高效液相色谱-串联质谱法同时测定动物肝脏中玉米赤霉醇及其类似物残留量
采用高效液相色谱-串联质谱方法（HPLC-MS/MS）同时测定了动物肝脏中6种玉米赤霉醇及其类似物的残留量。酶解后的样品采用乙醚提取,经液-液分配（LLP）和HLB固相萃取（SPE）柱净化后,采用HPLC-MS/MS电喷雾电离（ESI-）,多反应监测（MRM）模式检测,基质匹配外标曲线定量。按照欧盟法规2002/657/EC的要求进行验证。在添加浓度1～4μg/kg范围内,方法回收率在70%～90%之间;相对标准偏差小于20%。6种玉米赤霉醇及其类似物的判断限（CCα）在0.17～0.31μg/kg之间,检测能力（CCβ）在0.26～0.42μg/kg之间。本方法对其它动物源食品中玉米赤霉醇及...
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| Published in | Fēnxī huàxué Vol. 38; no. 4; pp. 469 - 474 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
中国检验检疫科学研究院,北京,100123%内蒙古出入境检验检疫局,呼和浩特,010020%黑龙江出入境检验检疫局,哈尔滨,150001
2010
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0253-3820 |
| DOI | 10.3724/SP.J.1096.2010.00469 |
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| Abstract | 采用高效液相色谱-串联质谱方法（HPLC-MS/MS）同时测定了动物肝脏中6种玉米赤霉醇及其类似物的残留量。酶解后的样品采用乙醚提取,经液-液分配（LLP）和HLB固相萃取（SPE）柱净化后,采用HPLC-MS/MS电喷雾电离（ESI-）,多反应监测（MRM）模式检测,基质匹配外标曲线定量。按照欧盟法规2002/657/EC的要求进行验证。在添加浓度1～4μg/kg范围内,方法回收率在70%～90%之间;相对标准偏差小于20%。6种玉米赤霉醇及其类似物的判断限（CCα）在0.17～0.31μg/kg之间,检测能力（CCβ）在0.26～0.42μg/kg之间。本方法对其它动物源食品中玉米赤霉醇及其类似物残留的检测具有适用性。 |
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| AbstractList | 采用高效液相色谱-串联质谱方法（HPLC-MS/MS）同时测定了动物肝脏中6种玉米赤霉醇及其类似物的残留量。酶解后的样品采用乙醚提取,经液-液分配（LLP）和HLB固相萃取（SPE）柱净化后,采用HPLC-MS/MS电喷雾电离（ESI-）,多反应监测（MRM）模式检测,基质匹配外标曲线定量。按照欧盟法规2002/657/EC的要求进行验证。在添加浓度1～4μg/kg范围内,方法回收率在70%～90%之间;相对标准偏差小于20%。6种玉米赤霉醇及其类似物的判断限（CCα）在0.17～0.31μg/kg之间,检测能力（CCβ）在0.26～0.42μg/kg之间。本方法对其它动物源食品中玉米赤霉醇及其类似物残留的检测具有适用性。 O6; 采用高效液相色谱-串联质谱方法(HPLC-MS/MS)同时测定了动物肝脏中6种玉米赤霉醇及其类似物的残留量.酶解后的样品采用乙醚提取,经液-液分配(LLP)和HLB固相萃取(SPE)柱净化后,采用HPLC-MS/MS电喷雾电离(ESI-),多反应监测(MRM)模式检测,基质匹配外标曲线定量.按照欧盟法规2002/657/EC的要求进行验证.在添加浓度1～4 μg/kg范围内,方法回收率在70%～90%之间;相对标准偏差小于20%.6种玉米赤霉醇及其类似物的判断限(CCα)在0.17～0.31 μg/kg之间,检测能力(CCβ)在0.26～0.42 μg/kg之间.本方法对其它动物源食品中玉米赤霉醇及其类似物残留的检测具有适用性. |
| Author | 彭涛 李晓娟 陈冬东 代汉慧 于静 朱明达 马微 唐英章 |
| AuthorAffiliation | 中国检验检疫科学研究院,北京100123 内蒙古出入境检验检疫局,呼和浩特010020 黑龙江出入境检验检疫局,哈尔滨150001 |
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| Author_FL | YU Jing TANG Ying-Zhang LI Xiao-Juan CHEN Dong-Dong MA Wei DAI Han-Hui ZHU Ming-Da PENG Tao |
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| Keywords | 玉米赤霉醇 动物肝脏 类似物 高效液相色谱-串联质谱 |
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| Publisher | 中国检验检疫科学研究院,北京,100123%内蒙古出入境检验检疫局,呼和浩特,010020%黑龙江出入境检验检疫局,哈尔滨,150001 |
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| Snippet | 采用高效液相色谱-串联质谱方法（HPLC-MS/MS）同时测定了动物肝脏中6种玉米赤霉醇及其类似物的残留量。酶解后的样品采用乙醚提取,经液-液分配（LLP）和HLB固相萃取（SPE）... O6; 采用高效液相色谱-串联质谱方法(HPLC-MS/MS)同时测定了动物肝脏中6种玉米赤霉醇及其类似物的残留量.酶解后的样品采用乙醚提取,经液-液分配(LLP)和HLB固相萃取(SPE)柱... |
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| Title | 高效液相色谱-串联质谱法同时测定动物肝脏中玉米赤霉醇及其类似物残留量 |
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