Synergistic Photocatalytic-Adsorption Removal of Basic Magenta Effect of AgZnO/Polyoxometalates Nanocomposites
The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles and polyoxometalates [Cu(L) 2 (H 2 O)]H 2 [Cu(L) 2 (P 2 Mo 5 O 23 )]⋅4H 2 O (HL = C 6 H 6 N 2 O) into nanostructures via a sonochemical method. Transm...
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Published in | Nanoscale research letters Vol. 16; no. 1; pp. 163 - 12 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
New York
Springer US
10.11.2021
Springer Nature B.V SpringerOpen |
Subjects | |
Online Access | Get full text |
ISSN | 1556-276X 1931-7573 1556-276X |
DOI | 10.1186/s11671-021-03620-0 |
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Abstract | The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles and polyoxometalates [Cu(L)
2
(H
2
O)]H
2
[Cu(L)
2
(P
2
Mo
5
O
23
)]⋅4H
2
O (HL = C
6
H
6
N
2
O) into nanostructures via a sonochemical method. Transmission electron microscopy (TEM) indicated that AgZnO/POMs nanocomposites were uniform with narrow particle size distribution and without agglomeration. X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis confirmed the nanostructure and composition of AgZnO/POMs nanocomposites. The ultraviolet–visible spectra (UV–Vis) and photoluminescence spectra (PL) confirmed excellent optical properties of the AgZnO/POMs nanocomposites. 94.13% ± 0.61 of basic magenta (BM) in aqueous solution could be removed using the AgZnO/POMs nanocomposites through adsorption and photocatalysis. The kinetic analysis showed that both the adsorption and photocatalysis process conform to pseudo-second-order kinetics. In addition, the removal rate of AgZnO/POMs nanocomposites was found to be almost unchanged after 5 cycles of use. The bifunctional photocatalytic-adsorbent AgZnO/POMs nanocomposites with high stability and cycling performance have broad application prospects in the treatment of refractory organic dye wastewater containing triphenylmethane. |
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AbstractList | Abstract The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles and polyoxometalates [Cu(L)2(H2O)]H2[Cu(L)2(P2Mo5O23)]⋅4H2O (HL = C6H6N2O) into nanostructures via a sonochemical method. Transmission electron microscopy (TEM) indicated that AgZnO/POMs nanocomposites were uniform with narrow particle size distribution and without agglomeration. X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis confirmed the nanostructure and composition of AgZnO/POMs nanocomposites. The ultraviolet–visible spectra (UV–Vis) and photoluminescence spectra (PL) confirmed excellent optical properties of the AgZnO/POMs nanocomposites. 94.13% ± 0.61 of basic magenta (BM) in aqueous solution could be removed using the AgZnO/POMs nanocomposites through adsorption and photocatalysis. The kinetic analysis showed that both the adsorption and photocatalysis process conform to pseudo-second-order kinetics. In addition, the removal rate of AgZnO/POMs nanocomposites was found to be almost unchanged after 5 cycles of use. The bifunctional photocatalytic-adsorbent AgZnO/POMs nanocomposites with high stability and cycling performance have broad application prospects in the treatment of refractory organic dye wastewater containing triphenylmethane. The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles and polyoxometalates [Cu(L) 2 (H 2 O)]H 2 [Cu(L) 2 (P 2 Mo 5 O 23 )]⋅4H 2 O (HL = C 6 H 6 N 2 O) into nanostructures via a sonochemical method. Transmission electron microscopy (TEM) indicated that AgZnO/POMs nanocomposites were uniform with narrow particle size distribution and without agglomeration. X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis confirmed the nanostructure and composition of AgZnO/POMs nanocomposites. The ultraviolet–visible spectra (UV–Vis) and photoluminescence spectra (PL) confirmed excellent optical properties of the AgZnO/POMs nanocomposites. 94.13% ± 0.61 of basic magenta (BM) in aqueous solution could be removed using the AgZnO/POMs nanocomposites through adsorption and photocatalysis. The kinetic analysis showed that both the adsorption and photocatalysis process conform to pseudo-second-order kinetics. In addition, the removal rate of AgZnO/POMs nanocomposites was found to be almost unchanged after 5 cycles of use. The bifunctional photocatalytic-adsorbent AgZnO/POMs nanocomposites with high stability and cycling performance have broad application prospects in the treatment of refractory organic dye wastewater containing triphenylmethane. The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles and polyoxometalates [Cu(L)2(H2O)]H2[Cu(L)2(P2Mo5O23)]⋅4H2O (HL = C6H6N2O) into nanostructures via a sonochemical method. Transmission electron microscopy (TEM) indicated that AgZnO/POMs nanocomposites were uniform with narrow particle size distribution and without agglomeration. X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis confirmed the nanostructure and composition of AgZnO/POMs nanocomposites. The ultraviolet–visible spectra (UV–Vis) and photoluminescence spectra (PL) confirmed excellent optical properties of the AgZnO/POMs nanocomposites. 94.13% ± 0.61 of basic magenta (BM) in aqueous solution could be removed using the AgZnO/POMs nanocomposites through adsorption and photocatalysis. The kinetic analysis showed that both the adsorption and photocatalysis process conform to pseudo-second-order kinetics. In addition, the removal rate of AgZnO/POMs nanocomposites was found to be almost unchanged after 5 cycles of use. The bifunctional photocatalytic-adsorbent AgZnO/POMs nanocomposites with high stability and cycling performance have broad application prospects in the treatment of refractory organic dye wastewater containing triphenylmethane. The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles and polyoxometalates [Cu(L)2(H2O)]H2[Cu(L)2(P2Mo5O23)]⋅4H2O (HL = C6H6N2O) into nanostructures via a sonochemical method. Transmission electron microscopy (TEM) indicated that AgZnO/POMs nanocomposites were uniform with narrow particle size distribution and without agglomeration. X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis confirmed the nanostructure and composition of AgZnO/POMs nanocomposites. The ultraviolet-visible spectra (UV-Vis) and photoluminescence spectra (PL) confirmed excellent optical properties of the AgZnO/POMs nanocomposites. 94.13% ± 0.61 of basic magenta (BM) in aqueous solution could be removed using the AgZnO/POMs nanocomposites through adsorption and photocatalysis. The kinetic analysis showed that both the adsorption and photocatalysis process conform to pseudo-second-order kinetics. In addition, the removal rate of AgZnO/POMs nanocomposites was found to be almost unchanged after 5 cycles of use. The bifunctional photocatalytic-adsorbent AgZnO/POMs nanocomposites with high stability and cycling performance have broad application prospects in the treatment of refractory organic dye wastewater containing triphenylmethane.The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles and polyoxometalates [Cu(L)2(H2O)]H2[Cu(L)2(P2Mo5O23)]⋅4H2O (HL = C6H6N2O) into nanostructures via a sonochemical method. Transmission electron microscopy (TEM) indicated that AgZnO/POMs nanocomposites were uniform with narrow particle size distribution and without agglomeration. X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis confirmed the nanostructure and composition of AgZnO/POMs nanocomposites. The ultraviolet-visible spectra (UV-Vis) and photoluminescence spectra (PL) confirmed excellent optical properties of the AgZnO/POMs nanocomposites. 94.13% ± 0.61 of basic magenta (BM) in aqueous solution could be removed using the AgZnO/POMs nanocomposites through adsorption and photocatalysis. The kinetic analysis showed that both the adsorption and photocatalysis process conform to pseudo-second-order kinetics. In addition, the removal rate of AgZnO/POMs nanocomposites was found to be almost unchanged after 5 cycles of use. The bifunctional photocatalytic-adsorbent AgZnO/POMs nanocomposites with high stability and cycling performance have broad application prospects in the treatment of refractory organic dye wastewater containing triphenylmethane. |
ArticleNumber | 163 |
Author | Zhang, Ke Tian, Heyun Ma, Chenguang Qi, Yiyi Liu, Hongling Luo, Jie Li, Mingxue Zhan, Shixia Liu, Xiao |
Author_xml | – sequence: 1 givenname: Heyun surname: Tian fullname: Tian, Heyun organization: Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University – sequence: 2 givenname: Jie surname: Luo fullname: Luo, Jie organization: Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University – sequence: 3 givenname: Ke surname: Zhang fullname: Zhang, Ke organization: Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University – sequence: 4 givenname: Chenguang surname: Ma fullname: Ma, Chenguang organization: Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University – sequence: 5 givenname: Yiyi surname: Qi fullname: Qi, Yiyi organization: Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University – sequence: 6 givenname: Shixia surname: Zhan fullname: Zhan, Shixia organization: Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University – sequence: 7 givenname: Xiao surname: Liu fullname: Liu, Xiao email: liuxiao0337@henu.edu.cn organization: Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University – sequence: 8 givenname: Mingxue surname: Li fullname: Li, Mingxue email: limingxue@henu.edu.cn organization: Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University – sequence: 9 givenname: Hongling orcidid: 0000-0002-8005-8477 surname: Liu fullname: Liu, Hongling email: hlliu@henu.edu.cn organization: Key Lab of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University |
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CitedBy_id | crossref_primary_10_1016_j_inoche_2024_112231 crossref_primary_10_1016_j_apsusc_2022_156310 crossref_primary_10_1039_D2RA07543A crossref_primary_10_1039_D2AY00934J crossref_primary_10_1021_acs_langmuir_4c03784 crossref_primary_10_2139_ssrn_4107515 crossref_primary_10_1016_j_jssc_2022_123513 |
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Keywords | Photocatalytic Nanocomposites Adsorption Basic magenta removal AgZnO/polyoxometalates |
Language | English |
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Snippet | The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles and... Abstract The bifunctional photocatalytic-adsorbent AgZnO/polyoxometalates (AgZnO/POMs) nanocomposites were synthesized by combining AgZnO hybrid nanoparticles... |
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SubjectTerms | Adsorbents Adsorption AgZnO/polyoxometalates Aqueous solutions Basic magenta removal Chemistry and Materials Science Dyes Industrial wastewater Materials Science Molecular Medicine Nano Express Nanochemistry Nanocomposites Nanoparticles Nanoscale Science and Technology Nanostructure Nanotechnology Nanotechnology and Microengineering Optical properties Particle size distribution Photocatalysis Photocatalytic Photoelectron spectroscopy Photoelectrons Photoluminescence Photons Polyoxometallates Size distribution Sonochemical reactions Spectrum analysis Transmission electron microscopy Ultraviolet spectra Wastewater X ray photoelectron spectroscopy X ray powder diffraction |
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Title | Synergistic Photocatalytic-Adsorption Removal of Basic Magenta Effect of AgZnO/Polyoxometalates Nanocomposites |
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