原位微悬浮法纳米二氧化硅/氯醚树脂复合粒子的制备及表征
用硅烷偶联剂KH-570对纳米SiO2进行表面处理,干燥后预先分散于乙烯基异丁基醚中,再通过原位微悬浮聚合法制备了纳米SiO2/氯醚树脂复合粒子;考察了KH-570添加量、pH值和反应时间对纳米SiO2表面接枝率的影响,并用傅里叶变换红外光谱、核磁共振氢谱、差示扫描量热分析、热重分析和透射电子显微镜对纳米SiO2和纳米SiO2/氯醚树脂复合粒子进行了表征.结果表明,纳米SiO2表面改性的最佳条件为：KH-570与纳米SiO2质量比为1.2∶1,pH值为8.0 ～9.0,反应时间为8h;制备出的纳米SiO2/氯醚树脂复合粒子以纳米SiO2为核,其平均粒径为150～ 250 nm,其中核的直径为1...
Saved in:
| Published in | 合成橡胶工业 Vol. 37; no. 2; pp. 91 - 95 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
安徽大学化学化工学院安徽省绿色高分子材料重点实验室,合肥,230601%安徽省化工研究院,合肥,230041
2014
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1000-1255 |
Cover
| Abstract | 用硅烷偶联剂KH-570对纳米SiO2进行表面处理,干燥后预先分散于乙烯基异丁基醚中,再通过原位微悬浮聚合法制备了纳米SiO2/氯醚树脂复合粒子;考察了KH-570添加量、pH值和反应时间对纳米SiO2表面接枝率的影响,并用傅里叶变换红外光谱、核磁共振氢谱、差示扫描量热分析、热重分析和透射电子显微镜对纳米SiO2和纳米SiO2/氯醚树脂复合粒子进行了表征.结果表明,纳米SiO2表面改性的最佳条件为：KH-570与纳米SiO2质量比为1.2∶1,pH值为8.0 ～9.0,反应时间为8h;制备出的纳米SiO2/氯醚树脂复合粒子以纳米SiO2为核,其平均粒径为150～ 250 nm,其中核的直径为100～150 nm. |
|---|---|
| AbstractList | TQ325.3; 用硅烷偶联剂KH-570对纳米SiO2进行表面处理,干燥后预先分散于乙烯基异丁基醚中,再通过原位微悬浮聚合法制备了纳米SiO2/氯醚树脂复合粒子;考察了KH-570添加量、pH值和反应时间对纳米SiO2表面接枝率的影响,并用傅里叶变换红外光谱、核磁共振氢谱、差示扫描量热分析、热重分析和透射电子显微镜对纳米SiO2和纳米SiO2/氯醚树脂复合粒子进行了表征.结果表明,纳米SiO2表面改性的最佳条件为:KH-570与纳米SiO2质量比为1.2∶1,pH值为8.0 ～9.0,反应时间为8h;制备出的纳米SiO2/氯醚树脂复合粒子以纳米SiO2为核,其平均粒径为150～ 250 nm,其中核的直径为100～150 nm. 用硅烷偶联剂KH-570对纳米SiO2进行表面处理,干燥后预先分散于乙烯基异丁基醚中,再通过原位微悬浮聚合法制备了纳米SiO2/氯醚树脂复合粒子;考察了KH-570添加量、pH值和反应时间对纳米SiO2表面接枝率的影响,并用傅里叶变换红外光谱、核磁共振氢谱、差示扫描量热分析、热重分析和透射电子显微镜对纳米SiO2和纳米SiO2/氯醚树脂复合粒子进行了表征.结果表明,纳米SiO2表面改性的最佳条件为：KH-570与纳米SiO2质量比为1.2∶1,pH值为8.0 ～9.0,反应时间为8h;制备出的纳米SiO2/氯醚树脂复合粒子以纳米SiO2为核,其平均粒径为150～ 250 nm,其中核的直径为100～150 nm. |
| Author | 杨建军 吕国斌 吴庆云 张建安 吴明元 王申生 |
| AuthorAffiliation | 安徽大学化学化工学院安徽省绿色高分子材料重点实验室,合肥230601 安徽省化工研究院,合肥230041 |
| AuthorAffiliation_xml | – name: 安徽大学化学化工学院安徽省绿色高分子材料重点实验室,合肥,230601%安徽省化工研究院,合肥,230041 |
| Author_FL | YANG Jian-jun WU Qing-yun ZHANG Jian-an Lü Guo-bin WU Ming-yuan WANG Shen-sheng |
| Author_FL_xml | – sequence: 1 fullname: YANG Jian-jun – sequence: 2 fullname: Lü Guo-bin – sequence: 3 fullname: WU Qing-yun – sequence: 4 fullname: ZHANG Jian-an – sequence: 5 fullname: WU Ming-yuan – sequence: 6 fullname: WANG Shen-sheng |
| Author_xml | – sequence: 1 fullname: 杨建军 吕国斌 吴庆云 张建安 吴明元 王申生 |
| BookMark | eNotzUtLAlEYxvGzMEitD9Gq1dB7bjNnliHdQHDjXs6ZznihxlKiXCZ2IbQsqIWbEoRalFlSCyE_jWfGvkWCrZ7Nj-efQLGgHOgYimMAsDDhfBElqtUSAHVtV8RRxlw_Tn5aZtwP66_hVz8c3kejYfQxnIya4eDZNB-i7tlaOHj_Pe-ET7fTRt30WqZ9GX3embd21GmYy2_TuzA3V9PuixmfLqEFX-5V9fL_JlF2cyOb2rbSma2d1Hra8rhglnK4FL6kQtkgCCUuI8RXShPBHUFsprD2d7XWPva4qyTFju0xTR3NFUjAkibR6vz2WAa-DPK5UvmoEsyCuYJ3UsrXCGAGBIDN5MpceoVykD8szuxBpbgvK7UcE4JjAjb9AxMUclo |
| ClassificationCodes | TQ325.3 |
| ContentType | Journal Article |
| Copyright | Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | 2RA 92L CQIGP W92 ~WA 2B. 4A8 92I 93N PSX TCJ |
| DatabaseName | 维普期刊资源整合服务平台 中文科技期刊数据库-CALIS站点 维普中文期刊数据库 中文科技期刊数据库-工程技术 中文科技期刊数据库- 镜像站点 Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| DocumentTitleAlternate | Preparation and characterization of nanosilica/poly（vinyl chloride-co-vinyl isobutyl ether） composite particles by in situ micro-suspension polymerization |
| DocumentTitle_FL | Preparation and characterization of nanosilica/poly(vinyl chloride-co-vinyl isobutyl ether) composite particles by in situ micro-suspension polymerization |
| EndPage | 95 |
| ExternalDocumentID | hcxjgy201402004 48851206 |
| GrantInformation_xml | – fundername: 国家自然科学基金资助项目; 安徽省2010年第3批科技计划资助项目 funderid: (51173001); (10111406012) |
| GroupedDBID | -02 2B. 2C0 2RA 5XA 5XC 92H 92I 92L ACGFS ALMA_UNASSIGNED_HOLDINGS CCEZO CDRFL CQIGP CW9 GROUPED_DOAJ TCJ TGT U1G U5L W92 ~WA 4A8 93N ABJNI PSX |
| ID | FETCH-LOGICAL-c584-b75a8fa38b6082329422fbbe28578264b1efdeeef1c59ba3176c4e37e5b0a01a3 |
| ISSN | 1000-1255 |
| IngestDate | Thu May 29 03:53:54 EDT 2025 Wed Feb 14 10:38:03 EST 2024 |
| IsPeerReviewed | false |
| IsScholarly | true |
| Issue | 2 |
| Keywords | 氯醚树脂 核壳结构 原位微悬浮聚合法 in situ micro-suspension polymerization surface modification grafting ratio 纳米二氧化硅 poly (vinyl chloride-co-vinyl isobutyl ether) 接枝率 nanosilica 表面改性 core-shell structure |
| Language | Chinese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c584-b75a8fa38b6082329422fbbe28578264b1efdeeef1c59ba3176c4e37e5b0a01a3 |
| Notes | nanosilica; poly （ vinyl chloride-co-vinyl isobutyl ether） ; in situ micro-suspension poly-merization; surface modification; core-shell struc-ture ; grafting ratio YANG Jian-jun1, LU Guo-bin1 , WU Qing-yun , ZHANG Jian-an1 , WU Ming-yuan, WANG Shen-sheng2 （1. Key Laboratory of Environment-friendly Polymer Materials of Anhui Province, School of Chemistry and Chemical Engineering of Anhui University, Hefei 230601, China; 2. Anhui Research Institute of Chemical Industry, Hefei 230041, China） 62-1036/TQ The nano-SiO2/poly（vinyl chloride-covinyl isobutyl ether） （VC-VIBE） composite particles were synthesized by in situ micro-suspension polymerization, before which nano-SiO2 was modified with silane coupling agent KH-570, dried and then dispersed in VIBE. The effects of the amount of KH- 570, pH value, reaction time on grafting ratio of KH-570 onto nano-SiO2 were investigated. The mod- ified nano-SiO2 and composite particles were charac- terized by Fourier transform infrared spectroscopy, Z H-nuclear magnetic resonance |
| PageCount | 5 |
| ParticipantIDs | wanfang_journals_hcxjgy201402004 chongqing_primary_48851206 |
| PublicationCentury | 2000 |
| PublicationDate | 2014 |
| PublicationDateYYYYMMDD | 2014-01-01 |
| PublicationDate_xml | – year: 2014 text: 2014 |
| PublicationDecade | 2010 |
| PublicationTitle | 合成橡胶工业 |
| PublicationTitleAlternate | China Synthetic Rubber Industry |
| PublicationTitle_FL | China Synthetic Rubber Industry |
| PublicationYear | 2014 |
| Publisher | 安徽大学化学化工学院安徽省绿色高分子材料重点实验室,合肥,230601%安徽省化工研究院,合肥,230041 |
| Publisher_xml | – name: 安徽大学化学化工学院安徽省绿色高分子材料重点实验室,合肥,230601%安徽省化工研究院,合肥,230041 |
| SSID | ssj0039698 ssib002263290 ssib046728776 ssib051370708 ssib001104941 |
| Score | 1.966628 |
| Snippet | 用硅烷偶联剂KH-570对纳米SiO2进行表面处理,干燥后预先分散于乙烯基异丁基醚中,再通过原位微悬浮聚合法制备了纳米SiO2/氯醚树脂复合粒子;考察了KH-570添加量、pH值和反应时... TQ325.3; 用硅烷偶联剂KH-570对纳米SiO2进行表面处理,干燥后预先分散于乙烯基异丁基醚中,再通过原位微悬浮聚合法制备了纳米SiO2/氯醚树脂复合粒子;考察了KH-570添加量、pH... |
| SourceID | wanfang chongqing |
| SourceType | Aggregation Database Publisher |
| StartPage | 91 |
| SubjectTerms | chloride-co-vinyl ether isobutyl poly vinyl 原位微悬浮聚合法 接枝率 核壳结构 氯醚树脂 纳米二氧化硅 表面改性 |
| Title | 原位微悬浮法纳米二氧化硅/氯醚树脂复合粒子的制备及表征 |
| URI | http://lib.cqvip.com/qk/92553X/201402/48851206.html https://d.wanfangdata.com.cn/periodical/hcxjgy201402004 |
| Volume | 37 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVAON databaseName: DOAJ Directory of Open Access Journals issn: 1000-1255 databaseCode: DOA dateStart: 20140101 customDbUrl: isFulltext: true dateEnd: 99991231 titleUrlDefault: https://www.doaj.org/ omitProxy: true ssIdentifier: ssj0039698 providerName: Directory of Open Access Journals |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LTxRBEJ4QTnowPiP4CAf7uDqv7uk-Ts_OhpioF0y4bWZ2ZyAeFsUlUW4SVGJA0UQPXJSERA-KKNEDifwaZhf_hVXdvbsTxOdlUqmpruqqrzNTNY9qy7qUBwn2DfMrdmbTip-lSUWI3K4EaeCmHFaIpzreXLvOxm_6Vyfp5NDwbOmrpbl2erkxf-h_Jf-DKvAAV_xL9h-Q7SsFBtCALxwBYTj-FcYkpoTHRNRI7BNZJbyKHBmTMCYxI9wlYYSEpIYjPSIoiQMiQ6SRcBThI4drYZuEgdIcEcFQJnQIx94QvbNACMIZESFyQpsIh8SccB8twsDQNzMRNuFcWXGJ0KeqyAQOjAV5tMKJZL1R2m6N8BAVgt2QG4_0jiu9NLqknOERdcJMBA7BmXhGp4TJU-UdyPTXKsqKak-3RNfRLDDlQEQZwGABITG4OAiMRQdEpPICo8dMGIVTFpERRqhsCKDQ-xn1nrY4g-es_fPGbVk1odGQQPhCVsLmMI7xuX9KEAFxcQ_TDDBEEFmFEMyupmInEC0YFUoiuEGIsxJ4KniGYKgcV0OgIA9wBUhhbIlY6dELS3HAETcqgcfVGoW1FWGNirs50N_O82c3A7X-fEUIhXrP318bsnUTNHMvxqYHkH_T8s1adwgyFyW3dOc12OocTu_beqCR-nTj3q2p-wiq7eoWwpCc26WnMKqCcLBhUimjxf0MBi-SIa1weTDI4KnjBXDT7L-49AQT-u9bM3ds2TI905q6A4mo-i-wlSetqVIKO3HcOmZqz7FQX0hOWEPz0yeto6WOpKesG8XT13vfVordzc7C-86Xzc72y-7OdvfT9t7OcmfrbbH8qrv-8Epn6-P3R2udN8_3FxeKjZVidan7-UXxYbW7tlgsfS02HhfPnuyvvyt2H5y2JmrxRDReMXuuVBpQilTSgCY8TzyeMnwF7wrfdfM0zVyO214wP3WyvJllWe40qEgTKD5Yw8-8IKOpndhO4p2xhlszreysNdZIszxoNinUmE0_F00OyYEPulMKNaBLGyPWaD8y9du6tU4d0gmoQGw2Yo2ZUNXN9fZu_QB-o38WOWcdQVo_MT1vDbdn57ILUEO004sK9R-1qNHx |
| linkProvider | Directory of Open Access Journals |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E5%8E%9F%E4%BD%8D%E5%BE%AE%E6%82%AC%E6%B5%AE%E6%B3%95%E7%BA%B3%E7%B1%B3%E4%BA%8C%E6%B0%A7%E5%8C%96%E7%A1%85%2F%E6%B0%AF%E9%86%9A%E6%A0%91%E8%84%82%E5%A4%8D%E5%90%88%E7%B2%92%E5%AD%90%E7%9A%84%E5%88%B6%E5%A4%87%E5%8F%8A%E8%A1%A8%E5%BE%81&rft.jtitle=%E5%90%88%E6%88%90%E6%A9%A1%E8%83%B6%E5%B7%A5%E4%B8%9A&rft.au=%E6%9D%A8%E5%BB%BA%E5%86%9B&rft.au=%E5%90%95%E5%9B%BD%E6%96%8C&rft.au=%E5%90%B4%E5%BA%86%E4%BA%91&rft.au=%E5%BC%A0%E5%BB%BA%E5%AE%89&rft.date=2014&rft.pub=%E5%AE%89%E5%BE%BD%E5%A4%A7%E5%AD%A6%E5%8C%96%E5%AD%A6%E5%8C%96%E5%B7%A5%E5%AD%A6%E9%99%A2%E5%AE%89%E5%BE%BD%E7%9C%81%E7%BB%BF%E8%89%B2%E9%AB%98%E5%88%86%E5%AD%90%E6%9D%90%E6%96%99%E9%87%8D%E7%82%B9%E5%AE%9E%E9%AA%8C%E5%AE%A4%2C%E5%90%88%E8%82%A5%2C230601%25%E5%AE%89%E5%BE%BD%E7%9C%81%E5%8C%96%E5%B7%A5%E7%A0%94%E7%A9%B6%E9%99%A2%2C%E5%90%88%E8%82%A5%2C230041&rft.issn=1000-1255&rft.volume=37&rft.issue=2&rft.spage=91&rft.epage=95&rft.externalDocID=hcxjgy201402004 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F92553X%2F92553X.jpg http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fhcxjgy%2Fhcxjgy.jpg |