通过自由基历程烯烃1，2-双官能团化反应同时构建C-O键和C-X键研究进展
通过自由基途径的烯烃1，2-双官能团化反应是有机合成中从烯烃直接构建C-X（X=C，N，O…）键的重要手段，其优点包括良好的区域选择性、步骤经济性和原子经济性，符合绿色化学的发展要求。含有碳-氧键的有机功能化合物种类很多，发展简单高效构建碳-氧键的合成方法是有机化学家广泛关注的研究领域。本文综述了在构建碳-氧键的同时，构建碳-碳键、碳-氮键、碳-硫键和碳-卤键的反应研究进程，并对该领域的未来发展方向进行了展望。...
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| Published in | 大学化学 Vol. 39; no. 11; pp. 146 - 157 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | Chinese |
| Published |
北京大学
28.11.2024
中国化学会 南开大学化学学院,元素有机化学国家重点实验室,天津 300071 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1000-8438 |
| DOI | 10.12461/PKU.DXHX202403087 |
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| Abstract | 通过自由基途径的烯烃1，2-双官能团化反应是有机合成中从烯烃直接构建C-X（X=C，N，O…）键的重要手段，其优点包括良好的区域选择性、步骤经济性和原子经济性，符合绿色化学的发展要求。含有碳-氧键的有机功能化合物种类很多，发展简单高效构建碳-氧键的合成方法是有机化学家广泛关注的研究领域。本文综述了在构建碳-氧键的同时，构建碳-碳键、碳-氮键、碳-硫键和碳-卤键的反应研究进程，并对该领域的未来发展方向进行了展望。 |
|---|---|
| AbstractList | 通过自由基途径的烯烃1，2-双官能团化反应是有机合成中从烯烃直接构建C-X（X=C，N，O…）键的重要手段，其优点包括良好的区域选择性、步骤经济性和原子经济性，符合绿色化学的发展要求。含有碳-氧键的有机功能化合物种类很多，发展简单高效构建碳-氧键的合成方法是有机化学家广泛关注的研究领域。本文综述了在构建碳-氧键的同时，构建碳-碳键、碳-氮键、碳-硫键和碳-卤键的反应研究进程，并对该领域的未来发展方向进行了展望。 G64%O6; 通过自由基途径的烯烃1,2-双官能团化反应是有机合成中从烯烃直接构建C―X(X=C,N,O…)键的重要手段,其优点包括良好的区域选择性、步骤经济性和原子经济性,符合绿色化学的发展要求.含有碳-氧键的有机功能化合物种类很多,发展简单高效构建碳-氧键的合成方法是有机化学家广泛关注的研究领域.本文综述了在构建碳-氧键的同时,构建碳-碳键、碳-氮键、碳-硫键和碳-卤键的反应研究进程,并对该领域的未来发展方向进行了展望. |
| Abstract_FL | The 1,2-difunctionalization of olefins via radical pathways is a crucial method in organic synthesis for the direct formation of C―X(X=C,N,O,etc.)bonds from olefins.This approach offers several advantages,including high regioselectivity,step economy,and atom economy,making it compatible with the principles of green chemistry.The development of simple and efficient methods for constructing carbon-oxygen bonds is a significant area of interest in organic chemistry due to the prevalence of organic functional compounds containing these bonds.This review summarizes the recent progress in constructing carbon-oxygen bonds concurrently with carbon-carbon,carbon-nitrogen,carbon-sulfur,and carbon-halogen bonds.Additionally,the article discusses the future directions for research in this field. |
| Author | 苗志伟 刘佳俊 徐大振 李天宇 吴丹清 |
| AuthorAffiliation | 南开大学化学学院,元素有机化学国家重点实验室,天津 300071 |
| AuthorAffiliation_xml | – name: 南开大学化学学院,元素有机化学国家重点实验室,天津 300071 |
| Author_FL | Dazhen Xu Zhiwei Miao Jiajun Liu Danqing Wu Tianyu Li |
| Author_FL_xml | – sequence: 1 fullname: Danqing Wu – sequence: 2 fullname: Jiajun Liu – sequence: 3 fullname: Tianyu Li – sequence: 4 fullname: Dazhen Xu – sequence: 5 fullname: Zhiwei Miao |
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| Keywords | 区域选择性 碳-氧键构建 烯烃 自由基历程 1,2-双官能团化 研究进展 1,2-Difunctionalization Research progress Alkenes Regioselectivity Radical pathways C―O bond construction |
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| Title | 通过自由基历程烯烃1，2-双官能团化反应同时构建C-O键和C-X键研究进展 |
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