Transition Metal‐Catalyzed Reactions Involving Oximes
Oximes are an easily prepared and transformed unit, which are widely used in organic synthesis. The oximes, including oxime ethers and esters, could realize various transformations, such as C–H bond activation, Heck‐type reactions, N–O bond cleavage/C–N bond formation, O–H bond cleavage and coupling...
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| Published in | Advanced synthesis & catalysis Vol. 359; no. 5; pp. 710 - 771 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Heidelberg
Wiley Subscription Services, Inc
06.03.2017
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1615-4150 1615-4169 |
| DOI | 10.1002/adsc.201600807 |
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| Abstract | Oximes are an easily prepared and transformed unit, which are widely used in organic synthesis. The oximes, including oxime ethers and esters, could realize various transformations, such as C–H bond activation, Heck‐type reactions, N–O bond cleavage/C–N bond formation, O–H bond cleavage and couplings. However, there is no a comprehensive review on this subject. Herein, we summarize the recent advances over the past 15 years in transition metal‐catalyzed reactions involving oximes, focusing on the reaction scope, limitations and mechanisms. |
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| AbstractList | Oximes are an easily prepared and transformed unit, which are widely used in organic synthesis. The oximes, including oxime ethers and esters, could realize various transformations, such as C-H bond activation, Heck-type reactions, N-O bond cleavage/C-N bond formation, O-H bond cleavage and couplings. However, there is no a comprehensive review on this subject. Herein, we summarize the recent advances over the past 15 years in transition metal-catalyzed reactions involving oximes, focusing on the reaction scope, limitations and mechanisms. Oximes are an easily prepared and transformed unit, which are widely used in organic synthesis. The oximes, including oxime ethers and esters, could realize various transformations, such as C–H bond activation, Heck‐type reactions, N–O bond cleavage/C–N bond formation, O–H bond cleavage and couplings. However, there is no a comprehensive review on this subject. Herein, we summarize the recent advances over the past 15 years in transition metal‐catalyzed reactions involving oximes, focusing on the reaction scope, limitations and mechanisms. magnified image |
| Author | Li, Jun Liu, Qing Liu, Hui Zhang, Daopeng Hu, Yitian Dong, Yunhui |
| Author_xml | – sequence: 1 givenname: Jun surname: Li fullname: Li, Jun organization: Shandong University of Technology – sequence: 2 givenname: Yitian surname: Hu fullname: Hu, Yitian organization: Shandong University of Technology – sequence: 3 givenname: Daopeng surname: Zhang fullname: Zhang, Daopeng organization: Shandong University of Technology – sequence: 4 givenname: Qing surname: Liu fullname: Liu, Qing email: qingliu0315@163.com organization: Shandong University of Technology – sequence: 5 givenname: Yunhui surname: Dong fullname: Dong, Yunhui organization: Shandong University of Technology – sequence: 6 givenname: Hui surname: Liu fullname: Liu, Hui email: huiliu1030@163.com organization: Dyeing and Finishing of Shandong University of Technology |
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| Snippet | Oximes are an easily prepared and transformed unit, which are widely used in organic synthesis. The oximes, including oxime ethers and esters, could realize... |
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| SubjectTerms | Activation Bonding catalysis Chemical reactions Cleavage Couplings C–H activation Esters Ethers Heck reaction Hydrogen bonds Oximes Transformations transition metal catalysts |
| Title | Transition Metal‐Catalyzed Reactions Involving Oximes |
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