Microstructure and plasma corrosion behavior of yttria coatings prepared by the aerosol deposition method

Particle contamination arising from inner ceramic components of the plasma etching equipment has become a serious issue. Yttria (Y2O3) coatings prepared via aerosol deposition (AD) have demonstrated superior plasma resistance in the reduction of particle contamination. The superior particle contamin...

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Published inJournal of the American Ceramic Society Vol. 103; no. 12; pp. 7031 - 7040
Main Authors Ashizawa, Hiroaki, Masakatsu, Kiyohara, Yoshida, Katsumi
Format Journal Article
LanguageEnglish
Published Columbus Wiley 01.12.2020
Wiley Subscription Services, Inc
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ISSN0002-7820
1551-2916
DOI10.1111/jace.17193

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Abstract Particle contamination arising from inner ceramic components of the plasma etching equipment has become a serious issue. Yttria (Y2O3) coatings prepared via aerosol deposition (AD) have demonstrated superior plasma resistance in the reduction of particle contamination. The superior particle contamination performance of Y2O3 coatings prepared by AD has been speculatively attributed to its unique microstructure; however, the relationship between the coatings’ microstructure and plasma corrosion behavior has been insufficiently clarified. Herein, we investigated the relationship between the microstructure and plasma corrosion behavior of Y2O3 coatings prepared by the AD method and compared the results with those for coatings prepared by other coating methods. When internal pores are present, these internal pores were selectively plasma corroded; plasma corrosion marks reflecting their pore shape were formed, and the surface roughness increased with increasing plasma exposure time. However, when no internal pores were present, as in the case of the AD coating, the surfaces were homogeneously corroded and maintained their initial surface. As the risk of particle contamination caused by the corrosion of the plasma‐resistant coatings is greatly increased with surface roughness, we concluded that the Y2O3 coating prepared via AD will contribute greatly to reducing particle contamination.
AbstractList Particle contamination arising from inner ceramic components of the plasma etching equipment has become a serious issue. Yttria (Y2O3) coatings prepared via aerosol deposition (AD) have demonstrated superior plasma resistance in the reduction of particle contamination. The superior particle contamination performance of Y2O3 coatings prepared by AD has been speculatively attributed to its unique microstructure; however, the relationship between the coatings’ microstructure and plasma corrosion behavior has been insufficiently clarified. Herein, we investigated the relationship between the microstructure and plasma corrosion behavior of Y2O3 coatings prepared by the AD method and compared the results with those for coatings prepared by other coating methods. When internal pores are present, these internal pores were selectively plasma corroded; plasma corrosion marks reflecting their pore shape were formed, and the surface roughness increased with increasing plasma exposure time. However, when no internal pores were present, as in the case of the AD coating, the surfaces were homogeneously corroded and maintained their initial surface. As the risk of particle contamination caused by the corrosion of the plasma‐resistant coatings is greatly increased with surface roughness, we concluded that the Y2O3 coating prepared via AD will contribute greatly to reducing particle contamination.
Particle contamination arising from inner ceramic components of the plasma etching equipment has become a serious issue. Yttria (Y 2 O 3 ) coatings prepared via aerosol deposition (AD) have demonstrated superior plasma resistance in the reduction of particle contamination. The superior particle contamination performance of Y 2 O 3 coatings prepared by AD has been speculatively attributed to its unique microstructure; however, the relationship between the coatings’ microstructure and plasma corrosion behavior has been insufficiently clarified. Herein, we investigated the relationship between the microstructure and plasma corrosion behavior of Y 2 O 3 coatings prepared by the AD method and compared the results with those for coatings prepared by other coating methods. When internal pores are present, these internal pores were selectively plasma corroded; plasma corrosion marks reflecting their pore shape were formed, and the surface roughness increased with increasing plasma exposure time. However, when no internal pores were present, as in the case of the AD coating, the surfaces were homogeneously corroded and maintained their initial surface. As the risk of particle contamination caused by the corrosion of the plasma‐resistant coatings is greatly increased with surface roughness, we concluded that the Y 2 O 3 coating prepared via AD will contribute greatly to reducing particle contamination.
Author Kiyohara Masakatsu
Hiroaki Ashizawa
Katsumi Yoshida
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  orcidid: 0000-0002-1025-9441
  surname: Ashizawa
  fullname: Ashizawa, Hiroaki
  email: hiroaki.ashizawa@jp.toto.com
  organization: Tokyo Institute of Technology
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Snippet Particle contamination arising from inner ceramic components of the plasma etching equipment has become a serious issue. Yttria (Y2O3) coatings prepared via...
Particle contamination arising from inner ceramic components of the plasma etching equipment has become a serious issue. Yttria (Y 2 O 3 ) coatings prepared...
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SubjectTerms aerosol deposition
Coatings
Contamination
Corrosion
Corrosion resistance
Deposition
Dew
Etching equipment
Microstructure
Plasma etching
Porosity
Surface roughness
yttrium compounds
Yttrium oxide
Title Microstructure and plasma corrosion behavior of yttria coatings prepared by the aerosol deposition method
URI https://cir.nii.ac.jp/crid/1874242817264520192
https://onlinelibrary.wiley.com/doi/abs/10.1111%2Fjace.17193
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