离子迁移谱快速筛查白酒中痕量邻苯二甲酸酯的研究
建立了离子迁移谱技术快速检测白酒中痕量邻苯二甲酸酯的方法。对迁移管温度、进样口温度进行了参数优化后,选取5种典型的邻苯二甲酸酯进行了系统研究。在迁移管和进样口温度分别为90℃和160℃的条件下,邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丁酯、邻苯二甲酸二异丁酯和邻苯二甲酸二（2-乙基己）酯的检出限分别为0.14,0.06,0.14,0.44和0.02 mg/L;9次平行测量的相对标准偏差RSD〈8.9%,单个样品的分析周期小于95 s。将本方法应用于5种白酒盲样的检测,成功筛查出邻苯二甲酸酯类物质。利用离子阱质谱对5种邻苯二甲酸酯标样产物离子和白酒盲样的产物离子进行了确认,结果表明,离子...
Saved in:
| Published in | 分析化学 Vol. 42; no. 2; pp. 278 - 282 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
中国科学院研究生院,北京100039%中国科学院大连化学物理研究所,大连,116023
2014
中国科学院大连化学物理研究所,大连116023 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0253-3820 |
| DOI | 10.3724/SP.J.1096.2014.30730 |
Cover
| Abstract | 建立了离子迁移谱技术快速检测白酒中痕量邻苯二甲酸酯的方法。对迁移管温度、进样口温度进行了参数优化后,选取5种典型的邻苯二甲酸酯进行了系统研究。在迁移管和进样口温度分别为90℃和160℃的条件下,邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丁酯、邻苯二甲酸二异丁酯和邻苯二甲酸二（2-乙基己）酯的检出限分别为0.14,0.06,0.14,0.44和0.02 mg/L;9次平行测量的相对标准偏差RSD〈8.9%,单个样品的分析周期小于95 s。将本方法应用于5种白酒盲样的检测,成功筛查出邻苯二甲酸酯类物质。利用离子阱质谱对5种邻苯二甲酸酯标样产物离子和白酒盲样的产物离子进行了确认,结果表明,离子迁移谱的谱峰是邻苯二甲酸酯离子。这说明丙酮作为掺杂剂,可以避免白酒中背景化合物的干扰。本方法适于大量白酒样品中邻苯二甲酸酯类物质的快速筛查。 |
|---|---|
| AbstractList | 建立了离子迁移谱技术快速检测白酒中痕量邻苯二甲酸酯的方法。对迁移管温度、进样口温度进行了参数优化后,选取5种典型的邻苯二甲酸酯进行了系统研究。在迁移管和进样口温度分别为90℃和160℃的条件下,邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丁酯、邻苯二甲酸二异丁酯和邻苯二甲酸二（2-乙基己）酯的检出限分别为0.14,0.06,0.14,0.44和0.02 mg/L;9次平行测量的相对标准偏差RSD〈8.9%,单个样品的分析周期小于95 s。将本方法应用于5种白酒盲样的检测,成功筛查出邻苯二甲酸酯类物质。利用离子阱质谱对5种邻苯二甲酸酯标样产物离子和白酒盲样的产物离子进行了确认,结果表明,离子迁移谱的谱峰是邻苯二甲酸酯离子。这说明丙酮作为掺杂剂,可以避免白酒中背景化合物的干扰。本方法适于大量白酒样品中邻苯二甲酸酯类物质的快速筛查。 建立了离子迁移谱技术快速检测白酒中痕量邻苯二甲酸酯的方法.对迁移管温度、进样口温度进行了参数优化后,选取5种典型的邻苯二甲酸酯进行了系统研究.在迁移管和进样口温度分别为90℃和160℃的条件下,邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丁酯、邻苯二甲酸二异丁酯和邻苯二甲酸二(2-乙基己)酯的检出限分别为0.14,0.06,0.14,0.44和0.02 mg/L;9次平行测量的相对标准偏差RSD＜8.9％,单个样品的分析周期小于95 s.将本方法应用于5种白酒盲样的检测,成功筛查出邻苯二甲酸酯类物质.利用离子阱质谱对5种邻苯二甲酸酯标样产物离子和白酒盲样的产物离子进行了确认,结果表明,离子迁移谱的谱峰是邻苯二甲酸酯离子.这说明丙酮作为掺杂剂,可以避免白酒中背景化合物的干扰.本方法适于大量白酒样品中邻苯二甲酸酯类物质的快速筛查. |
| Author | 彭丽英 王卫国 王新 陈文东 陈创 程沙沙 梁茜茜 周庆华 李京华 李海洋 |
| AuthorAffiliation | 中国科学院大连化学物理研究所,大连116023 中国科学院研究生院,北京100039 |
| AuthorAffiliation_xml | – name: 中国科学院大连化学物理研究所,大连116023;中国科学院研究生院,北京100039%中国科学院大连化学物理研究所,大连,116023 |
| Author_xml | – sequence: 1 fullname: 彭丽英 王卫国 王新 陈文东 陈创 程沙沙 梁茜茜 周庆华 李京华 李海洋 |
| BookMark | eNotj01LAlEYhe_CIDP_QZsWLWd679fMnWWIfSEU5F7ufFw1aiwlsl1F0qKgCCOqhW0qIsRqEZKEf0a7zr9owjiLs3l4DmcKJcJKGCA0g8GkNmHzG-vmqonBsUwCmJkUbAoJlATCqUEFgUmUrtXKLgDGwAQXSZTVT71h-3LUP9LPvdHb-7D_Gh22dPv-p_Wob7-jxtWg29Y319HpRXTcG511Bl_nuvkRNbpRo6PvTvRDU798TqMJJbdqQfq_Uyi_mM1nlo3c2tJKZiFneNwCgzmBsjyPc992BbcdX2DBXaEkDxRzlfQk8S3qYiABEZYKfIvYImAKO1gym7o0hebG2n0ZKhkWC5uVvWoYDxZUvVT_uwwkTszNjjmvVAmLu-WY3KmWt2X1oMCEwACOQ38Bv0hyhw |
| ContentType | Journal Article |
| Copyright | Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | 2RA 92L CQIGP ~WA 2B. 4A8 92I 93N PSX TCJ |
| DOI | 10.3724/SP.J.1096.2014.30730 |
| DatabaseName | 中文期刊服务平台 中文科技期刊数据库-CALIS站点 维普中文期刊数据库 中文科技期刊数据库- 镜像站点 Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| DocumentTitleAlternate | Rapid Screening of Trace Phthalate Estersin-Wine Using Ion Mobility Spectrometry |
| DocumentTitle_FL | Rapid Screening of Trace Phthalate Estersin-Wine Using Ion Mobility Spectrometry |
| EndPage | 282 |
| ExternalDocumentID | fxhx201402020 48810099 |
| GrantInformation_xml | – fundername: 国家高技术研究发展计划; 国家自然科学基金项目; the National High Technology Research and Development Program of China; the National Natural Science Foundation of China funderid: (863计划,2011AA060602); (.21177124,21077101,11004190); (2011AA060602); (.21177124,21077101,11004190) |
| GroupedDBID | --K --M .~1 0R~ 1B1 1~. 1~5 29B 2B. 2C. 2RA 4.4 457 4G. 5GY 5VS 7-5 71M 8P~ 92E 92I 92L AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AARLI AAXUO ABFNM ABMAC ABXDB ABYKQ ACDAQ ACGFS ACNNM ACRLP ADBBV ADECG ADEZE ADMUD AEBSH AEKER AENEX AFKWA AFTJW AFZHZ AGHFR AGUBO AGYEJ AIEXJ AIKHN AITUG AJBFU AJOXV AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLXMC CQIGP CS3 CW9 DU5 EBS EFJIC EFLBG EJD EO9 EP2 EP3 FDB FEDTE FIRID FLBIZ FNPLU FYGXN GBLVA HVGLF HZ~ J1W KOM M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 ROL SDF SDG SES SPC SPCBC SSK SSZ T5K TCJ TGP U1G U5L ~G- ~WA -02 -0B -SB -S~ .5D 188 4A8 5VR 5XA 5XC 8RM 92M 93N 9D9 9DB AAITT AATTM AAXKI AAYWO ABJNI ABWVN ACRPL ADNMO ADVLN AEIPS AFJKZ AFUIB AFXIZ AGCQF AGRNS AIIUN AKRWK ANKPU APXCP BBR BNPGV CAJEB CCEZO CDRFL CDYEO CJPJV CW7 FA0 J.9 JUIAU M~T PB1 PB6 PSX Q-- R-B RT2 S.. SSH T8R U1F U5B UY8 UZ4 W94 ~LN |
| ID | FETCH-LOGICAL-c560-49ef6cc55d7b8579d8185b8fa5ef4bfaca2d63b102e286fed6278e4f191a473b3 |
| ISSN | 0253-3820 |
| IngestDate | Thu May 29 04:00:22 EDT 2025 Wed Feb 14 10:37:47 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 2 |
| Keywords | Ion mobility spectrometry Phthalate esters Plasticizer 离子迁移谱 邻苯二甲酸酯 快速筛查 增塑剂 Rapid screening |
| Language | Chinese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c560-49ef6cc55d7b8579d8185b8fa5ef4bfaca2d63b102e286fed6278e4f191a473b3 |
| Notes | Phthalic acid ester is a kind of common environmental pollutants. Here, a method for fast screening trace phthalic acid ester in wine was constructed based on ion mobility spectrometry （IMS）. Tube temperature and inlet temperature were optimized, and five typical phthalic acid esters were detected successively. Under the optimal tube temperature of 90℃ and inlet temperature of 160℃, the limits of detection for dimethyl phthalate （DMP）, diethyl phthalate （ DEP）, dibutyl phthalate （ DBP）, diisobutyl phthalate （DIBP） and diethylhexyl phthalate （DEHP） are 0.14, 0.06, 0.14, 0.44 and 0.02 nag/L, respectively, and the relative standard deviation （RSD） of 9 times measurements are less than 8.9%. The analytical time for single sample is less than 95 s. At last, five types of white wines were analyzed and the suspicious problem samples were successfully screened. And a home-made ion trap mass spectrometer was used to verify the product ions of phthalic acid ester detected by IMS and the interferences in wines can be av |
| PageCount | 5 |
| ParticipantIDs | wanfang_journals_fxhx201402020 chongqing_primary_48810099 |
| PublicationCentury | 2000 |
| PublicationDate | 2014 |
| PublicationDateYYYYMMDD | 2014-01-01 |
| PublicationDate_xml | – year: 2014 text: 2014 |
| PublicationDecade | 2010 |
| PublicationTitle | 分析化学 |
| PublicationTitleAlternate | Chinese Journal of Analytical Chemistry |
| PublicationTitle_FL | Chinese Journal of Analytical Chemistry |
| PublicationYear | 2014 |
| Publisher | 中国科学院研究生院,北京100039%中国科学院大连化学物理研究所,大连,116023 中国科学院大连化学物理研究所,大连116023 |
| Publisher_xml | – name: 中国科学院大连化学物理研究所,大连116023 – name: 中国科学院研究生院,北京100039%中国科学院大连化学物理研究所,大连,116023 |
| SSID | ssib001104858 ssib048394981 ssj0037577 ssib002258198 ssib007686865 ssib051370160 |
| Score | 2.0142784 |
| Snippet | 建立了离子迁移谱技术快速检测白酒中痕量邻苯二甲酸酯的方法。对迁移管温度、进样口温度进行了参数优化后,选取5种典型的邻苯二甲酸酯进行了系统研究。在迁移管和进样口温度分... 建立了离子迁移谱技术快速检测白酒中痕量邻苯二甲酸酯的方法.对迁移管温度、进样口温度进行了参数优化后,选取5种典型的邻苯二甲酸酯进行了系统研究.在迁移管和进样口温度分... |
| SourceID | wanfang chongqing |
| SourceType | Aggregation Database Publisher |
| StartPage | 278 |
| SubjectTerms | 增塑剂 快速筛查 离子迁移谱 邻苯二甲酸酯 |
| Title | 离子迁移谱快速筛查白酒中痕量邻苯二甲酸酯的研究 |
| URI | http://lib.cqvip.com/qk/93919X/201402/48810099.html https://d.wanfangdata.com.cn/periodical/fxhx201402020 |
| Volume | 42 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVESC databaseName: Baden-Württemberg Complete Freedom Collection (Elsevier) issn: 0253-3820 databaseCode: GBLVA dateStart: 20110101 customDbUrl: isFulltext: true dateEnd: 99991231 titleUrlDefault: https://www.sciencedirect.com omitProxy: true ssIdentifier: ssj0037577 providerName: Elsevier – providerCode: PRVESC databaseName: Elsevier ScienceDirect issn: 0253-3820 databaseCode: .~1 dateStart: 20060101 customDbUrl: isFulltext: true dateEnd: 99991231 titleUrlDefault: https://www.sciencedirect.com omitProxy: true ssIdentifier: ssj0037577 providerName: Elsevier – providerCode: PRVESC databaseName: Elsevier ScienceDirect issn: 0253-3820 databaseCode: ACRLP dateStart: 20060101 customDbUrl: isFulltext: true dateEnd: 20221231 titleUrlDefault: https://www.sciencedirect.com omitProxy: true ssIdentifier: ssj0037577 providerName: Elsevier – providerCode: PRVESC databaseName: Elsevier SD Freedom Collection Journals [SCFCJ] issn: 0253-3820 databaseCode: AIKHN dateStart: 20060101 customDbUrl: isFulltext: true dateEnd: 20221231 titleUrlDefault: https://www.sciencedirect.com omitProxy: true ssIdentifier: ssj0037577 providerName: Elsevier – providerCode: PRVLSH databaseName: Elsevier Journals issn: 0253-3820 databaseCode: AKRWK dateStart: 20060101 customDbUrl: isFulltext: true mediaType: online dateEnd: 99991231 omitProxy: true ssIdentifier: ssj0037577 providerName: Library Specific Holdings |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnR1Na9RQMNR6UA_iJ7Zq6cF3zJq8vPeSd0yyWUpB8VChtyWf7WlbtYXSg6hYPCgoUhH1UC8qIqXqQYpF-mda0_0XzrykSbQLWmFZ3s5MZubNbHbmvZ3J07QrRsLsOIyFTiMj1pkdSj2iYajjCXZGQhMqVfvYteti4iabnObTQ8MnGlVLiwtRK14e2FfyP14FGPgVu2QP4dmKKQBgDP6Fd_AwvP-Tj0lgE1cQzyMBJ26bSIMEDvE6kB4qlK1QADGIZyINoFyASFXf0FE0cBVABH50OUKkJF5b0XAiKQkY8RwkQxS8uELZxOmoAS1FOB5xO4rYJY6viGFMSz7AoRi4SqgEGqakG0iGAxAqmokyausAW6F0C9TUOHKWopysW-0pqpm1lY5KWVRfaeSZNQloHCAMubSVFTjO3GsPIBEoxTNqjESrgDoFBmZfCJJ-c9PErLdLG1YrpZT-kGalfcnVpQcNUZpPdmoa6u_P3y6t7Pqm6nkmlB9SHEAYYovvChj3gGWVLSQqg5oYyg0HlRRIg7Wj_gCe1DdNYRRd3mWkodzSLYcazbDIaOP2p80YV5y5VKZLtDg76s9IbNmUYS3AjdYkPrEMi4FM1lIBpc48qnrQbGl2CQlg7UKNI9pRiptrEJxad-vgA-ti4dR_yTPI7Jl0qnouy-bqmNVqLkWfLOpxdZAW-CyV2bnezC3IEFXDXi8LezON3HLqlHayXBSOu8UdflobWp49ox3z989iPKsF-fut3fVne9v38w9be5-_7G5_6t9by9ff_Fx7l7_60V95vrO5nr980X_0tP9ga-_xxs73J_nq1_7KZn9lI3_9MH-7mn_8dk6b6gRT_oReHoCix7AQ0ZlMMxHHnCd25HBbJphcR04W8jRjURbGIU2EFcESIaWOyNJEgGtSlpnSDJltRdZ5bbg310svaOOcxgmLbengDoRkRsSMDK6MY8jwpXTkiDZaWaM7Xzznpgux3cQV5Ig2VpqnW_743en-5rHRvxFc1I7juNi6vKQNL9xeTC9DMr8QjSkn_wJFsLYx |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E7%A6%BB%E5%AD%90%E8%BF%81%E7%A7%BB%E8%B0%B1%E5%BF%AB%E9%80%9F%E7%AD%9B%E6%9F%A5%E7%99%BD%E9%85%92%E4%B8%AD%E7%97%95%E9%87%8F%E9%82%BB%E8%8B%AF%E4%BA%8C%E7%94%B2%E9%85%B8%E9%85%AF%E7%9A%84%E7%A0%94%E7%A9%B6&rft.jtitle=%E5%88%86%E6%9E%90%E5%8C%96%E5%AD%A6&rft.au=%E5%BD%AD%E4%B8%BD%E8%8B%B1&rft.au=%E7%8E%8B%E5%8D%AB%E5%9B%BD&rft.au=%E7%8E%8B%E6%96%B0&rft.au=%E9%99%88%E6%96%87%E4%B8%9C&rft.date=2014&rft.pub=%E4%B8%AD%E5%9B%BD%E7%A7%91%E5%AD%A6%E9%99%A2%E7%A0%94%E7%A9%B6%E7%94%9F%E9%99%A2%2C%E5%8C%97%E4%BA%AC100039%25%E4%B8%AD%E5%9B%BD%E7%A7%91%E5%AD%A6%E9%99%A2%E5%A4%A7%E8%BF%9E%E5%8C%96%E5%AD%A6%E7%89%A9%E7%90%86%E7%A0%94%E7%A9%B6%E6%89%80%2C%E5%A4%A7%E8%BF%9E%2C116023&rft.issn=0253-3820&rft.volume=42&rft.issue=2&rft.spage=278&rft.epage=282&rft_id=info:doi/10.3724%2FSP.J.1096.2014.30730&rft.externalDocID=fxhx201402020 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F93919X%2F93919X.jpg http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Ffxhx%2Ffxhx.jpg |