Graphene Oxide Chemistry Management via the Use of KMnO4/K2Cr2O7 Oxidizing Agents

• Published in: Nanomaterials (Basel, Switzerland) Vol. 11; no. 4; p. 915
• Main Authors: Shiyanova, Kseniya A., Gudkov, Maksim V., Rabchinskii, Maxim K., Sokura, Liliia A., Stolyarova, Dina Y., Baidakova, Marina V., Shashkin, Dmitriy P., Trofimuk, Andrei D., Smirnov, Dmitry A., Komarov, Ivan A., Timofeeva, Victoria A., Melnikov, Valery P.
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 03.04.2021; MDPI
• Subjects: Absorption spectroscopy; Atomic force microscopy; Carbonyl compounds; Carbonyls; chemical composition management; Chemical synthesis; Chemistry; Corrugated plates; Epoxides; Fourier transforms; Graphene; graphene oxide; Graphite; Infrared spectroscopy; Lamellar structure; Light microscopy; Methods; Optical microscopy; Oxidation; oxidation method; Oxidizing agents; Photoelectron spectroscopy; Photoelectrons; Platelets (materials); Potassium; Potassium dichromate; Potassium permanganate; Quantum dots; Raman spectroscopy; Transmission electron microscopy; X ray absorption; X ray photoelectron spectroscopy; X-ray absorption spectroscopy; X-ray diffraction; Russia
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano11040915

In this paper, we propose a facile approach to the management of graphene oxide (GO) chemistry via its synthesis using KMnO4/K2Cr2O7 oxidizing agents at different ratios. Using Fourier Transformed Infrared Spectroscopy, X-ray Photoelectron Spectroscopy, and X-ray Absorption Spectroscopy, we show that the number of basal-plane and edge-located oxygenic groups can be controllably tuned by altering the KMnO4/K2Cr2O7 ratio. The linear two-fold reduction in the number of the hydroxyls and epoxides with the simultaneous three-fold rise in the content of carbonyls and carboxyls is indicated upon the transition from KMnO4 to K2Cr2O7 as a predominant oxidizing agent. The effect of the oxidation mixture’s composition on the structure of the synthesized GOs is also comprehensively studied by means of X-ray diffraction, Raman spectroscopy, transmission electron microscopy, atomic-force microscopy, optical microscopy, and the laser diffraction method. The nanoscale corrugation of the GO platelets with the increase of the K2Cr2O7 content is signified, whereas the 10–100 μm lateral size, lamellar, and defect-free structure is demonstrated for all of the synthesized GOs regardless of the KMnO4/K2Cr2O7 ratio. The proposed method for the synthesis of GO with the desired chemistry opens up new horizons for the development of graphene-based materials with tunable functional properties.