High-temperature martensitic transformation of CuNiHfTiZr high- entropy alloys
One of the major challenges of near-equiatomic NiTi shape memory alloys is their limitation for high-temperature applications. To overcome this barrier, researchers have tried to enhance the transformation temperatures by addition of alloying elements or even by introducing the concept of high-entro...
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| Published in | Scientific reports Vol. 9; no. 1; pp. 19598 - 7 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
20.12.2019
Nature Publishing Group |
| Subjects | |
| Online Access | Get full text |
| ISSN | 2045-2322 2045-2322 |
| DOI | 10.1038/s41598-019-55762-y |
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| Abstract | One of the major challenges of near-equiatomic NiTi shape memory alloys is their limitation for high-temperature applications. To overcome this barrier, researchers have tried to enhance the transformation temperatures by addition of alloying elements or even by introducing the concept of high-entropy alloys (HEAs). In this study, the CuNiHfTiZr HEAs were developed for high-temperature shape memory effect. Based on their solubility and electron configurations, the alloying elements are divided into two groups, (CuNi)
50
and (HfTiZr)
50
. The content of Cu in (CuNi)
50
is modulated to investigate the influences of Cu on martensitic transformation of the HEAs by studying structural evolution and transformation behavior. The results of x-ray diffraction and thermal expansion tests revealed that Cu
15
Ni
35
Hf
16.67
Ti
16.67
Zr
16.67
possesses high transformation temperature, narrow hysteresis temperature loops, and good dimensional stability within this HEA system. |
|---|---|
| AbstractList | One of the major challenges of near-equiatomic NiTi shape memory alloys is their limitation for high-temperature applications. To overcome this barrier, researchers have tried to enhance the transformation temperatures by addition of alloying elements or even by introducing the concept of high-entropy alloys (HEAs). In this study, the CuNiHfTiZr HEAs were developed for high-temperature shape memory effect. Based on their solubility and electron configurations, the alloying elements are divided into two groups, (CuNi)50 and (HfTiZr)50. The content of Cu in (CuNi)50 is modulated to investigate the influences of Cu on martensitic transformation of the HEAs by studying structural evolution and transformation behavior. The results of x-ray diffraction and thermal expansion tests revealed that Cu15Ni35Hf16.67Ti16.67Zr16.67 possesses high transformation temperature, narrow hysteresis temperature loops, and good dimensional stability within this HEA system.One of the major challenges of near-equiatomic NiTi shape memory alloys is their limitation for high-temperature applications. To overcome this barrier, researchers have tried to enhance the transformation temperatures by addition of alloying elements or even by introducing the concept of high-entropy alloys (HEAs). In this study, the CuNiHfTiZr HEAs were developed for high-temperature shape memory effect. Based on their solubility and electron configurations, the alloying elements are divided into two groups, (CuNi)50 and (HfTiZr)50. The content of Cu in (CuNi)50 is modulated to investigate the influences of Cu on martensitic transformation of the HEAs by studying structural evolution and transformation behavior. The results of x-ray diffraction and thermal expansion tests revealed that Cu15Ni35Hf16.67Ti16.67Zr16.67 possesses high transformation temperature, narrow hysteresis temperature loops, and good dimensional stability within this HEA system. One of the major challenges of near-equiatomic NiTi shape memory alloys is their limitation for high-temperature applications. To overcome this barrier, researchers have tried to enhance the transformation temperatures by addition of alloying elements or even by introducing the concept of high-entropy alloys (HEAs). In this study, the CuNiHfTiZr HEAs were developed for high-temperature shape memory effect. Based on their solubility and electron configurations, the alloying elements are divided into two groups, (CuNi) 50 and (HfTiZr) 50 . The content of Cu in (CuNi) 50 is modulated to investigate the influences of Cu on martensitic transformation of the HEAs by studying structural evolution and transformation behavior. The results of x-ray diffraction and thermal expansion tests revealed that Cu 15 Ni 35 Hf 16.67 Ti 16.67 Zr 16.67 possesses high transformation temperature, narrow hysteresis temperature loops, and good dimensional stability within this HEA system. One of the major challenges of near-equiatomic NiTi shape memory alloys is their limitation for high-temperature applications. To overcome this barrier, researchers have tried to enhance the transformation temperatures by addition of alloying elements or even by introducing the concept of high-entropy alloys (HEAs). In this study, the CuNiHfTiZr HEAs were developed for high-temperature shape memory effect. Based on their solubility and electron configurations, the alloying elements are divided into two groups, (CuNi)50 and (HfTiZr)50. The content of Cu in (CuNi)50 is modulated to investigate the influences of Cu on martensitic transformation of the HEAs by studying structural evolution and transformation behavior. The results of x-ray diffraction and thermal expansion tests revealed that Cu15Ni35Hf16.67Ti16.67Zr16.67 possesses high transformation temperature, narrow hysteresis temperature loops, and good dimensional stability within this HEA system. One of the major challenges of near-equiatomic NiTi shape memory alloys is their limitation for high-temperature applications. To overcome this barrier, researchers have tried to enhance the transformation temperatures by addition of alloying elements or even by introducing the concept of high-entropy alloys (HEAs). In this study, the CuNiHfTiZr HEAs were developed for high-temperature shape memory effect. Based on their solubility and electron configurations, the alloying elements are divided into two groups, (CuNi) and (HfTiZr) . The content of Cu in (CuNi) is modulated to investigate the influences of Cu on martensitic transformation of the HEAs by studying structural evolution and transformation behavior. The results of x-ray diffraction and thermal expansion tests revealed that Cu Ni Hf Ti Zr possesses high transformation temperature, narrow hysteresis temperature loops, and good dimensional stability within this HEA system. |
| ArticleNumber | 19598 |
| Author | Chang, Shan-Hsiu Tsai, Che-Wei Lin, Po-Ting |
| Author_xml | – sequence: 1 givenname: Shan-Hsiu surname: Chang fullname: Chang, Shan-Hsiu organization: Department of Materials Science and Engineering, National Tsing Hua University – sequence: 2 givenname: Po-Ting surname: Lin fullname: Lin, Po-Ting organization: Department of Materials Science and Engineering, National Tsing Hua University, High Entropy Materials Center, National Tsing Hua University – sequence: 3 givenname: Che-Wei surname: Tsai fullname: Tsai, Che-Wei email: chewei@mx.nthu.edu.tw organization: Department of Materials Science and Engineering, National Tsing Hua University, High Entropy Materials Center, National Tsing Hua University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31863027$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1016/j.pmatsci.2004.10.001 10.1016/j.electacta.2008.08.001 10.1016/j.jallcom.2016.09.023 10.1007/s40830-015-0039-7 10.1002/adem.200300567 10.3166/acsm.31.633-648 10.1016/j.scriptamat.2018.08.019 10.1016/S0921-5093(99)00294-4 10.1051/matecconf/20153306006 10.1016/S1000-9361(07)60024-7 10.1016/S0921-5093(99)00303-2 10.1016/S0925-8388(03)00268-8 10.1115/1.2816006 10.1007/s12540-016-6034-5 10.1179/095066001771048745 10.1016/j.matpr.2015.07.335 10.4028/www.scientific.net/MSFo.81-82.207 10.1179/095066010X12646898728363 |
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| SubjectTerms | 639/301/1023/1026 639/301/930/1032 Alloys High temperature Humanities and Social Sciences multidisciplinary Science Science (multidisciplinary) Temperature Thermal expansion X-ray diffraction |
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| Title | High-temperature martensitic transformation of CuNiHfTiZr high- entropy alloys |
| URI | https://link.springer.com/article/10.1038/s41598-019-55762-y https://www.ncbi.nlm.nih.gov/pubmed/31863027 https://www.proquest.com/docview/2329323877 https://www.proquest.com/docview/2329731152 https://pubmed.ncbi.nlm.nih.gov/PMC6925220 |
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