Portevin-Le Chatelier mechanism in face-centered-cubic metallic alloys from low to high entropy
Serration phenomena during tensile testing on certain alloys with diffusing solute atoms (i.e., Portevin–Le Chatelier effect) have been observed for a long time, but detailed mechanisms are not fully clear yet. This study is intended to find the mechanism from different approaches verified by tensil...
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| Published in | International journal of plasticity Vol. 122; no. C; pp. 212 - 224 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Elsevier Ltd
01.11.2019
Elsevier BV Elsevier |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0749-6419 1879-2154 |
| DOI | 10.1016/j.ijplas.2019.07.003 |
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| Abstract | Serration phenomena during tensile testing on certain alloys with diffusing solute atoms (i.e., Portevin–Le Chatelier effect) have been observed for a long time, but detailed mechanisms are not fully clear yet. This study is intended to find the mechanism from different approaches verified by tensile testing on a series of single-phase face-centered-cubic (FCC) pure metal and alloys: Ni, CoNi, CoFeNi, CoCrFeNi, and CoCrFeMnNi, which range from low to high configurational entropy. The results of tensile tests, at strain rates from 1 × 10−5 to 1 × 10−2/s and temperature from room temperature to 700 °C, show that serrations occur on stress-strain curves of CoFeNi, CoCrFeNi, and CoCrFeMnNi alloys in their specific temperature and strain-rate regime. A mechanism for dislocation pinning is proposed and verified with theoretical calculation for the present substitutional alloys. The proposed mechanism involves the in-situ rearrangement of substitutional solute atoms by “local dislocation-core diffusion” and might also be applied to similar substitutional alloys.
[Display omitted]
•PLC effect and its trend are identified in Ni, CoNi, CoFeNi, CoFeNiCr, and CoCrFeMnNi alloys from low to high entropy.•Actual mechanism of PLC effect relating with in-situ dislocation pinning by dislocation-core diffusion is proved.•The mechanism could be generalized to substitutional solid solution alloys. |
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| AbstractList | Serration phenomena during tensile testing on certain alloys with diffusing solute atoms (i.e., Portevin–Le Chatelier effect) have been observed for a long time, but detailed mechanisms are not fully clear yet. This study is intended to find the mechanism from different approaches verified by tensile testing on a series of single-phase face-centered-cubic (FCC) pure metal and alloys: Ni, CoNi, CoFeNi, CoCrFeNi, and CoCrFeMnNi, which range from low to high configurational entropy. The results of tensile tests, at strain rates from 1 × 10−5 to 1 × 10−2/s and temperature from room temperature to 700 °C, show that serrations occur on stress-strain curves of CoFeNi, CoCrFeNi, and CoCrFeMnNi alloys in their specific temperature and strain-rate regime. A mechanism for dislocation pinning is proposed and verified with theoretical calculation for the present substitutional alloys. The proposed mechanism involves the in-situ rearrangement of substitutional solute atoms by "local dislocation-core diffusion" and might also be applied to similar substitutional alloys. Serration phenomena during tensile testing on certain alloys with diffusing solute atoms (i.e., Portevin–Le Chatelier effect) have been observed for a long time, but detailed mechanisms are not fully clear yet. This study is intended to find the mechanism from different approaches verified by tensile testing on a series of single-phase face-centered-cubic (FCC) pure metal and alloys: Ni, CoNi, CoFeNi, CoCrFeNi, and CoCrFeMnNi, which range from low to high configurational entropy. The results of tensile tests, at strain rates from 1 × 10−5 to 1 × 10−2/s and temperature from room temperature to 700 °C, show that serrations occur on stress-strain curves of CoFeNi, CoCrFeNi, and CoCrFeMnNi alloys in their specific temperature and strain-rate regime. A mechanism for dislocation pinning is proposed and verified with theoretical calculation for the present substitutional alloys. The proposed mechanism involves the in-situ rearrangement of substitutional solute atoms by “local dislocation-core diffusion” and might also be applied to similar substitutional alloys. [Display omitted] •PLC effect and its trend are identified in Ni, CoNi, CoFeNi, CoFeNiCr, and CoCrFeMnNi alloys from low to high entropy.•Actual mechanism of PLC effect relating with in-situ dislocation pinning by dislocation-core diffusion is proved.•The mechanism could be generalized to substitutional solid solution alloys. |
| Author | Brinkman, Braden A.W. Liaw, Peter K. Carroll, Robert Lee, Chi Lin, Po-Ting Xie, Xie LeBlanc, Michael Chen, Shuying Tsai, Che-Wei Yeh, Jien-Wei Dahmen, Karin A. |
| Author_xml | – sequence: 1 givenname: Che-Wei surname: Tsai fullname: Tsai, Che-Wei organization: Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, 30013, Taiwan – sequence: 2 givenname: Chi surname: Lee fullname: Lee, Chi organization: Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, 30013, Taiwan – sequence: 3 givenname: Po-Ting surname: Lin fullname: Lin, Po-Ting organization: Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, 30013, Taiwan – sequence: 4 givenname: Xie surname: Xie fullname: Xie, Xie organization: Department of Materials Science and Engineering, The University of Tennessee-Knoxville, Knoxville, TN, 37996, USA – sequence: 5 givenname: Shuying surname: Chen fullname: Chen, Shuying organization: Department of Materials Science and Engineering, The University of Tennessee-Knoxville, Knoxville, TN, 37996, USA – sequence: 6 givenname: Robert surname: Carroll fullname: Carroll, Robert organization: Department of Physics, University of Illinois at Urbana-Champaign, 1110 West Green Street, Urbana, IL, 61801, USA – sequence: 7 givenname: Michael surname: LeBlanc fullname: LeBlanc, Michael organization: Department of Physics, University of Illinois at Urbana-Champaign, 1110 West Green Street, Urbana, IL, 61801, USA – sequence: 8 givenname: Braden A.W. surname: Brinkman fullname: Brinkman, Braden A.W. organization: Department of Applied Mathematics, University of Washington, Seattle, WA, 98195, USA – sequence: 9 givenname: Peter K. surname: Liaw fullname: Liaw, Peter K. email: pliaw@utk.edu organization: High Entropy Materials Center, National Tsing Hua University, Hsinchu, 30013, Taiwan – sequence: 10 givenname: Karin A. surname: Dahmen fullname: Dahmen, Karin A. email: dahmen@illinois.edu organization: Department of Physics, University of Illinois at Urbana-Champaign, 1110 West Green Street, Urbana, IL, 61801, USA – sequence: 11 givenname: Jien-Wei surname: Yeh fullname: Yeh, Jien-Wei email: jwyeh@mx.nthu.edu.tw organization: Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, 30013, Taiwan |
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| Keywords | Serration mechanism Substitutional alloy Portevin-Le Chatelier effect Medium-entropy alloy High-entropy alloy |
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| SubjectTerms | Diffusion Dislocation pinning Face centered cubic lattice High entropy alloys High-entropy alloy Medium-entropy alloy Nickel Portevin-Le Chatelier effect Room temperature Serration mechanism Solutes Strain rate Stress-strain curves Substitutional alloy Tensile tests |
| Title | Portevin-Le Chatelier mechanism in face-centered-cubic metallic alloys from low to high entropy |
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