Binder-Free Cathode for Thermal Batteries Fabricated Using FeS2 Treated Metal Foam
In this study, we fabricated a cathode with lower amounts of additive materials and higher amounts of active materials than those of a conventional cathode. A thermal battery was fabricated using FeS2 treated foam as the cathode frame, and its feasibility was verified. X-ray diffraction, transmissio...
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Published in | Frontiers in chemistry Vol. 7; p. 904 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
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Frontiers Media S.A
10.01.2020
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ISSN | 2296-2646 2296-2646 |
DOI | 10.3389/fchem.2019.00904 |
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Abstract | In this study, we fabricated a cathode with lower amounts of additive materials and higher amounts of active materials than those of a conventional cathode. A thermal battery was fabricated using FeS2 treated foam as the cathode frame, and its feasibility was verified. X-ray diffraction, transmission electron microscopy, and scanning electron microscopy were used to analyze the effects of thermal sulfidation temperature (400 and 500°C) on the structure and surface morphology of the FeS2 foam. The optimal temperature for the fabrication of the FeSx treated foam was determined to be 500°C. The FeS2 treated foam reduced the interfacial resistance and improved the mechanical strength of the cathode. The discharge capacity of the thermal battery using the FeS2 treated foam was about 1.3 times higher than that of a thermal battery using pure Fe metal foam.In this study, we fabricated a cathode with lower amounts of additive materials and higher amounts of active materials than those of a conventional cathode. A thermal battery was fabricated using FeS2 treated foam as the cathode frame, and its feasibility was verified. X-ray diffraction, transmission electron microscopy, and scanning electron microscopy were used to analyze the effects of thermal sulfidation temperature (400 and 500°C) on the structure and surface morphology of the FeS2 foam. The optimal temperature for the fabrication of the FeSx treated foam was determined to be 500°C. The FeS2 treated foam reduced the interfacial resistance and improved the mechanical strength of the cathode. The discharge capacity of the thermal battery using the FeS2 treated foam was about 1.3 times higher than that of a thermal battery using pure Fe metal foam. |
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AbstractList | In this study, we fabricated a cathode with lower amounts of additive materials and higher amounts of active materials than those of a conventional cathode. A thermal battery was fabricated using FeS2 treated foam as the cathode frame, and its feasibility was verified. X-ray diffraction, transmission electron microscopy, and scanning electron microscopy were used to analyze the effects of thermal sulfidation temperature (400 and 500°C) on the structure and surface morphology of the FeS2 foam. The optimal temperature for the fabrication of the FeSx treated foam was determined to be 500°C. The FeS2 treated foam reduced the interfacial resistance and improved the mechanical strength of the cathode. The discharge capacity of the thermal battery using the FeS2 treated foam was about 1.3 times higher than that of a thermal battery using pure Fe metal foam.In this study, we fabricated a cathode with lower amounts of additive materials and higher amounts of active materials than those of a conventional cathode. A thermal battery was fabricated using FeS2 treated foam as the cathode frame, and its feasibility was verified. X-ray diffraction, transmission electron microscopy, and scanning electron microscopy were used to analyze the effects of thermal sulfidation temperature (400 and 500°C) on the structure and surface morphology of the FeS2 foam. The optimal temperature for the fabrication of the FeSx treated foam was determined to be 500°C. The FeS2 treated foam reduced the interfacial resistance and improved the mechanical strength of the cathode. The discharge capacity of the thermal battery using the FeS2 treated foam was about 1.3 times higher than that of a thermal battery using pure Fe metal foam. In this study, we fabricated a cathode with lower amounts of additive materials and higher amounts of active materials than those of a conventional cathode. A thermal battery was fabricated using FeS2 treated foam as the cathode frame, and its feasibility was verified. X-ray diffraction, transmission electron microscopy, and scanning electron microscopy were used to analyze the effects of thermal sulfidation temperature (400 and 500°C) on the structure and surface morphology of the FeS2 foam. The optimal temperature for the fabrication of the FeSx treated foam was determined to be 500°C. The FeS2 treated foam reduced the interfacial resistance and improved the mechanical strength of the cathode. The discharge capacity of the thermal battery using the FeS2 treated foam was about 1.3 times higher than that of a thermal battery using pure Fe metal foam. In this study, we fabricated a cathode with lower amounts of additive materials and higher amounts of active materials than those of a conventional cathode. A thermal battery was fabricated using FeS 2 treated foam as the cathode frame, and its feasibility was verified. X-ray diffraction, transmission electron microscopy, and scanning electron microscopy were used to analyze the effects of thermal sulfidation temperature (400 and 500°C) on the structure and surface morphology of the FeS 2 foam. The optimal temperature for the fabrication of the FeS x treated foam was determined to be 500°C. The FeS 2 treated foam reduced the interfacial resistance and improved the mechanical strength of the cathode. The discharge capacity of the thermal battery using the FeS 2 treated foam was about 1.3 times higher than that of a thermal battery using pure Fe metal foam. |
Author | Kim, In Yea Woo, Sung Pil Ko, Jaehwan Yoon, Young Soo Kang, Seung-Ho Lim, Jae-Hong Cheong, Hae-Won |
AuthorAffiliation | 1 Department of Materials Science and Engineering, Gachon University , Seongnam , South Korea 2 Department of Materials Science and Engineering, Yonsei University , Seoul , South Korea 3 Agency for Defense Development , Daejeon , South Korea |
AuthorAffiliation_xml | – name: 3 Agency for Defense Development , Daejeon , South Korea – name: 1 Department of Materials Science and Engineering, Gachon University , Seongnam , South Korea – name: 2 Department of Materials Science and Engineering, Yonsei University , Seoul , South Korea |
Author_xml | – sequence: 1 givenname: In Yea surname: Kim fullname: Kim, In Yea – sequence: 2 givenname: Sung Pil surname: Woo fullname: Woo, Sung Pil – sequence: 3 givenname: Jaehwan surname: Ko fullname: Ko, Jaehwan – sequence: 4 givenname: Seung-Ho surname: Kang fullname: Kang, Seung-Ho – sequence: 5 givenname: Young Soo surname: Yoon fullname: Yoon, Young Soo – sequence: 6 givenname: Hae-Won surname: Cheong fullname: Cheong, Hae-Won – sequence: 7 givenname: Jae-Hong surname: Lim fullname: Lim, Jae-Hong |
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Copyright | Copyright © 2020 Kim, Woo, Ko, Kang, Yoon, Cheong and Lim. Copyright © 2020 Kim, Woo, Ko, Kang, Yoon, Cheong and Lim. 2020 Kim, Woo, Ko, Kang, Yoon, Cheong and Lim |
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Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 Edited by: Nosang Vincent Myung, University of California, Riverside, United States Reviewed by: Pankaj Madhukar Koinkar, Tokushima University, Japan; Xianhong Rui, Guangdong University of Technology, China This article was submitted to Electrochemistry, a section of the journal Frontiers in Chemistry |
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Title | Binder-Free Cathode for Thermal Batteries Fabricated Using FeS2 Treated Metal Foam |
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