Model structures for C‐(A)‐S‐H(I)

• Published in: Acta crystallographica Section B, Structural science, crystal engineering and materials Vol. 70; no. 6; pp. 903 - 923
• Main Author: Richardson, Ian G.
• Format: Journal Article
• Language: English
• Published: 5 Abbey Square, Chester, Cheshire CH1 2HU, England International Union of Crystallography 01.12.2014; Blackwell Publishing Ltd
• Subjects: Anions; binding phase; Calcium; cement‐based concrete; Chemical compounds; Crystal structure; Crystallography; Hydrates; tobermorite; tobermorite; binding phase; cement-based concrete
• ISSN: 2052-5206; 2052-5192; 2052-5206
• DOI: 10.1107/S2052520614021982

C‐(A)‐S‐H(I) is a calcium silicate hydrate that is studied extensively as a model for the main binding phase in concrete. It is a structurally imperfect form of 14 Å tobermorite that has variable composition and length of (alumino)silicate anions. New structural–chemical formulae are presented for single‐ and double‐chain tobermorite‐based phases and equations are provided that can be used to calculate a number of useful quantities from 29Si NMR data. It is shown that there are no interlayer calcium ions when the silicate chains are of infinite length and that one is added for each tetrahedral `bridging' site that is vacant. Preparations that have Ca/Si greater than about 1.4 include an intermixed Ca‐rich phase. It is not possible to generate a structural model for a dimer that is crystal‐chemically consistent with known calcium silicate hydrates if the starting structure is an orthotobermorite, i.e. of the type that has been used in all previous studies. Crystal‐chemically plausible models are developed that are based instead on clinotobermorite. A number of models that represent different mean chain lengths are developed using crystal‐chemical and geometrical reasoning. The models account for experimental observations, including variations in Ca/Si, H2O/Si, (alumino)silicate anion structure and layer spacing.