Organometallic-polyoxometalate hybrid based on V-Schiff base and phosphovanadomolybdate as a highly effective heterogenous catalyst for hydroxylation of benzene
A new organometallic-polyoxometalate hybrid is synthesized and proved to be a highly efficient and steadily reused heterogeneous catalyst for hydroxylation of benzene with H2O2. [Display omitted] •A novel organometallic-polyoxometalate hybrid is prepared.•The hybrid catalyst leads to the heterogeneo...
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| Published in | Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 239; pp. 1 - 7 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.03.2014
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1385-8947 1873-3212 |
| DOI | 10.1016/j.cej.2013.10.092 |
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| Abstract | A new organometallic-polyoxometalate hybrid is synthesized and proved to be a highly efficient and steadily reused heterogeneous catalyst for hydroxylation of benzene with H2O2. [Display omitted]
•A novel organometallic-polyoxometalate hybrid is prepared.•The hybrid catalyst leads to the heterogeneous hydroxylation of benzene with H2O2.•The hybrid catalyst gives high conversion and selectivity.•The catalyst can be easily recovered and reused.
A novel organometallic-polyoxometalate hybrid has been prepared by anion-exchange of V Schiff base functionalized ionic liquid with V-containing Keggin-type polyoxometalate. The hybrid solid with two types of catalytic active V components demonstrates remarkable capability for heterogeneous hydroxylation of benzene with excellent phenol yield 19.6% and 100% selectivity. After reaction, the catalyst can be simply recovered by filtration and reused at least 4times without the change of catalyst structure. The synergistic effect between metal Schiff base complex and polyoxometalate plays an important role in the promotion of catalytic activity. |
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| AbstractList | A new organometallic-polyoxometalate hybrid is synthesized and proved to be a highly efficient and steadily reused heterogeneous catalyst for hydroxylation of benzene with H2O2. [Display omitted]
•A novel organometallic-polyoxometalate hybrid is prepared.•The hybrid catalyst leads to the heterogeneous hydroxylation of benzene with H2O2.•The hybrid catalyst gives high conversion and selectivity.•The catalyst can be easily recovered and reused.
A novel organometallic-polyoxometalate hybrid has been prepared by anion-exchange of V Schiff base functionalized ionic liquid with V-containing Keggin-type polyoxometalate. The hybrid solid with two types of catalytic active V components demonstrates remarkable capability for heterogeneous hydroxylation of benzene with excellent phenol yield 19.6% and 100% selectivity. After reaction, the catalyst can be simply recovered by filtration and reused at least 4times without the change of catalyst structure. The synergistic effect between metal Schiff base complex and polyoxometalate plays an important role in the promotion of catalytic activity. A novel organometallic-polyoxometalate hybrid has been prepared by anion-exchange of V Schiff base functionalized ionic liquid with V-containing Keggin-type polyoxometalate. The hybrid solid with two types of catalytic active V components demonstrates remarkable capability for heterogeneous hydroxylation of benzene with excellent phenol yield 19.6% and 100% selectivity. After reaction, the catalyst can be simply recovered by filtration and reused at least 4 times without the change of catalyst structure. The synergistic effect between metal Schiff base complex and polyoxometalate plays an important role in the promotion of catalytic activity. |
| Author | Liu, Jian Jiang, Pingping Leng, Yan Wang, Jun |
| Author_xml | – sequence: 1 givenname: Yan surname: Leng fullname: Leng, Yan email: lengyan1114@126.com organization: The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China – sequence: 2 givenname: Jian surname: Liu fullname: Liu, Jian organization: The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China – sequence: 3 givenname: Pingping surname: Jiang fullname: Jiang, Pingping organization: The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China – sequence: 4 givenname: Jun surname: Wang fullname: Wang, Jun organization: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China |
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| Snippet | A new organometallic-polyoxometalate hybrid is synthesized and proved to be a highly efficient and steadily reused heterogeneous catalyst for hydroxylation of... A novel organometallic-polyoxometalate hybrid has been prepared by anion-exchange of V Schiff base functionalized ionic liquid with V-containing Keggin-type... |
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| SubjectTerms | Benzene Catalysts Chemical engineering Filtration Hydroxylation Ionic liquids Phenol Polyoxometalate Promotion Schiff base Schiff bases Synergistic effect |
| Title | Organometallic-polyoxometalate hybrid based on V-Schiff base and phosphovanadomolybdate as a highly effective heterogenous catalyst for hydroxylation of benzene |
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