Fouling mitigation and wastewater decontamination in UV treatment systems
This work applied the photo‐Fenton process to mitigate quartz fouling in ultraviolet‐A (UVA) wastewater treatment. The impacts of the pH, iron and phosphorus concentration in synthetic wastewater were explored. It was observed that the photo‐Fenton process (5 mg/L of Fe2+, 10 mg/L of H2O2) mitigated...
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Published in | Water and environment journal : WEJ Vol. 39; no. 2; pp. 168 - 177 |
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Main Authors | , |
Format | Journal Article |
Language | English |
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01.05.2025
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ISSN | 1747-6585 1747-6593 |
DOI | 10.1111/wej.12964 |
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Abstract | This work applied the photo‐Fenton process to mitigate quartz fouling in ultraviolet‐A (UVA) wastewater treatment. The impacts of the pH, iron and phosphorus concentration in synthetic wastewater were explored. It was observed that the photo‐Fenton process (5 mg/L of Fe2+, 10 mg/L of H2O2) mitigated quartz fouling and achieved 33% of chemical oxygen demand (COD) removal. It was also found that the presence of UVA irradiation and/or acidic conditions substantially decreased fouling formation. X‐ray diffraction as well as energy‐dispersive spectroscopy measurements showed that fouling consisted mainly of Fe, Ca, P, and Na. Increasing P concentration in wastewater from 5 to 40 mg/L enhanced fouling formation as well as COD removal from 35% to 51%, respectively. This work provides insight, for the first time, into the role of Fenton reaction in mitigating quartz fouling, one of the technical challenges in upscaling photocatalytic treatment. |
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AbstractList | This work applied the photo‐Fenton process to mitigate quartz fouling in ultraviolet‐A (UVA) wastewater treatment. The impacts of the pH, iron and phosphorus concentration in synthetic wastewater were explored. It was observed that the photo‐Fenton process (5 mg/L of Fe2+, 10 mg/L of H2O2) mitigated quartz fouling and achieved 33% of chemical oxygen demand (COD) removal. It was also found that the presence of UVA irradiation and/or acidic conditions substantially decreased fouling formation. X‐ray diffraction as well as energy‐dispersive spectroscopy measurements showed that fouling consisted mainly of Fe, Ca, P, and Na. Increasing P concentration in wastewater from 5 to 40 mg/L enhanced fouling formation as well as COD removal from 35% to 51%, respectively. This work provides insight, for the first time, into the role of Fenton reaction in mitigating quartz fouling, one of the technical challenges in upscaling photocatalytic treatment. This work applied the photo‐Fenton process to mitigate quartz fouling in ultraviolet‐A (UVA) wastewater treatment. The impacts of the pH, iron and phosphorus concentration in synthetic wastewater were explored. It was observed that the photo‐Fenton process (5 mg/L of Fe 2+ , 10 mg/L of H 2 O 2 ) mitigated quartz fouling and achieved 33% of chemical oxygen demand (COD) removal. It was also found that the presence of UVA irradiation and/or acidic conditions substantially decreased fouling formation. X‐ray diffraction as well as energy‐dispersive spectroscopy measurements showed that fouling consisted mainly of Fe, Ca, P, and Na. Increasing P concentration in wastewater from 5 to 40 mg/L enhanced fouling formation as well as COD removal from 35% to 51%, respectively. This work provides insight, for the first time, into the role of Fenton reaction in mitigating quartz fouling, one of the technical challenges in upscaling photocatalytic treatment. This work applied the photo‐Fenton process to mitigate quartz fouling in ultraviolet‐A (UVA) wastewater treatment. The impacts of the pH, iron and phosphorus concentration in synthetic wastewater were explored. It was observed that the photo‐Fenton process (5 mg/L of Fe2+, 10 mg/L of H2O2) mitigated quartz fouling and achieved 33% of chemical oxygen demand (COD) removal. It was also found that the presence of UVA irradiation and/or acidic conditions substantially decreased fouling formation. X‐ray diffraction as well as energy‐dispersive spectroscopy measurements showed that fouling consisted mainly of Fe, Ca, P, and Na. Increasing P concentration in wastewater from 5 to 40 mg/L enhanced fouling formation as well as COD removal from 35% to 51%, respectively. This work provides insight, for the first time, into the role of Fenton reaction in mitigating quartz fouling, one of the technical challenges in upscaling photocatalytic treatment. This work applied the photo‐Fenton process to mitigate quartz fouling in ultraviolet‐A (UVA) wastewater treatment. The impacts of the pH, iron and phosphorus concentration in synthetic wastewater were explored. It was observed that the photo‐Fenton process (5 mg/L of Fe²⁺, 10 mg/L of H₂O₂) mitigated quartz fouling and achieved 33% of chemical oxygen demand (COD) removal. It was also found that the presence of UVA irradiation and/or acidic conditions substantially decreased fouling formation. X‐ray diffraction as well as energy‐dispersive spectroscopy measurements showed that fouling consisted mainly of Fe, Ca, P, and Na. Increasing P concentration in wastewater from 5 to 40 mg/L enhanced fouling formation as well as COD removal from 35% to 51%, respectively. This work provides insight, for the first time, into the role of Fenton reaction in mitigating quartz fouling, one of the technical challenges in upscaling photocatalytic treatment. |
Author | Chatzisymeon, Efthalia Aslam, Tooba |
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Cites_doi | 10.4028/www.scientific.net/MSF.734.247 10.1115/1.3450419 10.1016/S0043-1354(99)00037-8 10.1080/10643380500326564 10.1021/la00093a015 10.1021/es60091a008 10.1038/s41598-022-20984-0 10.1016/S0927-7757(97)00150-7 10.1006/jcis.2001.7773 10.2175/106143006X95474 10.1016/B978-0-12-804703-3.00002-4 10.2175/106143096X127389 10.1002/jctb.1169 10.2166/wqrj.2001.005 10.1016/0016-7037(81)90162-9 10.1115/1.3246879 10.3390/w10091275 10.1071/SR04049 |
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SubjectTerms | advanced oxidation processes Chemical oxygen demand Decontamination energy-dispersive X-ray analysis environment Fouling fouling mitigation Hydrogen peroxide Iron Irradiation Oxygen requirement Phosphorus photocatalysis Quartz Spectroscopy Ultraviolet radiation wastewater Wastewater treatment water X-ray diffraction |
Title | Fouling mitigation and wastewater decontamination in UV treatment systems |
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