State‐of‐Charge Distribution of Single‐Crystalline NMC532 Cathodes in Lithium‐Ion Batteries: A Critical Look at the Mesoscale
The electrochemical response of layered lithium transition metal oxides LiMO2 [M=Ni, Mn, Co; e. g., Li(Ni0.5Mn0.3Co0.2)O2 (NMC532)] with single‐crystalline architecture to slow and fast charging protocols and the implication of incomplete and heterogeneous redox reactions on the active material util...
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| Published in | ChemSusChem Vol. 15; no. 21; pp. e202201169 - n/a |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
08.11.2022
John Wiley and Sons Inc |
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| Online Access | Get full text |
| ISSN | 1864-5631 1864-564X 1864-564X |
| DOI | 10.1002/cssc.202201169 |
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| Abstract | The electrochemical response of layered lithium transition metal oxides LiMO2 [M=Ni, Mn, Co; e. g., Li(Ni0.5Mn0.3Co0.2)O2 (NMC532)] with single‐crystalline architecture to slow and fast charging protocols and the implication of incomplete and heterogeneous redox reactions on the active material utilization during cycling were the subject of this work. The role of the active material size and the influence of the local microstructural and chemical ramifications in the composite electrode on the evolution of heterogeneous state of charge (SOC) distribution were deciphered. For this, classification‐single‐particle inductively coupled plasma optical emission spectroscopy (CL‐SP‐ICP‐OES) was comprehensively supplemented by various post mortem analytical techniques. The presented results question the impact of surface‐dependent failure mechanisms of single crystals for the evolution of SOC heterogeneity and identify the deficient structural flexibility of the composite electrode framework as the main driver for the observed non‐uniform active material utilization.
State of charge: The particle size‐ and rate‐dependent evolution of persistent mesoscale state‐of‐charge heterogeneity is revealed upon different cycling protocols for NMC532 with single‐crystalline architecture. The structural fatigue of the composite matrix is concluded to be the main driver for the observed non‐uniform active material utilization. |
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| AbstractList | The electrochemical response of layered lithium transition metal oxides LiMO
2
[M=Ni, Mn, Co; e. g., Li(Ni
0.5
Mn
0.3
Co
0.2
)O
2
(NMC532)] with single‐crystalline architecture to slow and fast charging protocols and the implication of incomplete and heterogeneous redox reactions on the active material utilization during cycling were the subject of this work. The role of the active material size and the influence of the local microstructural and chemical ramifications in the composite electrode on the evolution of heterogeneous state of charge (SOC) distribution were deciphered. For this, classification‐single‐particle inductively coupled plasma optical emission spectroscopy (CL‐SP‐ICP‐OES) was comprehensively supplemented by various post mortem analytical techniques. The presented results question the impact of surface‐dependent failure mechanisms of single crystals for the evolution of SOC heterogeneity and identify the deficient structural flexibility of the composite electrode framework as the main driver for the observed non‐uniform active material utilization.
State of charge
: The particle size‐ and rate‐dependent evolution of persistent mesoscale state‐of‐charge heterogeneity is revealed upon different cycling protocols for NMC532 with single‐crystalline architecture. The structural fatigue of the composite matrix is concluded to be the main driver for the observed non‐uniform active material utilization. The electrochemical response of layered lithium transition metal oxides LiMO2 [M=Ni, Mn, Co; e. g., Li(Ni0.5 Mn0.3 Co0.2 )O2 (NMC532)] with single-crystalline architecture to slow and fast charging protocols and the implication of incomplete and heterogeneous redox reactions on the active material utilization during cycling were the subject of this work. The role of the active material size and the influence of the local microstructural and chemical ramifications in the composite electrode on the evolution of heterogeneous state of charge (SOC) distribution were deciphered. For this, classification-single-particle inductively coupled plasma optical emission spectroscopy (CL-SP-ICP-OES) was comprehensively supplemented by various post mortem analytical techniques. The presented results question the impact of surface-dependent failure mechanisms of single crystals for the evolution of SOC heterogeneity and identify the deficient structural flexibility of the composite electrode framework as the main driver for the observed non-uniform active material utilization.The electrochemical response of layered lithium transition metal oxides LiMO2 [M=Ni, Mn, Co; e. g., Li(Ni0.5 Mn0.3 Co0.2 )O2 (NMC532)] with single-crystalline architecture to slow and fast charging protocols and the implication of incomplete and heterogeneous redox reactions on the active material utilization during cycling were the subject of this work. The role of the active material size and the influence of the local microstructural and chemical ramifications in the composite electrode on the evolution of heterogeneous state of charge (SOC) distribution were deciphered. For this, classification-single-particle inductively coupled plasma optical emission spectroscopy (CL-SP-ICP-OES) was comprehensively supplemented by various post mortem analytical techniques. The presented results question the impact of surface-dependent failure mechanisms of single crystals for the evolution of SOC heterogeneity and identify the deficient structural flexibility of the composite electrode framework as the main driver for the observed non-uniform active material utilization. The electrochemical response of layered lithium transition metal oxides LiMO2 [M=Ni, Mn, Co; e. g., Li(Ni0.5Mn0.3Co0.2)O2 (NMC532)] with single‐crystalline architecture to slow and fast charging protocols and the implication of incomplete and heterogeneous redox reactions on the active material utilization during cycling were the subject of this work. The role of the active material size and the influence of the local microstructural and chemical ramifications in the composite electrode on the evolution of heterogeneous state of charge (SOC) distribution were deciphered. For this, classification‐single‐particle inductively coupled plasma optical emission spectroscopy (CL‐SP‐ICP‐OES) was comprehensively supplemented by various post mortem analytical techniques. The presented results question the impact of surface‐dependent failure mechanisms of single crystals for the evolution of SOC heterogeneity and identify the deficient structural flexibility of the composite electrode framework as the main driver for the observed non‐uniform active material utilization. State of charge: The particle size‐ and rate‐dependent evolution of persistent mesoscale state‐of‐charge heterogeneity is revealed upon different cycling protocols for NMC532 with single‐crystalline architecture. The structural fatigue of the composite matrix is concluded to be the main driver for the observed non‐uniform active material utilization. The electrochemical response of layered lithium transition metal oxides LiMO [M=Ni, Mn, Co; e. g., Li(Ni Mn Co )O (NMC532)] with single-crystalline architecture to slow and fast charging protocols and the implication of incomplete and heterogeneous redox reactions on the active material utilization during cycling were the subject of this work. The role of the active material size and the influence of the local microstructural and chemical ramifications in the composite electrode on the evolution of heterogeneous state of charge (SOC) distribution were deciphered. For this, classification-single-particle inductively coupled plasma optical emission spectroscopy (CL-SP-ICP-OES) was comprehensively supplemented by various post mortem analytical techniques. The presented results question the impact of surface-dependent failure mechanisms of single crystals for the evolution of SOC heterogeneity and identify the deficient structural flexibility of the composite electrode framework as the main driver for the observed non-uniform active material utilization. The electrochemical response of layered lithium transition metal oxides LiMO2 [M=Ni, Mn, Co; e. g., Li(Ni0.5Mn0.3Co0.2)O2 (NMC532)] with single‐crystalline architecture to slow and fast charging protocols and the implication of incomplete and heterogeneous redox reactions on the active material utilization during cycling were the subject of this work. The role of the active material size and the influence of the local microstructural and chemical ramifications in the composite electrode on the evolution of heterogeneous state of charge (SOC) distribution were deciphered. For this, classification‐single‐particle inductively coupled plasma optical emission spectroscopy (CL‐SP‐ICP‐OES) was comprehensively supplemented by various post mortem analytical techniques. The presented results question the impact of surface‐dependent failure mechanisms of single crystals for the evolution of SOC heterogeneity and identify the deficient structural flexibility of the composite electrode framework as the main driver for the observed non‐uniform active material utilization. The electrochemical response of layered lithium transition metal oxides LiMO 2 [M=Ni, Mn, Co; e. g., Li(Ni 0.5 Mn 0.3 Co 0.2 )O 2 (NMC532)] with single‐crystalline architecture to slow and fast charging protocols and the implication of incomplete and heterogeneous redox reactions on the active material utilization during cycling were the subject of this work. The role of the active material size and the influence of the local microstructural and chemical ramifications in the composite electrode on the evolution of heterogeneous state of charge (SOC) distribution were deciphered. For this, classification‐single‐particle inductively coupled plasma optical emission spectroscopy (CL‐SP‐ICP‐OES) was comprehensively supplemented by various post mortem analytical techniques. The presented results question the impact of surface‐dependent failure mechanisms of single crystals for the evolution of SOC heterogeneity and identify the deficient structural flexibility of the composite electrode framework as the main driver for the observed non‐uniform active material utilization. |
| Author | Harte, Patrick Nowak, Sascha Kröger, Till‐Niklas Wölke, Mathis Jan Wiemers‐Meyer, Simon Winter, Martin Beuse, Thomas |
| AuthorAffiliation | 1 MEET Battery Research Center University of Münster Corrensstraße 46 48149 Münster Germany 2 Helmholtz-Institute Münster IEK-12 FZ Jülich Corrensstraße 46 48149 Münster Germany |
| AuthorAffiliation_xml | – name: 2 Helmholtz-Institute Münster IEK-12 FZ Jülich Corrensstraße 46 48149 Münster Germany – name: 1 MEET Battery Research Center University of Münster Corrensstraße 46 48149 Münster Germany |
| Author_xml | – sequence: 1 givenname: Till‐Niklas surname: Kröger fullname: Kröger, Till‐Niklas organization: University of Münster – sequence: 2 givenname: Mathis Jan surname: Wölke fullname: Wölke, Mathis Jan organization: University of Münster – sequence: 3 givenname: Patrick surname: Harte fullname: Harte, Patrick organization: University of Münster – sequence: 4 givenname: Thomas surname: Beuse fullname: Beuse, Thomas organization: University of Münster – sequence: 5 givenname: Martin orcidid: 0000-0003-4176-5811 surname: Winter fullname: Winter, Martin organization: Helmholtz-Institute Münster – sequence: 6 givenname: Sascha orcidid: 0000-0003-1508-6073 surname: Nowak fullname: Nowak, Sascha organization: University of Münster – sequence: 7 givenname: Simon orcidid: 0000-0001-8608-4521 surname: Wiemers‐Meyer fullname: Wiemers‐Meyer, Simon email: Simon.Wiemers-Meyer@uni-muenster.de organization: University of Münster |
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| Snippet | The electrochemical response of layered lithium transition metal oxides LiMO2 [M=Ni, Mn, Co; e. g., Li(Ni0.5Mn0.3Co0.2)O2 (NMC532)] with single‐crystalline... The electrochemical response of layered lithium transition metal oxides LiMO 2 [M=Ni, Mn, Co; e. g., Li(Ni 0.5 Mn 0.3 Co 0.2 )O 2 (NMC532)] with... The electrochemical response of layered lithium transition metal oxides LiMO [M=Ni, Mn, Co; e. g., Li(Ni Mn Co )O (NMC532)] with single-crystalline... The electrochemical response of layered lithium transition metal oxides LiMO2 [M=Ni, Mn, Co; e. g., Li(Ni0.5 Mn0.3 Co0.2 )O2 (NMC532)] with single-crystalline... |
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| SubjectTerms | Charge distribution electrochemistry Electrodes energy storage Evolution Failure mechanisms Heterogeneity Inductively coupled plasma Lithium-ion batteries Optical emission spectroscopy particle size Redox reactions Single crystals State of charge Transition metal oxides |
| Title | State‐of‐Charge Distribution of Single‐Crystalline NMC532 Cathodes in Lithium‐Ion Batteries: A Critical Look at the Mesoscale |
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