Stable Adducts of a Dimeric Magnesium(I) Compound
A bit of a stretch! A series of stable Lewis base adducts of a dimeric magnesium(I) complex has been prepared and shown to possess exceptionally long MgMg bonds. Theoretical studies on model compounds suggest the elongations of these bonds are low‐energy processes. The structures of the magnesium(I...
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| Published in | Angewandte Chemie (International ed.) Vol. 47; no. 47; pp. 9079 - 9083 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Wiley-VCH Verlag
10.11.2008
WILEY‐VCH Verlag |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1433-7851 1521-3773 1521-3773 |
| DOI | 10.1002/anie.200803960 |
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| Abstract | A bit of a stretch! A series of stable Lewis base adducts of a dimeric magnesium(I) complex has been prepared and shown to possess exceptionally long MgMg bonds. Theoretical studies on model compounds suggest the elongations of these bonds are low‐energy processes. The structures of the magnesium(I) adducts are compared with those of related magnesium(II) hydride complexes (see picture; Mg pink, N blue, O red, H green). |
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| AbstractList | A bit of a stretch! A series of stable Lewis base adducts of a dimeric magnesium(I) complex has been prepared and shown to possess exceptionally long MgMg bonds. Theoretical studies on model compounds suggest the elongations of these bonds are low‐energy processes. The structures of the magnesium(I) adducts are compared with those of related magnesium(II) hydride complexes (see picture; Mg pink, N blue, O red, H green). |
| Author | Green, Shaun P Stasch, Andreas Jones, Cameron |
| Author_xml | – sequence: 1 fullname: Green, Shaun P – sequence: 2 fullname: Jones, Cameron – sequence: 3 fullname: Stasch, Andreas |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/18925599$$D View this record in MEDLINE/PubMed |
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| Copyright | Copyright © 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Notes | http://dx.doi.org/10.1002/anie.200803960 We thank the Australian Research Council (fellowships for C.J. and A.S.), the Engineering and Physical Sciences Research Council (partial studentship for S.P.G.) and the US Air Force Asian Office of Aerospace Research and Development for funding. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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| Snippet | A bit of a stretch! A series of stable Lewis base adducts of a dimeric magnesium(I) complex has been prepared and shown to possess exceptionally long MgMg... |
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| SubjectTerms | low oxidation states magnesium metal hydrides metal–metal bonding structure elucidation |
| Title | Stable Adducts of a Dimeric Magnesium(I) Compound |
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