Bromotrimethylsilane as a selective reagent for the synthesis of bromohydrins

Bromotrimethylsilane (TMSBr) is a very efficient reagent in the solvent-free conversion of glycerol into bromohydrins, useful intermediates in the production of fine chemicals. As glycerol is a relevant by-product in biodiesel production, TMSBr has been also tested as a mediator in transesterificati...

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Published inRSC advances Vol. 11; no. 24; pp. 14453 - 14458
Main Authors Giomi, Donatella, Salvini, Antonella, Ceccarelli, Jacopo, Brandi, Alberto
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 16.04.2021
The Royal Society of Chemistry
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ISSN2046-2069
2046-2069
DOI10.1039/d1ra01980e

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Abstract Bromotrimethylsilane (TMSBr) is a very efficient reagent in the solvent-free conversion of glycerol into bromohydrins, useful intermediates in the production of fine chemicals. As glycerol is a relevant by-product in biodiesel production, TMSBr has been also tested as a mediator in transesterification in acidic conditions, providing FAME from castor oil in good yields, along with bromohydrins from glycerol. Subsequently the glycerol conversion was optimized and depending on the reaction conditions, glycerol can be selectively converted into α-monobromohydrin (1-MBH) or α,γ-dibromohydrin (1,3-DBH) in very good yields. Glycerol, a by-product of biodiesel production, can be efficiently converted into α-monobromohydrin or α,γ-dibromohydrin with trimethylsilyl bromide (TMSBr), in solvent-free and mild reaction conditions.
AbstractList Bromotrimethylsilane (TMSBr) is a very efficient reagent in the solvent-free conversion of glycerol into bromohydrins, useful intermediates in the production of fine chemicals. As glycerol is a relevant by-product in biodiesel production, TMSBr has been also tested as a mediator in transesterification in acidic conditions, providing FAME from castor oil in good yields, along with bromohydrins from glycerol. Subsequently the glycerol conversion was optimized and depending on the reaction conditions, glycerol can be selectively converted into α-monobromohydrin (1-MBH) or α,γ-dibromohydrin (1,3-DBH) in very good yields.
Bromotrimethylsilane (TMSBr) is a very efficient reagent in the solvent-free conversion of glycerol into bromohydrins, useful intermediates in the production of fine chemicals. As glycerol is a relevant by-product in biodiesel production, TMSBr has been also tested as a mediator in transesterification in acidic conditions, providing FAME from castor oil in good yields, along with bromohydrins from glycerol. Subsequently the glycerol conversion was optimized and depending on the reaction conditions, glycerol can be selectively converted into α-monobromohydrin (1-MBH) or α,γ-dibromohydrin (1,3-DBH) in very good yields. Glycerol, a by-product of biodiesel production, can be efficiently converted into α-monobromohydrin or α,γ-dibromohydrin with trimethylsilyl bromide (TMSBr), in solvent-free and mild reaction conditions.
Bromotrimethylsilane (TMSBr) is a very efficient reagent in the solvent-free conversion of glycerol into bromohydrins, useful intermediates in the production of fine chemicals. As glycerol is a relevant by-product in biodiesel production, TMSBr has been also tested as a mediator in transesterification in acidic conditions, providing FAME from castor oil in good yields, along with bromohydrins from glycerol. Subsequently the glycerol conversion was optimized and depending on the reaction conditions, glycerol can be selectively converted into α-monobromohydrin (1-MBH) or α,γ-dibromohydrin (1,3-DBH) in very good yields.Bromotrimethylsilane (TMSBr) is a very efficient reagent in the solvent-free conversion of glycerol into bromohydrins, useful intermediates in the production of fine chemicals. As glycerol is a relevant by-product in biodiesel production, TMSBr has been also tested as a mediator in transesterification in acidic conditions, providing FAME from castor oil in good yields, along with bromohydrins from glycerol. Subsequently the glycerol conversion was optimized and depending on the reaction conditions, glycerol can be selectively converted into α-monobromohydrin (1-MBH) or α,γ-dibromohydrin (1,3-DBH) in very good yields.
Author Salvini, Antonella
Giomi, Donatella
Ceccarelli, Jacopo
Brandi, Alberto
AuthorAffiliation Università degli Studi di Firenze
Laboratorio congiunto VALORE, "Valorizzazione di masse algali e sottoprodotti agro-industriali e riduzione di gas serra in atmosfera"
Dipartimento di Chimica 'Ugo Schiff'
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10.1071/CH9942123
10.1055/s-1987-27988
10.1021/jo00087a048
10.1186/1754-6834-5-13
10.1039/C5RA12756D
10.3390/molecules25010221
10.1039/c1gc15053g
10.1039/C9CC09643D
10.2174/1876973X01003010017
10.1590/S0103-50531998000300002
10.1007/BF02540998
10.1016/j.biortech.2003.08.014
10.1016/S0960-8524(99)00025-5
10.1039/C4RA08240K
10.1055/s-0034-1379226
10.1021/jo00113a055
10.3389/fchem.2020.00069
10.1016/j.tetlet.2016.04.083
10.15227/orgsyn.014.0042
10.1039/c2ra20558k
10.1186/2043-7129-2-1
10.1166/jnn.2017.14768
10.1021/ie403268b
10.1039/C4RA00758A
10.1055/s-1983-30320
10.1080/17518253.2019.1679265
10.1021/ja00905a001
10.1021/jo00250a048
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C NMR spectra of reaction mixtures and purified products. See DOI
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References Salvini (D1RA01980E-(cit9)/*[position()=1]) 2012; 2
da Silva (D1RA01980E-(cit1a)/*[position()=1]) 2020; 31
De Sousa (D1RA01980E-(cit7d)/*[position()=1]) 2011; 13
dos Santos (D1RA01980E-(cit1b)/*[position()=1]) 2019; 12
Wright (D1RA01980E-(cit8a)/*[position()=1]) 1944; 21
Mittelbach (D1RA01980E-(cit8e)/*[position()=1]) 2006
Camps (D1RA01980E-(cit6)/*[position()=1]) 1987
Bouillaud (D1RA01980E-(cit5)/*[position()=1]) 1994; 47
Schuchardt (D1RA01980E-(cit8b)/*[position()=1]) 1998; 9
Fan (D1RA01980E-(cit7b)/*[position()=1]) 2010; 3
Santacesaria (D1RA01980E-(cit7a)/*[position()=1]) 2014; 53
Braun (D1RA01980E-(cit2)/*[position()=2]) 1936; 16
Lee (D1RA01980E-(cit3a)/*[position()=1]) 2017; 17
Yang (D1RA01980E-(cit7c)/*[position()=1]) 2012; 5
Tandiary (D1RA01980E-(cit15e)/*[position()=1]) 2014; 25
Braun (D1RA01980E-(cit4)/*[position()=1]) 1934; 14
Lissel (D1RA01980E-(cit15a)/*[position()=1]) 1983
Saggadi (D1RA01980E-(cit7f)/*[position()=1]) 2014; 4
Ma (D1RA01980E-(cit8c)/*[position()=1]) 1999; 70
Ajvazi (D1RA01980E-(cit16)/*[position()=1]) 2016; 57
Aroua (D1RA01980E-(cit7g)/*[position()=1]) 2020; 8
Zhang (D1RA01980E-(cit3c)/*[position()=1]) 2020; 56
Lee (D1RA01980E-(cit15b)/*[position()=1]) 1988; 53
Le Roux (D1RA01980E-(cit15c)/*[position()=1]) 1994; 59
Len (D1RA01980E-(cit7e)/*[position()=1]) 2014; 2
Gelbard (D1RA01980E-(cit12)/*[position()=2]) 1995; 72
Vicente (D1RA01980E-(cit8d)/*[position()=1]) 2004; 92
Malavolti (D1RA01980E-(cit10)/*[position()=1]) 2015; 5
Mojzych (D1RA01980E-(cit3b)/*[position()=1]) 2020; 25
Pearson (D1RA01980E-(cit14)/*[position()=1]) 1963; 85
Giomi (D1RA01980E-(cit11)/*[position()=1]) 2014; 4
Synder (D1RA01980E-(cit15d)/*[position()=1]) 1995; 60
References_xml – issn: 2006
  publication-title: Biodiesel, the Comprehensive Handbook
  doi: Mittelbach Remschmidt
– volume: 16
  start-page: 30
  year: 1936
  ident: D1RA01980E-(cit2)/*[position()=2]
  publication-title: Org. Synth.
  doi: 10.15227/orgsyn.016.0030
– volume: 47
  start-page: 2123
  year: 1994
  ident: D1RA01980E-(cit5)/*[position()=1]
  publication-title: Aust. J. Chem.
  doi: 10.1071/CH9942123
– start-page: 511
  year: 1987
  ident: D1RA01980E-(cit6)/*[position()=1]
  publication-title: Synthesis
  doi: 10.1055/s-1987-27988
– volume: 59
  start-page: 2238
  year: 1994
  ident: D1RA01980E-(cit15c)/*[position()=1]
  publication-title: J. Org. Chem.
  doi: 10.1021/jo00087a048
– volume: 5
  start-page: 1
  year: 2012
  ident: D1RA01980E-(cit7c)/*[position()=1]
  publication-title: Biotechnol. Biofuels
  doi: 10.1186/1754-6834-5-13
– volume-title: Biodiesel, the Comprehensive Handbook
  year: 2006
  ident: D1RA01980E-(cit8e)/*[position()=1]
– volume: 5
  start-page: 77341
  year: 2015
  ident: D1RA01980E-(cit10)/*[position()=1]
  publication-title: RSC Adv.
  doi: 10.1039/C5RA12756D
– volume: 25
  start-page: 221
  year: 2020
  ident: D1RA01980E-(cit3b)/*[position()=1]
  publication-title: Molecules
  doi: 10.3390/molecules25010221
– volume: 13
  start-page: 1129
  year: 2011
  ident: D1RA01980E-(cit7d)/*[position()=1]
  publication-title: Green Chem.
  doi: 10.1039/c1gc15053g
– volume: 56
  start-page: 3309
  year: 2020
  ident: D1RA01980E-(cit3c)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/C9CC09643D
– volume: 3
  start-page: 17
  year: 2010
  ident: D1RA01980E-(cit7b)/*[position()=1]
  publication-title: Open Fuels Energy Sci. J.
  doi: 10.2174/1876973X01003010017
– volume: 9
  start-page: 199
  year: 1998
  ident: D1RA01980E-(cit8b)/*[position()=1]
  publication-title: J. Braz. Chem. Soc.
  doi: 10.1590/S0103-50531998000300002
– volume: 72
  start-page: 1239
  year: 1995
  ident: D1RA01980E-(cit12)/*[position()=2]
  publication-title: J. Am. Oil Chem. Soc.
  doi: 10.1007/BF02540998
– volume: 92
  start-page: 297
  year: 2004
  ident: D1RA01980E-(cit8d)/*[position()=1]
  publication-title: Bioresour. Technol.
  doi: 10.1016/j.biortech.2003.08.014
– volume: 70
  start-page: 1
  year: 1999
  ident: D1RA01980E-(cit8c)/*[position()=1]
  publication-title: Bioresour. Technol.
  doi: 10.1016/S0960-8524(99)00025-5
– volume: 4
  start-page: 46319
  year: 2014
  ident: D1RA01980E-(cit11)/*[position()=1]
  publication-title: RSC Adv.
  doi: 10.1039/C4RA08240K
– volume: 25
  start-page: 2639
  year: 2014
  ident: D1RA01980E-(cit15e)/*[position()=1]
  publication-title: Synlett
  doi: 10.1055/s-0034-1379226
– volume: 60
  start-page: 2638
  year: 1995
  ident: D1RA01980E-(cit15d)/*[position()=1]
  publication-title: J. Org. Chem.
  doi: 10.1021/jo00113a055
– volume: 8
  start-page: 69
  year: 2020
  ident: D1RA01980E-(cit7g)/*[position()=1]
  publication-title: Front. Chem.
  doi: 10.3389/fchem.2020.00069
– volume: 57
  start-page: 2430
  year: 2016
  ident: D1RA01980E-(cit16)/*[position()=1]
  publication-title: Tetrahedron Lett.
  doi: 10.1016/j.tetlet.2016.04.083
– volume: 14
  start-page: 42
  year: 1934
  ident: D1RA01980E-(cit4)/*[position()=1]
  publication-title: Org. Synth.
  doi: 10.15227/orgsyn.014.0042
– volume: 2
  start-page: 4864
  year: 2012
  ident: D1RA01980E-(cit9)/*[position()=1]
  publication-title: RSC Adv.
  doi: 10.1039/c2ra20558k
– volume: 2
  start-page: 1
  year: 2014
  ident: D1RA01980E-(cit7e)/*[position()=1]
  publication-title: Sustainable Chem. Processes
  doi: 10.1186/2043-7129-2-1
– volume: 17
  start-page: 7579
  year: 2017
  ident: D1RA01980E-(cit3a)/*[position()=1]
  publication-title: J. Nanosci. Nanotechnol.
  doi: 10.1166/jnn.2017.14768
– volume: 53
  start-page: 8939
  year: 2014
  ident: D1RA01980E-(cit7a)/*[position()=1]
  publication-title: Ind. Eng. Chem. Res.
  doi: 10.1021/ie403268b
– volume: 4
  start-page: 21456
  year: 2014
  ident: D1RA01980E-(cit7f)/*[position()=1]
  publication-title: RSC Adv.
  doi: 10.1039/C4RA00758A
– start-page: 314
  year: 1983
  ident: D1RA01980E-(cit15a)/*[position()=1]
  publication-title: Synthesis
  doi: 10.1055/s-1983-30320
– volume: 12
  start-page: 389
  year: 2019
  ident: D1RA01980E-(cit1b)/*[position()=1]
  publication-title: Green Chem. Lett. Rev.
  doi: 10.1080/17518253.2019.1679265
– volume: 31
  start-page: 1725
  year: 2020
  ident: D1RA01980E-(cit1a)/*[position()=1]
  publication-title: J. Braz. Chem. Soc.
– volume: 21
  start-page: 145
  year: 1944
  ident: D1RA01980E-(cit8a)/*[position()=1]
  publication-title: J. Am. Oil Chem. Soc.
– volume: 85
  start-page: 3533
  year: 1963
  ident: D1RA01980E-(cit14)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00905a001
– volume: 53
  start-page: 3634
  year: 1988
  ident: D1RA01980E-(cit15b)/*[position()=1]
  publication-title: J. Org. Chem.
  doi: 10.1021/jo00250a048
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Snippet Bromotrimethylsilane (TMSBr) is a very efficient reagent in the solvent-free conversion of glycerol into bromohydrins, useful intermediates in the production...
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SubjectTerms biodiesel
Biodiesel fuels
byproducts
Castor oil
Chemistry
Conversion
Fine chemicals
Glycerol
NMR
Nuclear magnetic resonance
Reagents
Transesterification
Title Bromotrimethylsilane as a selective reagent for the synthesis of bromohydrins
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