用Kissinger方程计算了LLDPE/ Nano-diamond复合材料的非等温结晶活化能.结果表明:Nano-diamond是一种有效的成核剂,为LLDPE结晶提供了更多的活化晶核,起到了异相成核的作用,既提高了LLDPE的结晶起始温度T.、结晶峰值温度Tp和结晶速率,又降低了球晶的尺寸,使得球晶的分布更为均匀致密;添加Nano-diamond使得复合材料的结晶迁移活化能降低,当Nano-diamond含量为1％时,复合材料结晶活化能达到最小值. 采用X射线衍射（XRD）、偏光显微镜（POM）以及差示扫描量热（DSC）法,考察了纳米金刚石（Nano-diamond）对线型低密度聚乙烯（LLDPE）的结晶形态以及非等温结晶行为的影响。通过Jeziorny法和莫志深法研究了复合材料的非等温结晶动力学,并利用Kissinger方程计算了LLDPE/Nano-diamond复合材料的非等温结晶活化能。结果表明：Nano-diamond是一种有效的成核剂,为LLDPE结晶提供了更多的活化晶核,起到了异相成核的作用,既提高了LLDPE的结晶起始温度To、结晶峰值温度Tp和结晶速率，又降低了球晶的尺寸，使得球晶的分布更为均匀致密；添加Nano-diamond使得复合材料的结晶迁移活化能降低，当Nano-diamond含量为1％时，复合材料结晶活化能达到最小值。 |
| Author | 曹新鑫 罗四海 王优 何小芳 |
| AuthorAffiliation | 河南理工大学材料科学与工程学院,河南焦作454000 |
| AuthorAffiliation_xml | – name: 河南理工大学材料科学与工程学院,河南焦作,454000 |
| Author_FL | LUO Si-hai HE Xiao-fang CAO Xin-xin WANG You |
| Author_FL_xml | – sequence: 1 fullname: CAO Xin-xin – sequence: 2 fullname: LUO Si-hai – sequence: 3 fullname: WANG You – sequence: 4 fullname: HE Xiao-fang |
| Author_xml | – sequence: 1 fullname: 曹新鑫 罗四海 王优 何小芳 |
| BookMark | eNo9j8tKw0AYhWdRwVr7EiK4Svz_SWY6s5RaLxDQRfdl0k7a1DrRBlF3LoRqd6IbK-rOy6ILKYiX50lC38JIxdWBw8e5LJCCiYwmZBnBRhRcrHbtMI6NjQDMYsAcmwK6NrMBZIEU_-15Uo7j0AdApFIwUSQs-5pkb5Pp4Cq5GGWPk_TmMz179rz13Vo2Op_eP2Tjy_TjNfu-Tm_fk-FLMrxLxk-LZC5QvViX_7RE6hu1enXL8nY2t6trntVkUlqa-hpYy6fabQU-6orDJVVOy6USFFKueAColczHoJIqUCiFlkAlOpwJIZ0SWZnFHisTKNNudKOjvskLG529Zu_E_z0JLP-Yk0szstmJTPswzNmDfriv-qcNzilHUZHM-QHQ92cN |
| ClassificationCodes | TQ320.1%TQ315.14 |
| ContentType | Journal Article |
| Copyright | Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | 2RA 92L CQIGP W92 ~WA 2B. 4A8 92I 93N PSX TCJ |
| DOI | 10.11868/j.issn.1005-5053.2014.5.009 |
| DatabaseName | 维普期刊资源整合服务平台 中文科技期刊数据库-CALIS站点 中文科技期刊数据库-7.0平台 中文科技期刊数据库-工程技术 中文科技期刊数据库- 镜像站点 Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| DocumentTitleAlternate | Nonisothermal Crystallization Kinetics of Polypropylene Nano-diamond as Fillers |
| DocumentTitle_FL | Nonisothermal Crystallization Kinetics of Polypropylene Nano-diamond as Fillers |
| EndPage | 62 |
| ExternalDocumentID | hkclxb201405009 662618795 |
| GrantInformation_xml | – fundername: 河南省安全生产科技发展计划; 河南理工大学博士基金; 国家级大学生创新创业训练计划项目 funderid: (H12-089); (B2013-010); (201310460038) |
| GroupedDBID | -03 2B. 2C0 2RA 5VS 5XA 5XC 5XD 92H 92I 92L ACGFS ALMA_UNASSIGNED_HOLDINGS CCEZO CEKLB CQIGP CW9 FIJ GROUPED_DOAJ IPNFZ RIG TCJ TGT U1G U5L U5M W92 ~WA 4A8 93N ABJNI ADMLS PSX |
| ID | FETCH-LOGICAL-c599-e2be05db2e4dfb1e73692a3d4290a126a6f01ea91121a9afa198e902913658893 |
| ISSN | 1005-5053 |
| IngestDate | Thu May 29 04:00:12 EDT 2025 Wed Feb 14 10:36:34 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 5 |
| Keywords | 非等温结晶 composites nucleating agent 纳米金刚石 Nano-diamond 成核剂 复合材料 linear low density polyethylene 线型低密度聚乙烯 non-isothermal crystallization |
| Language | Chinese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c599-e2be05db2e4dfb1e73692a3d4290a126a6f01ea91121a9afa198e902913658893 |
| Notes | CAO Xin-xin, LUO Si-hai, WANG You, HE Xiao-fang （ School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, Henan China） linear low density polyethylene; Nano-diamond ; non-isothermal crystallization ; nucleating agent; composites 11-3159/V Effeets of Nano-diamond composites on the crystal morphology and non-isothermal crystallization of linear low density polyethylene （LLLDPE） were investigated by XRD, polarization microscope（POM） and differential scanning calorimetry（DSC）. The Jeziorny and Mo methods were applied to the analysis of the non-isothermal crystallization kinetics of LLDPE and LLDPE/ Nano-diamond composites, and the activation energy （AE） based on Kissinger method was evaluated. The results show that Nano-diamond is an ef- fective nucleating agent, provides more activated nuclei for the crystallization of LLDPE, plays a role in heterogeneous nucleation, and enhances crystallization onset temperature（ To ） , crystallization peak temperature（ Tp ） and crystallization r |
| PageCount | 8 |
| ParticipantIDs | wanfang_journals_hkclxb201405009 chongqing_primary_662618795 |
| PublicationCentury | 2000 |
| PublicationDate | 2014 |
| PublicationDateYYYYMMDD | 2014-01-01 |
| PublicationDate_xml | – year: 2014 text: 2014 |
| PublicationDecade | 2010 |
| PublicationTitle | 航空材料学报 |
| PublicationTitleAlternate | Journal of Aeronautical Materials |
| PublicationTitle_FL | Journal of Aeronautical Materials |
| PublicationYear | 2014 |
| Publisher | 河南理工大学材料科学与工程学院,河南焦作,454000 |
| Publisher_xml | – name: 河南理工大学材料科学与工程学院,河南焦作,454000 |
| SSID | ssib001129858 ssib051375391 ssj0000561693 ssib031741046 ssib023167179 ssib038074666 ssib017479244 |
| Score | 2.0038826 |
| Snippet | 采用X射线衍射（XRD）、偏光显微镜（POM）以及差示扫描量热（DSC）法,考察了纳米金刚石（Nano-diamond）对线型低密度聚乙烯（LLDPE）的结晶形态以及非等温结晶行为的影响。... TQ320.1%TQ315.14; 采用X射线衍射(XRD)、偏光显微镜(POM)以及差示扫描量热(DSC)法,考察了纳米金刚石(Nano-diamond)对线型低密度聚乙烯(LLDPE)的结晶形态以及非等温结晶行为... |
| SourceID | wanfang chongqing |
| SourceType | Aggregation Database Publisher |
| StartPage | 55 |
| SubjectTerms | 复合材料 成核剂 纳米金刚石 线型低密度聚乙烯 非等温结晶 |
| Title | 纳米金刚石改性LLDPE的非等温结晶动力学 |
| URI | http://lib.cqvip.com/qk/91216X/201405/662618795.html https://d.wanfangdata.com.cn/periodical/hkclxb201405009 |
| Volume | 34 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVAON databaseName: DOAJ Directory of Open Access Journals issn: 1005-5053 databaseCode: DOA dateStart: 20120101 customDbUrl: isFulltext: true dateEnd: 99991231 titleUrlDefault: https://www.doaj.org/ omitProxy: true ssIdentifier: ssj0000561693 providerName: Directory of Open Access Journals – providerCode: PRVALS databaseName: IngentaConnect Open Access Journals issn: 1005-5053 databaseCode: FIJ dateStart: 20110215 customDbUrl: isFulltext: true dateEnd: 20150615 titleUrlDefault: http://www.ingentaconnect.com/content/title?j_type=online&j_startat=Aa&j_endat=Af&j_pagesize=200&j_page=1 omitProxy: true ssIdentifier: ssj0000561693 providerName: Ingenta |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwELZKkRAcEE9RCqiH-rgldhzHPjrtVhUqiEORelslm6RFRVserYR64oAE9IZAQhQBNx6HHlAlxOP37K76L5iZpLumVLwu0aw9_jLjiTNjx55lbLJU2mAeuobI86ChMpHCe1DpRgq-XyuRlsLgQeGr1_TcDXVlMVocOfTC27W0vpZNtTcOPFfyP1aFMrArnpL9B8sOQKEAaLAvXMHCcP0rG_NmzBPHk5AIQYTlML23gjcjbgy3DqvsLFVpbhVPLBIm4C6en5-53qR6x43CpnaGWypxM9wQY2K4swSfcFthWJ5ognfcmZqwCRLQymk_3OVNg1I4kgJwQFhEgLsERBDaXkOSCzCjvYeAWJJaYuBNApJRcJcMWUAygIsRBXhRDmCMeBL7LKbJDdSA9tPcmmGNosYRNgZwM0vyYof6iyFiuAxK4JI6E9Su7hujMoZ6JAElCcwp6N6fFNuvc4wMlZlqHoV9DYIOcWLsX5N4PBbbOgnj4mBJwIo1FJRMAxtmPgwCz_NgSlgIR0PfNdXrvDf9j__kZ6rUxnXEUrmzX32h0YacIeJPDfBxO6OawpVEO4wBBjszl1fat-5nyBJEdDD2sIwhhPPWKijOhijRS4IkMZ2CGH7uhZhU4d6BwW_MuOTNkyMRwiy5TtJUJeHXmBSIdibUYh5hk3tKXP6NCpgSZXm1s3QHAj06d9cp086SFyIunGDH67ndhKsG6kk2srF8ih3zMn6eZlH_207_087uo6fdx1v9tzu95197D97TQOxvPdx9_aa__aT35WP_-7Pey8_dzQ_dzVfd7Xdn2MJsc2F6rlH_c0mjHVnbKGRWBFGeyULlZSaKONRWpmEOsV-QCqlTXQaiSCHOkCK1aZkKawobSIt7Tg3MIM6y0c5qpzjHJqwGlFCWRRGmqq3jzIg0a7dzzJSZ57IYY-MD_Vu3qwQ1La2lFia20RibqHukVb-27rX2Wfj8n1nG2VGkq4XHC2x07e56cRFC8bXsEj0WPwDr56Ic |
| linkProvider | Directory of Open Access Journals |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E7%BA%B3%E7%B1%B3%E9%87%91%E5%88%9A%E7%9F%B3%E6%94%B9%E6%80%A7LLDPE%E7%9A%84%E9%9D%9E%E7%AD%89%E6%B8%A9%E7%BB%93%E6%99%B6%E5%8A%A8%E5%8A%9B%E5%AD%A6&rft.jtitle=%E8%88%AA%E7%A9%BA%E6%9D%90%E6%96%99%E5%AD%A6%E6%8A%A5&rft.au=%E6%9B%B9%E6%96%B0%E9%91%AB&rft.au=%E7%BD%97%E5%9B%9B%E6%B5%B7&rft.au=%E7%8E%8B%E4%BC%98&rft.au=%E4%BD%95%E5%B0%8F%E8%8A%B3&rft.date=2014&rft.pub=%E6%B2%B3%E5%8D%97%E7%90%86%E5%B7%A5%E5%A4%A7%E5%AD%A6%E6%9D%90%E6%96%99%E7%A7%91%E5%AD%A6%E4%B8%8E%E5%B7%A5%E7%A8%8B%E5%AD%A6%E9%99%A2%2C%E6%B2%B3%E5%8D%97%E7%84%A6%E4%BD%9C%2C454000&rft.issn=1005-5053&rft.volume=34&rft.issue=5&rft.spage=55&rft.epage=62&rft_id=info:doi/10.11868%2Fj.issn.1005-5053.2014.5.009&rft.externalDocID=hkclxb201405009 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F91216X%2F91216X.jpg http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fhkclxb%2Fhkclxb.jpg |