Reduction of nitrate to ammonia using photocatalytically accumulated electrons on titanium(IV) oxide in a time-separated redox reaction
[Display omitted] •Reduction of NO3− to ammonia NH3 was performed by a time-separated redox reaction.•The reaction uses a two-step reaction under the control of photoexcitation an electron acceptor.•Eight-electron reduction of NO3− to NH3 was performed by accumulated electrons in a TiO2 suspension.•...
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| Published in | Inorganic chemistry communications Vol. 141; p. 109585 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.07.2022
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1387-7003 1879-0259 1879-0259 |
| DOI | 10.1016/j.inoche.2022.109585 |
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| Abstract | [Display omitted]
•Reduction of NO3− to ammonia NH3 was performed by a time-separated redox reaction.•The reaction uses a two-step reaction under the control of photoexcitation an electron acceptor.•Eight-electron reduction of NO3− to NH3 was performed by accumulated electrons in a TiO2 suspension.•The use of a rutile sample with a large number of defective sites is a key factor for the reaction.
Reduction of nitrate (NO3−) to ammonia (NH3) was performed by a time-separated redox reaction using photocatalytically accumulated electrons in a titanium(IV) oxide (TiO2) suspension. The time-separated redox reaction uses a two-step reaction under the control of photoexcitation and an electron acceptor: (1) accumulation of electrons in TiO2 powder under photoexcitation and (2) reduction of added NO3− by accumulated electrons in the dark. Color change of TiO2 depending on the degree of electron accumulation was observed during the reaction, and 8-electron reduction of NO3− to NH3 was performed by accumulated electrons. The results of the time-separated redox reaction using 10 kinds of commercial TiO2 powder indicate that the use of a rutile sample with a large number of trivalent titanium species is a key factor for NH3 production. |
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| AbstractList | [Display omitted]
•Reduction of NO3− to ammonia NH3 was performed by a time-separated redox reaction.•The reaction uses a two-step reaction under the control of photoexcitation an electron acceptor.•Eight-electron reduction of NO3− to NH3 was performed by accumulated electrons in a TiO2 suspension.•The use of a rutile sample with a large number of defective sites is a key factor for the reaction.
Reduction of nitrate (NO3−) to ammonia (NH3) was performed by a time-separated redox reaction using photocatalytically accumulated electrons in a titanium(IV) oxide (TiO2) suspension. The time-separated redox reaction uses a two-step reaction under the control of photoexcitation and an electron acceptor: (1) accumulation of electrons in TiO2 powder under photoexcitation and (2) reduction of added NO3− by accumulated electrons in the dark. Color change of TiO2 depending on the degree of electron accumulation was observed during the reaction, and 8-electron reduction of NO3− to NH3 was performed by accumulated electrons. The results of the time-separated redox reaction using 10 kinds of commercial TiO2 powder indicate that the use of a rutile sample with a large number of trivalent titanium species is a key factor for NH3 production. |
| ArticleNumber | 109585 |
| Author | Murakami, Naoya Suenaga, Masato Deguchi, Ryota |
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•Reduction of NO3− to ammonia NH3 was performed by a time-separated redox reaction.•The reaction uses a two-step reaction under the control... |
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| SubjectTerms | Ammonia Electron accumulation Photocatalyst Titanium(IV) oxide |
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| Title | Reduction of nitrate to ammonia using photocatalytically accumulated electrons on titanium(IV) oxide in a time-separated redox reaction |
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