Enhanced carbon dioxide conversion at ambient conditions via a pore enrichment effect
Chemical fixation of carbon dioxide (CO 2 ) may be a pathway to retard the current trend of rapid global warming. However, the current economic cost of chemical fixation remains high because the chemical fixation of CO 2 usually requires high temperature or high pressure. The rational design of an e...
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| Published in | Nature communications Vol. 11; no. 1; pp. 4481 - 9 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
08.09.2020
Nature Publishing Group Nature Portfolio |
| Subjects | |
| Online Access | Get full text |
| ISSN | 2041-1723 2041-1723 |
| DOI | 10.1038/s41467-020-18154-9 |
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| Abstract | Chemical fixation of carbon dioxide (CO
2
) may be a pathway to retard the current trend of rapid global warming. However, the current economic cost of chemical fixation remains high because the chemical fixation of CO
2
usually requires high temperature or high pressure. The rational design of an efficient catalyst that works at ambient conditions might substantially reduce the economic cost of fixation. Here, we report the rational design of covalent organic frameworks (COFs) as efficient CO
2
fixation catalysts under ambient conditions based on the finding of “pore enrichment”, which is concluded by a detailed investigation of the 10994 COFs. The best predicted COF, Zn-Salen-COF-SDU113, is synthesized, and its efficient catalytic performance for CO
2
cycloaddition to terminal epoxide is confirmed with a yield of 98.2% and turnover number (TON) of 3068.9 under ambient conditions, which is comparable to the reported leading catalysts. Moreover, this COF achieves the cycloaddition of CO
2
to 2,3-epoxybutane under ambient conditions among all porous materials. This work provides a strategy for designing porous catalysts in the economic fixation of carbon dioxide.
Currently the cost of CO
2
chemical fixation remains high because of harsh reaction conditions. Here, the authors report a covalent organic framework screened from 10994 candidates as the efficient CO
2
fixation catalyst under ambient conditions based on the finding of a “pore enrichment effect”. |
|---|---|
| AbstractList | Chemical fixation of carbon dioxide (CO
2
) may be a pathway to retard the current trend of rapid global warming. However, the current economic cost of chemical fixation remains high because the chemical fixation of CO
2
usually requires high temperature or high pressure. The rational design of an efficient catalyst that works at ambient conditions might substantially reduce the economic cost of fixation. Here, we report the rational design of covalent organic frameworks (COFs) as efficient CO
2
fixation catalysts under ambient conditions based on the finding of “pore enrichment”, which is concluded by a detailed investigation of the 10994 COFs. The best predicted COF, Zn-Salen-COF-SDU113, is synthesized, and its efficient catalytic performance for CO
2
cycloaddition to terminal epoxide is confirmed with a yield of 98.2% and turnover number (TON) of 3068.9 under ambient conditions, which is comparable to the reported leading catalysts. Moreover, this COF achieves the cycloaddition of CO
2
to 2,3-epoxybutane under ambient conditions among all porous materials. This work provides a strategy for designing porous catalysts in the economic fixation of carbon dioxide.
Currently the cost of CO
2
chemical fixation remains high because of harsh reaction conditions. Here, the authors report a covalent organic framework screened from 10994 candidates as the efficient CO
2
fixation catalyst under ambient conditions based on the finding of a “pore enrichment effect”. Chemical fixation of carbon dioxide (CO2) may be a pathway to retard the current trend of rapid global warming. However, the current economic cost of chemical fixation remains high because the chemical fixation of CO2 usually requires high temperature or high pressure. The rational design of an efficient catalyst that works at ambient conditions might substantially reduce the economic cost of fixation. Here, we report the rational design of covalent organic frameworks (COFs) as efficient CO2 fixation catalysts under ambient conditions based on the finding of “pore enrichment”, which is concluded by a detailed investigation of the 10994 COFs. The best predicted COF, Zn-Salen-COF-SDU113, is synthesized, and its efficient catalytic performance for CO2 cycloaddition to terminal epoxide is confirmed with a yield of 98.2% and turnover number (TON) of 3068.9 under ambient conditions, which is comparable to the reported leading catalysts. Moreover, this COF achieves the cycloaddition of CO2 to 2,3-epoxybutane under ambient conditions among all porous materials. This work provides a strategy for designing porous catalysts in the economic fixation of carbon dioxide.Currently the cost of CO2 chemical fixation remains high because of harsh reaction conditions. Here, the authors report a covalent organic framework screened from 10994 candidates as the efficient CO2 fixation catalyst under ambient conditions based on the finding of a “pore enrichment effect”. Currently the cost of CO2 chemical fixation remains high because of harsh reaction conditions. Here, the authors report a covalent organic framework screened from 10994 candidates as the efficient CO2 fixation catalyst under ambient conditions based on the finding of a “pore enrichment effect”. Chemical fixation of carbon dioxide (CO 2 ) may be a pathway to retard the current trend of rapid global warming. However, the current economic cost of chemical fixation remains high because the chemical fixation of CO 2 usually requires high temperature or high pressure. The rational design of an efficient catalyst that works at ambient conditions might substantially reduce the economic cost of fixation. Here, we report the rational design of covalent organic frameworks (COFs) as efficient CO 2 fixation catalysts under ambient conditions based on the finding of “pore enrichment”, which is concluded by a detailed investigation of the 10994 COFs. The best predicted COF, Zn-Salen-COF-SDU113, is synthesized, and its efficient catalytic performance for CO 2 cycloaddition to terminal epoxide is confirmed with a yield of 98.2% and turnover number (TON) of 3068.9 under ambient conditions, which is comparable to the reported leading catalysts. Moreover, this COF achieves the cycloaddition of CO 2 to 2,3-epoxybutane under ambient conditions among all porous materials. This work provides a strategy for designing porous catalysts in the economic fixation of carbon dioxide. Chemical fixation of carbon dioxide (CO2) may be a pathway to retard the current trend of rapid global warming. However, the current economic cost of chemical fixation remains high because the chemical fixation of CO2 usually requires high temperature or high pressure. The rational design of an efficient catalyst that works at ambient conditions might substantially reduce the economic cost of fixation. Here, we report the rational design of covalent organic frameworks (COFs) as efficient CO2 fixation catalysts under ambient conditions based on the finding of "pore enrichment", which is concluded by a detailed investigation of the 10994 COFs. The best predicted COF, Zn-Salen-COF-SDU113, is synthesized, and its efficient catalytic performance for CO2 cycloaddition to terminal epoxide is confirmed with a yield of 98.2% and turnover number (TON) of 3068.9 under ambient conditions, which is comparable to the reported leading catalysts. Moreover, this COF achieves the cycloaddition of CO2 to 2,3-epoxybutane under ambient conditions among all porous materials. This work provides a strategy for designing porous catalysts in the economic fixation of carbon dioxide.Chemical fixation of carbon dioxide (CO2) may be a pathway to retard the current trend of rapid global warming. However, the current economic cost of chemical fixation remains high because the chemical fixation of CO2 usually requires high temperature or high pressure. The rational design of an efficient catalyst that works at ambient conditions might substantially reduce the economic cost of fixation. Here, we report the rational design of covalent organic frameworks (COFs) as efficient CO2 fixation catalysts under ambient conditions based on the finding of "pore enrichment", which is concluded by a detailed investigation of the 10994 COFs. The best predicted COF, Zn-Salen-COF-SDU113, is synthesized, and its efficient catalytic performance for CO2 cycloaddition to terminal epoxide is confirmed with a yield of 98.2% and turnover number (TON) of 3068.9 under ambient conditions, which is comparable to the reported leading catalysts. Moreover, this COF achieves the cycloaddition of CO2 to 2,3-epoxybutane under ambient conditions among all porous materials. This work provides a strategy for designing porous catalysts in the economic fixation of carbon dioxide. |
| ArticleNumber | 4481 |
| Author | Zhou, Yi-Hong Yang, Li Zhai, Dong Deng, Qi-Wen Ren, Guo-Qing Sun, Lei Zhou, Wei Deng, Wei-Qiao Li, Yi-Meng |
| Author_xml | – sequence: 1 givenname: Wei surname: Zhou fullname: Zhou, Wei organization: Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University – sequence: 2 givenname: Qi-Wen surname: Deng fullname: Deng, Qi-Wen organization: Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Collage of Hydraulic & Environmental Engineering, China Three Gorges University – sequence: 3 givenname: Guo-Qing orcidid: 0000-0002-0278-0018 surname: Ren fullname: Ren, Guo-Qing organization: Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University – sequence: 4 givenname: Lei orcidid: 0000-0001-9960-205X surname: Sun fullname: Sun, Lei email: slei@sdu.edu.cn organization: Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University – sequence: 5 givenname: Li orcidid: 0000-0001-6570-5704 surname: Yang fullname: Yang, Li organization: Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, State Key Laboratory of Molecular Reaction Dynamics, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, University of the Chinese Academy of Sciences – sequence: 6 givenname: Yi-Meng surname: Li fullname: Li, Yi-Meng organization: Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University – sequence: 7 givenname: Dong orcidid: 0000-0003-3155-4607 surname: Zhai fullname: Zhai, Dong organization: Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University – sequence: 8 givenname: Yi-Hong surname: Zhou fullname: Zhou, Yi-Hong organization: Collage of Hydraulic & Environmental Engineering, China Three Gorges University – sequence: 9 givenname: Wei-Qiao orcidid: 0000-0002-3671-5951 surname: Deng fullname: Deng, Wei-Qiao email: dengwq@sdu.edu.cn organization: Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, State Key Laboratory of Molecular Reaction Dynamics, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences |
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| Snippet | Chemical fixation of carbon dioxide (CO
2
) may be a pathway to retard the current trend of rapid global warming. However, the current economic cost of... Chemical fixation of carbon dioxide (CO2) may be a pathway to retard the current trend of rapid global warming. However, the current economic cost of chemical... Currently the cost of CO2 chemical fixation remains high because of harsh reaction conditions. Here, the authors report a covalent organic framework screened... |
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| SubjectTerms | 119/118 140/131 147/135 639/638/563/981 639/638/77/884 639/638/77/887 Carbon dioxide Carbon dioxide fixation Carbon sequestration Catalysts Chemical synthesis Climate change Cycloaddition Economic impact Economics Enrichment Global warming High pressure High temperature Humanities and Social Sciences multidisciplinary Porous materials Science Science (multidisciplinary) Temperature requirements |
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| Title | Enhanced carbon dioxide conversion at ambient conditions via a pore enrichment effect |
| URI | https://link.springer.com/article/10.1038/s41467-020-18154-9 https://www.proquest.com/docview/2440762892 https://www.proquest.com/docview/2441263916 https://pubmed.ncbi.nlm.nih.gov/PMC7479596 https://doaj.org/article/8969462bf4bd437d92dc060710056191 |
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