Twofold fused concave hosts containing two phosphorus atoms: modules for the sandwich-type encapsulation of fullerenes in variable cavities
The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the fullerene guests C60 and C70 afforded the 2 : 1 host–guest complexes (P2)2 ⊃ C60 and (P2)2 ⊃ C70, in which the two concave surfaces of P2 encapsulat...
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| Published in | Chemical science Vol. 6; no. 11; pp. 6373 - 6378 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
The Royal Society of Chemistry
01.11.2015
Royal Society of Chemistry |
| Subjects | |
| Online Access | Get full text |
| ISSN | 2041-6520 2041-6539 2041-6539 |
| DOI | 10.1039/c5sc02224j |
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| Abstract | The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the fullerene guests C60 and C70 afforded the 2 : 1 host–guest complexes (P2)2 ⊃ C60 and (P2)2 ⊃ C70, in which the two concave surfaces of P2 encapsulate the convex surface of the fullerenes in a sandwich fashion. Interestingly, the orientation of the two P2 molecules with respect to each other was observed to be flexible, resulting in the formation of a variety of cavity shapes. MALDI-TOF mass, NMR, and UV-vis absorption spectra supported the formation of host–guest complexes between P2 and the fullerenes in solution. The affinity of P2, containing two phosphorus atoms, towards fullerenes was significantly enhanced relative to P1 with one phosphorus atom. |
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| AbstractList | The design and synthesis of extended concave host
by fusion of two concave phosphorus-containing units is reported. Co-crystallization of
and the fullerene guests C
and C
afforded the 2 : 1 host-guest complexes (
)
⊃ C
and (
)
⊃ C
, in which the two concave surfaces of
encapsulate the convex surface of the fullerenes in a sandwich fashion. Interestingly, the orientation of the two
molecules with respect to each other was observed to be flexible, resulting in the formation of a variety of cavity shapes. MALDI-TOF mass, NMR, and UV-vis absorption spectra supported the formation of host-guest complexes between
and the fullerenes in solution. The affinity of
, containing two phosphorus atoms, towards fullerenes was significantly enhanced relative to
with one phosphorus atom. The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the fullerene guests C sub(60) and C sub(70) afforded the 2 : 1 host-guest complexes (P2) sub(2) super( C) sub(6)0and (P2) sub(2) super( C) sub(7)0 in which the two concave surfaces of P2 encapsulate the convex surface of the fullerenes in a sandwich fashion. Interestingly, the orientation of the two P2 molecules with respect to each other was observed to be flexible, resulting in the formation of a variety of cavity shapes. MALDI-TOF mass, NMR, and UV-vis absorption spectra supported the formation of host-guest complexes between P2 and the fullerenes in solution. The affinity of P2, containing two phosphorus atoms, towards fullerenes was significantly enhanced relative to P1 with one phosphorus atom. Concave host by fusion of two phosphorus atoms affords variable sandwich-type cavities for guest fullerene, C60 or C70. The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the fullerene guests C60 and C70 afforded the 2 : 1 host–guest complexes (P2)2 ⊃ C60 and (P2)2 ⊃ C70, in which the two concave surfaces of P2 encapsulate the convex surface of the fullerenes in a sandwich fashion. Interestingly, the orientation of the two P2 molecules with respect to each other was observed to be flexible, resulting in the formation of a variety of cavity shapes. MALDI-TOF mass, NMR, and UV-vis absorption spectra supported the formation of host–guest complexes between P2 and the fullerenes in solution. The affinity of P2, containing two phosphorus atoms, towards fullerenes was significantly enhanced relative to P1 with one phosphorus atom. The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the fullerene guests C60 and C70 afforded the 2 : 1 host–guest complexes (P2)2 ⊃ C60 and (P2)2 ⊃ C70, in which the two concave surfaces of P2 encapsulate the convex surface of the fullerenes in a sandwich fashion. Interestingly, the orientation of the two P2 molecules with respect to each other was observed to be flexible, resulting in the formation of a variety of cavity shapes. MALDI-TOF mass, NMR, and UV-vis absorption spectra supported the formation of host–guest complexes between P2 and the fullerenes in solution. The affinity of P2, containing two phosphorus atoms, towards fullerenes was significantly enhanced relative to P1 with one phosphorus atom. The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the fullerene guests C 60 and C 70 afforded the 2 : 1 host–guest complexes ( P2 ) 2 ⊃ C 60 and ( P2 ) 2 ⊃ C 70 , in which the two concave surfaces of P2 encapsulate the convex surface of the fullerenes in a sandwich fashion. Interestingly, the orientation of the two P2 molecules with respect to each other was observed to be flexible, resulting in the formation of a variety of cavity shapes. MALDI-TOF mass, NMR, and UV-vis absorption spectra supported the formation of host–guest complexes between P2 and the fullerenes in solution. The affinity of P2 , containing two phosphorus atoms, towards fullerenes was significantly enhanced relative to P1 with one phosphorus atom. The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the fullerene guests C60 and C70 afforded the 2 : 1 host-guest complexes (P2)2 ⊃ C60 and (P2)2 ⊃ C70, in which the two concave surfaces of P2 encapsulate the convex surface of the fullerenes in a sandwich fashion. Interestingly, the orientation of the two P2 molecules with respect to each other was observed to be flexible, resulting in the formation of a variety of cavity shapes. MALDI-TOF mass, NMR, and UV-vis absorption spectra supported the formation of host-guest complexes between P2 and the fullerenes in solution. The affinity of P2, containing two phosphorus atoms, towards fullerenes was significantly enhanced relative to P1 with one phosphorus atom.The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the fullerene guests C60 and C70 afforded the 2 : 1 host-guest complexes (P2)2 ⊃ C60 and (P2)2 ⊃ C70, in which the two concave surfaces of P2 encapsulate the convex surface of the fullerenes in a sandwich fashion. Interestingly, the orientation of the two P2 molecules with respect to each other was observed to be flexible, resulting in the formation of a variety of cavity shapes. MALDI-TOF mass, NMR, and UV-vis absorption spectra supported the formation of host-guest complexes between P2 and the fullerenes in solution. The affinity of P2, containing two phosphorus atoms, towards fullerenes was significantly enhanced relative to P1 with one phosphorus atom. |
| Author | 山村 正樹 鍋島 達弥 Yamamura Masaki Hongo Daigo Nabeshima Tatsuya |
| AuthorAffiliation | a Graduate School of Pure and Applied Sciences , Tsukuba Research Center for Interdisciplinary Materials Science , University of Tsukuba , 1-1-1 Tennodai , Tsukuba , Ibaraki , 305-8571 Japan . Email: myama@chem.tsukuba.ac.jp ; Email: nabesima@chem.tsukuba.ac.jp |
| AuthorAffiliation_xml | – name: a Graduate School of Pure and Applied Sciences , Tsukuba Research Center for Interdisciplinary Materials Science , University of Tsukuba , 1-1-1 Tennodai , Tsukuba , Ibaraki , 305-8571 Japan . Email: myama@chem.tsukuba.ac.jp ; Email: nabesima@chem.tsukuba.ac.jp |
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| BackLink | https://cir.nii.ac.jp/crid/1571980077548971648$$DView record in CiNii https://www.ncbi.nlm.nih.gov/pubmed/30090256$$D View this record in MEDLINE/PubMed |
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| Snippet | The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the... The design and synthesis of extended concave host P2 by fusion of two concave phosphorus-containing units is reported. Co-crystallization of P2 and the... The design and synthesis of extended concave host by fusion of two concave phosphorus-containing units is reported. Co-crystallization of and the fullerene... Concave host by fusion of two phosphorus atoms affords variable sandwich-type cavities for guest fullerene, C60 or C70. The design and synthesis of extended... |
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| SubjectTerms | Affinity Buckminsterfullerene Chemistry Encapsulation Formations Fullerenes Holes Phosphorus Surface chemistry |
| Title | Twofold fused concave hosts containing two phosphorus atoms: modules for the sandwich-type encapsulation of fullerenes in variable cavities |
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