Effect of drying rate on mesoporous silica morphology templated from PEO-PPO-PEO block copolymer assemblies
The authors have shown that the rapid drying process of the nanocomplex of silicate and pluronics is favorable for the formation of closed nanopores, where the enclosure of the pores is promoted due to the solidification of silica prior to the formation of the liquid crystalline phase of pluronics m...
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Published in | Journal of Materials Science Vol. 39; no. 12; pp. 4045 - 4047 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Heidelberg
Springer Science and Business Media LLC
01.06.2004
Springer Springer Nature B.V |
Subjects | |
Online Access | Get full text |
ISSN | 0022-2461 1573-4803 |
DOI | 10.1023/b:jmsc.0000031492.71835.2b |
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Abstract | The authors have shown that the rapid drying process of the nanocomplex of silicate and pluronics is favorable for the formation of closed nanopores, where the enclosure of the pores is promoted due to the solidification of silica prior to the formation of the liquid crystalline phase of pluronics molecular assemblies Here, we report the effect of drying rate on the morphology of mesoporous silicas templated from the pluronic triblock copolymer aggregates, and the formation of closed pores in the mesoscopic structure of the silica. |
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AbstractList | The authors have shown that the rapid drying process of the nanocomplex of silicate and pluronics is favorable for the formation of closed nanopores, where the enclosure of the pores is promoted due to the solidification of silica prior to the formation of the liquid crystalline phase of pluronics molecular assemblies Here, we report the effect of drying rate on the morphology of mesoporous silicas templated from the pluronic triblock copolymer aggregates, and the formation of closed pores in the mesoscopic structure of the silica. |
Author | Kurumada, KI Susa, K Tanigaki, M Hiro, M Pei, L |
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Cites_doi | 10.1016/S0254-0584(02)00340-1 10.1021/cm0101069 10.1039/b000603n 10.1021/ja974025i 10.1126/science.286.5439.421 10.1126/science.279.5350.548 |
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Keywords | Triblock copolymer Transmission electron microscopy Non ionic surfactant Adsorption isotherm Desorption isotherm Propylene oxide copolymer Nitrogen Ethylene oxide copolymer Porous material Silica Mesoporosity Drying |
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References | R. D. Miller (5276687_CR1) 1999; 286 D. Zhao (5276687_CR3) 1998; 120 W. Luckens Jr. (5276687_CR6) 1999; 15 D. Zhao (5276687_CR2) 1998; 279 5276687_CR4 C. Yu (5276687_CR7) 2000; 7 M. Kruk (5276687_CR5) 2001; 13 J. Jiu (5276687_CR8) 2002; 78 |
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SubjectTerms | Block copolymers Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry Materials science Morphology Porous materials Silicon dioxide |
Title | Effect of drying rate on mesoporous silica morphology templated from PEO-PPO-PEO block copolymer assemblies |
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