Research on preparation optimization of nano CeB6 powder and its high temperature stability
High temperature self-propagating synthesis (SHS) process is very rapid, the reaction process becomes un-controlled after the SHS reaction is ignited. So the initial reaction conditions will have great effects on phase compositions and microstructures of reaction products. In this paper, the effects...
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Published in | Journal of rare earths Vol. 30; no. 11; pp. 1129 - 1133 |
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Format | Journal Article |
Language | English |
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Elsevier B.V
01.11.2012
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ISSN | 1002-0721 2509-4963 |
DOI | 10.1016/S1002-0721(12)60192-6 |
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Abstract | High temperature self-propagating synthesis (SHS) process is very rapid, the reaction process becomes un-controlled after the SHS reaction is ignited. So the initial reaction conditions will have great effects on phase compositions and microstructures of reaction products. In this paper, the effects of the proportioning amount of Mg on the yield ratio and particle sizes of CeB6 were studied. The SHS reaction products and leached products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the SHS products consisted of MgO, CeB6 and little Mg3B206. The single CeB6 phase was contained after the SHS reaction products were leached. The purity of CeB6 was higher than 99.0 mass%, and the minimum particle sizes of CeB6 were within 30-70 nm. When the propor- tioning amount of Mg was 25% more than the theoretic amount, the yield of CeB6 was 68.68%. The antioxidant ability of CeB6 was rather stronger, which was oxidized step by step, and the initial oxidation temperature was 750 ℃ which indicated that it had good high temperature stability. The apparent activation energies of oxidation reactions of CeB6 were 200.09 and 312.10 kJ/mol, respectively, and reaction orders were 0.69 and 0.40, respectively. |
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AbstractList | High temperature self-propagating synthesis (SHS) process is very rapid, the reaction process becomes un-controlled after the SHS reaction is ignited. So the initial reaction conditions will have great effects on phase compositions and microstructures of reaction products. In this paper, the effects of the proportioning amount of Mg on the yield ratio and particle sizes of CeB6 were studied. The SHS reaction products and leached products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the SHS products consisted of MgO, CeB6 and little Mg3B206. The single CeB6 phase was contained after the SHS reaction products were leached. The purity of CeB6 was higher than 99.0 mass%, and the minimum particle sizes of CeB6 were within 30-70 nm. When the propor- tioning amount of Mg was 25% more than the theoretic amount, the yield of CeB6 was 68.68%. The antioxidant ability of CeB6 was rather stronger, which was oxidized step by step, and the initial oxidation temperature was 750 ℃ which indicated that it had good high temperature stability. The apparent activation energies of oxidation reactions of CeB6 were 200.09 and 312.10 kJ/mol, respectively, and reaction orders were 0.69 and 0.40, respectively. High temperature self-propagating synthesis (SHS) process is very rapid, the reaction process becomes un-controlled after the SHS reaction is ignited. So the initial reaction conditions will have great effects on phase compositions and microstructures of reaction products. In this paper, the effects of the proportioning amount of Mg on the yield ratio and particle sizes of CeB6 were studied. The SHS reaction products and leached products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the SHS products consisted of MgO, CeB6 and little Mg3B2O6. The single CeB6 phase was contained after the SHS reaction products were leached. The purity of CeB6 was higher than 99.0 mass%, and the minimum particle sizes of CeB6 were within 30–70 nm. When the proportioning amount of Mg was 25% more than the theoretic amount, the yield of CeB6 was 68.68%. The antioxidant ability of CeB6 was rather stronger, which was oxidized step by step, and the initial oxidation temperature was 750 °C, which indicated that it had good high temperature stability. The apparent activation energies of oxidation reactions of CeB6 were 200.09 and 312.10 kJ/mol, respectively, and reaction orders were 0.69 and 0.40, respectively. High temperature self-propagating synthesis (SHS) process is very rapid, the reaction process becomes un-controlled after the SHS reaction is ignited. So the initial reaction conditions will have great effects on phase compositions and microstructures of reaction products. In this paper, the effects of the proportioning amount of Mg on the yield ratio and particle sizes of CeB6 were studied. The SHS reaction products and leached products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the SHS products consisted of MgO, CeB6 and little Mg3B2O6. The single CeB6 phase was contained after the SHS reaction products were leached. The purity of CeB6 was higher than 99.0 mass%, and the minimum particle sizes of CeB6 were within 30a70 nm. When the proportioning amount of Mg was 25% more than the theoretic amount, the yield of CeB6 was 68.68%. The antioxidant ability of CeB6 was rather stronger, which was oxidized step by step, and the initial oxidation temperature was 750 degree C, which indicated that it had good high temperature stability. The apparent activation energies of oxidation reactions of CeB6 were 200.09 and 312.10 kJ/mol, respectively, and reaction orders were 0.69 and 0.40, respectively. |
Author | 豆志河 张廷安 郭永楠 赫冀成 |
AuthorAffiliation | Key Laboratory for Ecological Utilization of Multimetallic Mineral (Ministry of Education), Northeastern Universiiy, Shenyang 110004, China |
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CitedBy_id | crossref_primary_10_1016_j_ceramint_2019_06_199 crossref_primary_10_1007_s41779_017_0168_x crossref_primary_10_14356_kona_2016001 crossref_primary_10_1016_j_jre_2021_11_012 crossref_primary_10_1002_jccs_201500479 crossref_primary_10_1007_s41779_021_00659_1 crossref_primary_10_1016_j_matchemphys_2019_122253 crossref_primary_10_1016_j_jre_2022_09_017 |
Cites_doi | 10.1016/j.jallcom.2004.12.161 10.1016/S1002-0721(10)60501-7 10.1016/S0022-0248(03)01296-X 10.3724/SP.J.1077.2009.00793 10.1016/j.jssc.2007.12.011 10.1016/S1002-0721(10)60583-2 10.1016/0925-8388(94)05051-1 10.1016/j.jcrysgro.2006.02.042 10.1016/j.jssc.2003.02.005 |
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Notes | 11-2788/TF High temperature self-propagating synthesis (SHS) process is very rapid, the reaction process becomes un-controlled after the SHS reaction is ignited. So the initial reaction conditions will have great effects on phase compositions and microstructures of reaction products. In this paper, the effects of the proportioning amount of Mg on the yield ratio and particle sizes of CeB6 were studied. The SHS reaction products and leached products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the SHS products consisted of MgO, CeB6 and little Mg3B206. The single CeB6 phase was contained after the SHS reaction products were leached. The purity of CeB6 was higher than 99.0 mass%, and the minimum particle sizes of CeB6 were within 30-70 nm. When the propor- tioning amount of Mg was 25% more than the theoretic amount, the yield of CeB6 was 68.68%. The antioxidant ability of CeB6 was rather stronger, which was oxidized step by step, and the initial oxidation temperature was 750 ℃ which indicated that it had good high temperature stability. The apparent activation energies of oxidation reactions of CeB6 were 200.09 and 312.10 kJ/mol, respectively, and reaction orders were 0.69 and 0.40, respectively. DOU Zhihe , ZHANG Tingan , GUO Yongnan, HE Jicheng (1. Key Laboratory for Ecological Utilization of Multimetallic Mineral (Ministry of Education), Northeastern University, Shenyang 110004, China) SHS; CeB6; nano-powders; high temperature stability; rare earths ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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Snippet | High temperature self-propagating synthesis (SHS) process is very rapid, the reaction process becomes un-controlled after the SHS reaction is ignited. So the... High temperature self-propagating synthesis (SHS) process is very rapid, the reaction process becomes un-controlled after the SHS reaction is ignited. So the... |
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SubjectTerms | CeB6 high temperature stability Magnesium nano-powders Nanostructure Oxidation Particle size Rare earth metals rare earths Reaction products Scanning electron microscopy Self-propagating synthesis SHS SHS反应 X-射线衍射 优化 扫描电子显微镜 抗氧化能力 纳米 自蔓延高温合成 高温稳定性 |
Title | Research on preparation optimization of nano CeB6 powder and its high temperature stability |
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