毛细管电泳-电感耦合等离子体质谱法测定地下水中不同形态的砷
目前砷形态分析主要采用液相色谱（HPLC）分离与电感耦合等离子体质谱（1CP—MS）、原子荧光光谱（AFS）、以及原子吸收光谱（AAS）等联用技术。与HPLC分离技术相比，毛细管电泳（CE）具有分离效率高、样品消耗少、分析速度快的优点，而ICP—MS具有元素特异性检测以及检出限极低的优势。因此，CE与ICP—MS联用成为进行包括砷在内的元素形态分析的强有力分析工具。本实验采用CE进行不同砷形态的分离，并与ICP-MS联用，实现了水样中砷形态的测定。...
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| Published in | 分析化学 Vol. 41; no. 11; pp. 1780 - 1781 |
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| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
中国地质科学院水文地质环境地质研究所,正定,050803%河北省环境地质勘察院,石家庄,050000
2013
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0253-3820 |
| DOI | 10.3724/SP.J.1096.2013.30257 |
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| Abstract | 目前砷形态分析主要采用液相色谱（HPLC）分离与电感耦合等离子体质谱（1CP—MS）、原子荧光光谱（AFS）、以及原子吸收光谱（AAS）等联用技术。与HPLC分离技术相比，毛细管电泳（CE）具有分离效率高、样品消耗少、分析速度快的优点，而ICP—MS具有元素特异性检测以及检出限极低的优势。因此，CE与ICP—MS联用成为进行包括砷在内的元素形态分析的强有力分析工具。本实验采用CE进行不同砷形态的分离，并与ICP-MS联用，实现了水样中砷形态的测定。 |
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| AbstractList | 目前砷形态分析主要采用液相色谱（HPLC）分离与电感耦合等离子体质谱（1CP—MS）、原子荧光光谱（AFS）、以及原子吸收光谱（AAS）等联用技术。与HPLC分离技术相比，毛细管电泳（CE）具有分离效率高、样品消耗少、分析速度快的优点，而ICP—MS具有元素特异性检测以及检出限极低的优势。因此，CE与ICP—MS联用成为进行包括砷在内的元素形态分析的强有力分析工具。本实验采用CE进行不同砷形态的分离，并与ICP-MS联用，实现了水样中砷形态的测定。 |
| Author | 韩梅 赵国兴 李淑珍 孙振华 李义 贾娜 |
| AuthorAffiliation | 中国地质科学院水文地质环境地质研究所,正定050803 河北省环境地质勘察院,石家庄050000 |
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| Author_FL | HAN Mei ZHAO Guo-Xing JIA Na LI Yi LI Shu-Zhen SUN Zhen-Hua |
| Author_FL_xml | – sequence: 1 fullname: HAN Mei – sequence: 2 fullname: ZHAO Guo-Xing – sequence: 3 fullname: LI Shu-Zhen – sequence: 4 fullname: SUN Zhen-Hua – sequence: 5 fullname: LI Yi – sequence: 6 fullname: JIA Na |
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| DocumentTitleAlternate | Speciation Analysis of Arsenic in Groundwater by Capillary Electrophoresis-Inductively Coupled Plasma Mass Spectrometry |
| DocumentTitle_FL | Speciation Analysis of Arsenic in Groundwater by Capillary Electrophoresis-Inductively Coupled Plasma Mass Spectrometry |
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| Keywords | Speciation analysis Inductively coupled plasma mass spectrometry Arsenic Groundwater Capillary electrophoresis |
| Language | Chinese |
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| Notes | A method for the detection of trace As（~）, As（V）, monomethylarsonic acid（ MMA）, dimethylarsinic acid（DMA） in groundwater by capillary electrophoresis-inductively coupled plasma mass spectrometry（CE-ICP-MS） was developed. The results showed that the above four species of arsenic were baseline separated within 9 min under the optimized conditions. The detection limits （S/N = 3 ） of As（IB）, As（V）, DMA, MMA were O. 2-0.5μg/L, and the RSD （ n = 6） of the peak areas were smaller than 4.0%. The recoveries were 93%-106%. The result indicated that As（Ill） and As（V） as the main arsenic speciation existed in the groundwater of Inner Mongolia. HAN Mei1 , ZHAO Guo-XingI , LI Shu-ZhenI , SUN Zhen-HuaI , LI Yi2 , JIA Na ＊ 1 1 （ The Institute of Hydrogeology and Environmental Geology,Zhengding 050803, China） 2 （Hebei Institute of Environmental Geological Exploration,Shijiazhuang 050000, China） 22-1125/O6 Capillary electrophoresis; Inductively coupled plasma mass spectrometry; Speciation analysis; Arsenic;Groundwater |
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| PublicationDateYYYYMMDD | 2013-01-01 |
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| PublicationTitle | 分析化学 |
| PublicationTitleAlternate | Chinese Journal of Analytical Chemistry |
| PublicationTitle_FL | Chinese Journal of Analytical Chemistry |
| PublicationYear | 2013 |
| Publisher | 中国地质科学院水文地质环境地质研究所,正定,050803%河北省环境地质勘察院,石家庄,050000 |
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| Snippet | 目前砷形态分析主要采用液相色谱（HPLC）分离与电感耦合等离子体质谱（1CP—MS）、原子荧光光谱（AFS）、以及原子吸收光谱（AAS）等联用技术。与HPLC分离技术相比，毛细管电... |
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| SubjectTerms | ICP-MS 元素形态分析 原子荧光光谱 地下水 毛细管电泳 测定 电感耦合等离子体质谱法 砷形态 |
| Title | 毛细管电泳-电感耦合等离子体质谱法测定地下水中不同形态的砷 |
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