Highly Efficient and Selective Hydrogenation of Biomass-Derived Furfural Using Interface-Active Rice Husk-Based Porous Carbon-Supported NiCu Alloy Catalysts
A series of bimetallic NixCuy catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were prepared using a simple impregnation method for the liquid-phase hydrogenation of furfural (FFA) to tetrahydrofurfuryl alcohol (THFA). The Ni2Cu1/RH...
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| Published in | Molecules (Basel, Switzerland) Vol. 29; no. 11; p. 2638 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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03.06.2024
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| Online Access | Get full text |
| ISSN | 1420-3049 1420-3049 |
| DOI | 10.3390/molecules29112638 |
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| Abstract | A series of bimetallic NixCuy catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were prepared using a simple impregnation method for the liquid-phase hydrogenation of furfural (FFA) to tetrahydrofurfuryl alcohol (THFA). The Ni2Cu1/RHPC catalyst, with an average metal particle size of 9.3 nm, exhibits excellent catalytic performance for the selective hydrogenation of FFA to THFA. The 100% conversion of FFA and the 99% selectivity to THFA were obtained under mild reaction conditions (50 °C, 1 MPa, 1 h), using water as a green reaction solvent. The synergistic effect of NiCu alloy ensures the high catalytic activity. The acid sites and oxygen-containing functional groups on the surface of the modified RHPC can enhance the selectivity of THFA. The Ni2Cu1/RHPC catalyst offers good cyclability and regenerability. The current work proposes a simple method for preparing an NiCu bimetallic catalyst. The catalyst exhibits excellent performance in the catalytic hydrogenation of furfural to tetrahydrofurfuryl alcohol, which broadens the application of non-noble metal bimetallic nanocatalysts in the catalytic hydrogenation of furfural. |
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| AbstractList | A series of bimetallic NixCuy catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were prepared using a simple impregnation method for the liquid-phase hydrogenation of furfural (FFA) to tetrahydrofurfuryl alcohol (THFA). The Ni2Cu1/RHPC catalyst, with an average metal particle size of 9.3 nm, exhibits excellent catalytic performance for the selective hydrogenation of FFA to THFA. The 100% conversion of FFA and the 99% selectivity to THFA were obtained under mild reaction conditions (50 °C, 1 MPa, 1 h), using water as a green reaction solvent. The synergistic effect of NiCu alloy ensures the high catalytic activity. The acid sites and oxygen-containing functional groups on the surface of the modified RHPC can enhance the selectivity of THFA. The Ni2Cu1/RHPC catalyst offers good cyclability and regenerability. The current work proposes a simple method for preparing an NiCu bimetallic catalyst. The catalyst exhibits excellent performance in the catalytic hydrogenation of furfural to tetrahydrofurfuryl alcohol, which broadens the application of non-noble metal bimetallic nanocatalysts in the catalytic hydrogenation of furfural. A series of bimetallic Ni Cu catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were prepared using a simple impregnation method for the liquid-phase hydrogenation of furfural (FFA) to tetrahydrofurfuryl alcohol (THFA). The Ni Cu /RHPC catalyst, with an average metal particle size of 9.3 nm, exhibits excellent catalytic performance for the selective hydrogenation of FFA to THFA. The 100% conversion of FFA and the 99% selectivity to THFA were obtained under mild reaction conditions (50 °C, 1 MPa, 1 h), using water as a green reaction solvent. The synergistic effect of NiCu alloy ensures the high catalytic activity. The acid sites and oxygen-containing functional groups on the surface of the modified RHPC can enhance the selectivity of THFA. The Ni Cu /RHPC catalyst offers good cyclability and regenerability. The current work proposes a simple method for preparing an NiCu bimetallic catalyst. The catalyst exhibits excellent performance in the catalytic hydrogenation of furfural to tetrahydrofurfuryl alcohol, which broadens the application of non-noble metal bimetallic nanocatalysts in the catalytic hydrogenation of furfural. A series of bimetallic Ni[sub.x]Cu[sub.y] catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were prepared using a simple impregnation method for the liquid-phase hydrogenation of furfural (FFA) to tetrahydrofurfuryl alcohol (THFA). The Ni[sub.2]Cu[sub.1]/RHPC catalyst, with an average metal particle size of 9.3 nm, exhibits excellent catalytic performance for the selective hydrogenation of FFA to THFA. The 100% conversion of FFA and the 99% selectivity to THFA were obtained under mild reaction conditions (50 °C, 1 MPa, 1 h), using water as a green reaction solvent. The synergistic effect of NiCu alloy ensures the high catalytic activity. The acid sites and oxygen-containing functional groups on the surface of the modified RHPC can enhance the selectivity of THFA. The Ni[sub.2]Cu[sub.1]/RHPC catalyst offers good cyclability and regenerability. The current work proposes a simple method for preparing an NiCu bimetallic catalyst. The catalyst exhibits excellent performance in the catalytic hydrogenation of furfural to tetrahydrofurfuryl alcohol, which broadens the application of non-noble metal bimetallic nanocatalysts in the catalytic hydrogenation of furfural. A series of bimetallic NixCuy catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were prepared using a simple impregnation method for the liquid-phase hydrogenation of furfural (FFA) to tetrahydrofurfuryl alcohol (THFA). The Ni2Cu1/RHPC catalyst, with an average metal particle size of 9.3 nm, exhibits excellent catalytic performance for the selective hydrogenation of FFA to THFA. The 100% conversion of FFA and the 99% selectivity to THFA were obtained under mild reaction conditions (50 °C, 1 MPa, 1 h), using water as a green reaction solvent. The synergistic effect of NiCu alloy ensures the high catalytic activity. The acid sites and oxygen-containing functional groups on the surface of the modified RHPC can enhance the selectivity of THFA. The Ni2Cu1/RHPC catalyst offers good cyclability and regenerability. The current work proposes a simple method for preparing an NiCu bimetallic catalyst. The catalyst exhibits excellent performance in the catalytic hydrogenation of furfural to tetrahydrofurfuryl alcohol, which broadens the application of non-noble metal bimetallic nanocatalysts in the catalytic hydrogenation of furfural.A series of bimetallic NixCuy catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were prepared using a simple impregnation method for the liquid-phase hydrogenation of furfural (FFA) to tetrahydrofurfuryl alcohol (THFA). The Ni2Cu1/RHPC catalyst, with an average metal particle size of 9.3 nm, exhibits excellent catalytic performance for the selective hydrogenation of FFA to THFA. The 100% conversion of FFA and the 99% selectivity to THFA were obtained under mild reaction conditions (50 °C, 1 MPa, 1 h), using water as a green reaction solvent. The synergistic effect of NiCu alloy ensures the high catalytic activity. The acid sites and oxygen-containing functional groups on the surface of the modified RHPC can enhance the selectivity of THFA. The Ni2Cu1/RHPC catalyst offers good cyclability and regenerability. The current work proposes a simple method for preparing an NiCu bimetallic catalyst. The catalyst exhibits excellent performance in the catalytic hydrogenation of furfural to tetrahydrofurfuryl alcohol, which broadens the application of non-noble metal bimetallic nanocatalysts in the catalytic hydrogenation of furfural. A series of bimetallic Ni x Cu y catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were prepared using a simple impregnation method for the liquid-phase hydrogenation of furfural (FFA) to tetrahydrofurfuryl alcohol (THFA). The Ni 2 Cu 1 /RHPC catalyst, with an average metal particle size of 9.3 nm, exhibits excellent catalytic performance for the selective hydrogenation of FFA to THFA. The 100% conversion of FFA and the 99% selectivity to THFA were obtained under mild reaction conditions (50 °C, 1 MPa, 1 h), using water as a green reaction solvent. The synergistic effect of NiCu alloy ensures the high catalytic activity. The acid sites and oxygen-containing functional groups on the surface of the modified RHPC can enhance the selectivity of THFA. The Ni 2 Cu 1 /RHPC catalyst offers good cyclability and regenerability. The current work proposes a simple method for preparing an NiCu bimetallic catalyst. The catalyst exhibits excellent performance in the catalytic hydrogenation of furfural to tetrahydrofurfuryl alcohol, which broadens the application of non-noble metal bimetallic nanocatalysts in the catalytic hydrogenation of furfural. |
| Audience | Academic |
| Author | Ding, Zhiyao Hu, Lianghai Yang, Xiaomin Gao, Yujun |
| AuthorAffiliation | 1 School of Life Sciences, Jilin University, Changchun 130012, China; dingzy17@mails.jlu.edu.cn (Z.D.); yjgao18@mails.jlu.edu.cn (Y.G.) 2 College of Chemistry, Jilin University, Changchun 130012, China |
| AuthorAffiliation_xml | – name: 1 School of Life Sciences, Jilin University, Changchun 130012, China; dingzy17@mails.jlu.edu.cn (Z.D.); yjgao18@mails.jlu.edu.cn (Y.G.) – name: 2 College of Chemistry, Jilin University, Changchun 130012, China |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38893516$$D View this record in MEDLINE/PubMed |
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| Keywords | NiCu bimetallic catalyst tetrahydrofurfuryl alcohol furfural |
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| References | Conner (ref_24) 1978; 15 Nemoshkalenko (ref_25) 1983; 28 Wu (ref_11) 2017; 203 ref_12 Du (ref_30) 2019; 193 Mansour (ref_23) 1994; 3 Xu (ref_17) 2018; 6 Kim (ref_14) 2024; 558 Mansour (ref_22) 1994; 3 Liu (ref_10) 2016; 37 Gong (ref_29) 2017; 5 Banerjee (ref_3) 2018; 122 Mironenko (ref_13) 2015; 249 Nandi (ref_4) 2018; 10 Nakagawa (ref_2) 2012; 4 Li (ref_6) 2016; 192 Liu (ref_15) 2015; 5 Chen (ref_19) 2020; 161 Thongratkaew (ref_7) 2022; 169 Lin (ref_28) 2012; 291 Singh (ref_18) 2012; 258 Seemala (ref_8) 2017; 7 Manfro (ref_5) 2013; 3 Wang (ref_9) 2016; 299 Dube (ref_26) 1995; 142 Chen (ref_1) 2007; 126 Naghash (ref_20) 2006; 18 Liu (ref_16) 2018; 550 Xia (ref_27) 2016; 180 Wu (ref_21) 2014; 6 |
| References_xml | – volume: 4 start-page: 1791 year: 2012 ident: ref_2 article-title: Total Hydrogenation of Furfural over a Silica-Supported Nickel Catalyst Prepared by the Reduction of a Nickel Nitrate Precursor publication-title: ChemCatChem doi: 10.1002/cctc.201200218 – volume: 142 start-page: 3357 year: 1995 ident: ref_26 article-title: Electrodeposition of metal alloy and mixed-oxide films using a single-precursor tetranuclear copper-nickel complex publication-title: J. Electrochem. Soc. doi: 10.1149/1.2049987 – volume: 18 start-page: 2480 year: 2006 ident: ref_20 article-title: XRD and XPS study of Cu-Ni interactions on reduced copper-nickel-aluminum oxide solid solution catalysts publication-title: Chem. Mat. doi: 10.1021/cm051910o – volume: 291 start-page: 149 year: 2012 ident: ref_28 article-title: Deactivation of Ni/TiO2 catalyst in the hydrogenation of nitrobenzene in water and improvement in its stability by coating a layer of hydrophobic carbon publication-title: J. Catal. doi: 10.1016/j.jcat.2012.04.020 – volume: 192 start-page: 171 year: 2016 ident: ref_6 article-title: Characterization and catalytic performance of hydrotalcite-derived Ni-Cu alloy nanoparticles catalysts for steam reforming of 1-methylnaphthalene publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2016.03.052 – volume: 558 start-page: 114025 year: 2024 ident: ref_14 article-title: Effect of physicochemical properties of carbons on the performance of bead-type Pd/C catalysts for furfural hydrogenation publication-title: Mol. Catal. doi: 10.1016/j.mcat.2024.114025 – ident: ref_12 doi: 10.1016/j.ces.2023.119654 – volume: 3 start-page: 1278 year: 2013 ident: ref_5 article-title: Aqueous-phase reforming of glycerol using Ni–Cu catalysts prepared from hydrotalcite-like precursors publication-title: Catal. Sci. Technol. doi: 10.1039/c3cy20770f – volume: 161 start-page: 432 year: 2020 ident: ref_19 article-title: Rice husk-based hierarchical porous carbon for high performance supercapacitors: The structure-performance relationship publication-title: Carbon doi: 10.1016/j.carbon.2020.01.088 – volume: 6 start-page: 8325 year: 2018 ident: ref_17 article-title: Hydrogen from Rice Husk Pyrolysis Volatiles via Non-Noble Ni–Fe Catalysts Supported on Five Differently Treated Rice Husk Pyrolysis Carbon Supports publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.8b00343 – volume: 203 start-page: 227 year: 2017 ident: ref_11 article-title: Efficient and versatile CuNi alloy nanocatalysts for the highly selective hydrogenation of furfural publication-title: Appl Catal B Env. doi: 10.1016/j.apcatb.2016.10.038 – volume: 5 start-page: 66704 year: 2015 ident: ref_15 article-title: Hydrogenation in supercritical conditions catalyzed by palladium supported on modified activated carbon publication-title: Rsc Adv. doi: 10.1039/C5RA14284A – volume: 7 start-page: 4070 year: 2017 ident: ref_8 article-title: Support Induced Control of Surface Composition in Cu–Ni/TiO2 Catalysts Enables High Yield Co-Conversion of HMF and Furfural to Methylated Furans publication-title: ACS Catal. doi: 10.1021/acscatal.7b01095 – volume: 10 start-page: 24480 year: 2018 ident: ref_4 article-title: Hydrogenation of Furfural with Nickel Nanoparticles Stabilized on Nitrogen-Rich Carbon Core-Shell and Its Transformations for the Synthesis of gamma-Valerolactone in Aqueous Conditions publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.8b04239 – volume: 3 start-page: 211 year: 1994 ident: ref_23 article-title: Nickel Mg Kalpha XPS spectra from the Physical Electronics Model 5400 spectrometer publication-title: Surf. Sci. Spectra doi: 10.1116/1.1247749 – volume: 28 start-page: 2182 year: 1983 ident: ref_25 article-title: Study of the charge state of atoms in iron, cobalt and nickel phosphides publication-title: Zhurnal Neorg. Khimii – volume: 193 start-page: 221 year: 2019 ident: ref_30 article-title: Catalytic furfural hydrogenation to furfuryl alcohol over Cu/SiO2 catalysts: A comparative study of the preparation methods publication-title: Fuel Process. Technol. doi: 10.1016/j.fuproc.2019.05.003 – volume: 180 start-page: 408 year: 2016 ident: ref_27 article-title: Hydrogenation of nitrophenols catalyzed by carbon black-supported nickel nanoparticles under mild conditions publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2015.06.043 – volume: 299 start-page: 104 year: 2016 ident: ref_9 article-title: CuNi@C catalysts with high activity derived from metal-organic frameworks precursor for conversion of furfural to cyclopentanone publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2016.04.068 – volume: 122 start-page: 18383 year: 2018 ident: ref_3 article-title: Investigating Reaction Mechanisms for Furfural Hydrodeoxygenation on Ni and the Effect of Boron Doping on the Activity and Selectivity of the Catalyst publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.8b01301 – volume: 126 start-page: 5 year: 2007 ident: ref_1 article-title: Experimental study for liquid phase selective hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol on supported Ni catalysts publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2006.08.019 – volume: 5 start-page: 2172 year: 2017 ident: ref_29 article-title: Efficient Synthesis of Furfuryl Alcohol from H2-Hydrogenation/Transfer Hydrogenation of Furfural Using Sulfonate Group Modified Cu Catalyst publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.6b02343 – volume: 550 start-page: 1 year: 2018 ident: ref_16 article-title: Selective hydrogenation of furfural over Pt based and Pd based bimetallic catalysts supported on modified multiwalled carbon nanotubes (MWNT) publication-title: Appl. Catal. A Gen. doi: 10.1016/j.apcata.2017.10.003 – volume: 37 start-page: 700 year: 2016 ident: ref_10 article-title: Selective hydrogenolysis of biomass-derived furfuryl alcohol into 1,2- and 1,5-pentanediol over highly dispersed Cu-Al2O3 catalysts publication-title: Chin. J. Catal. doi: 10.1016/S1872-2067(15)61080-4 – volume: 6 start-page: 301 year: 2014 ident: ref_21 article-title: In Situ Observation of Cu-Ni Alloy Nanoparticle Formation by X-Ray Diffraction, X-Ray Absorption Spectroscopy, and Transmission Electron Microscopy: Influence of Cu/Ni Ratio publication-title: Chemcatchem doi: 10.1002/cctc.201300628 – volume: 15 start-page: 343 year: 1978 ident: ref_24 article-title: Combination analysis of metal-oxides using esca, aes, and sims publication-title: J. Vac. Sci. Technol. doi: 10.1116/1.569543 – volume: 169 start-page: 106468 year: 2022 ident: ref_7 article-title: Solvent effects in integrated reaction-separation process of liquid-phase hydrogenation of furfural to furfuryl alcohol over CuAl2O4 catalysts publication-title: Catal. Commun. doi: 10.1016/j.catcom.2022.106468 – volume: 258 start-page: 3405 year: 2012 ident: ref_18 article-title: Enhancing the hydrogen storage capacity of Pd-functionalized multi-walled carbon nanotubes publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2011.11.075 – volume: 249 start-page: 145 year: 2015 ident: ref_13 article-title: Effect of the nature of carbon support on the formation of active sites in Pd/C and Ru/C catalysts for hydrogenation of furfural publication-title: Catal. Today doi: 10.1016/j.cattod.2014.10.037 – volume: 3 start-page: 221 year: 1994 ident: ref_22 article-title: Nickel monochromated Al Kalpha XPS spectra from the Physical Electronics Model 5400 spectrometer publication-title: Surf. Sci. Spectra doi: 10.1116/1.1247750 |
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| Snippet | A series of bimetallic NixCuy catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were... A series of bimetallic Ni Cu catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were prepared... A series of bimetallic Ni[sub.x]Cu[sub.y] catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC),... A series of bimetallic Ni x Cu y catalysts with different metal molar ratios, supported on nitric acid modified rice husk-based porous carbon (RHPC), were... |
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| StartPage | 2638 |
| SubjectTerms | Acidification Acids Alcohol Alloys Carbon Catalysts furfural Hydrogenation Nanoparticles NiCu bimetallic catalyst Pore size Precious metals Ratios tetrahydrofurfuryl alcohol |
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| Title | Highly Efficient and Selective Hydrogenation of Biomass-Derived Furfural Using Interface-Active Rice Husk-Based Porous Carbon-Supported NiCu Alloy Catalysts |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/38893516 https://www.proquest.com/docview/3067455653 https://www.proquest.com/docview/3070800759 https://pubmed.ncbi.nlm.nih.gov/PMC11173685 https://doaj.org/article/452baaa796d94289a587c8b7639a2c86 |
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