Study on the efficacy of amorphous calcium carbonate as a consolidant for calcareous matrix

The popular involvement of amorphous calcium carbonate (ACC) in organisms, usually via a complicated non-classical crystallization pathway, has aroused interest in the scientific community. In recent years, a lot of work has been carried out for the preparation and application of ACC. In this paper,...

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Published inHeritage science Vol. 10; no. 1; pp. 1 - 14
Main Authors Wang, Wenwen, Wang, Shuzhe, Liu, Qiang, Wang, Xiaofei, Zhu, Jianfeng, Luo, Hongjie, Ji, Shidong
Format Journal Article
LanguageEnglish
Published Cham Springer International Publishing 20.10.2022
Springer Nature B.V
SpringerOpen
Subjects
Amorphous calcium carbonate
Amorphous to crystal transformation
Calcareous matrix
Calcite
Calcium carbonate
Calcium oxide
Carbonation
Chemistry and Materials Science
Chromaticity
Compressive strength
Crystallization
Efficacy of consolidation
Ethanol
Freezing
Lime
Materials Science
Nucleation
Permeability
Spot welding
Water absorption
Water vapor
Efficacy of consolidation
Calcareous matrix
Amorphous to crystal transformation
Amorphous calcium carbonate
Online AccessGet full text
ISSN2050-7445
2050-7445
DOI10.1186/s40494-022-00804-4

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Abstract The popular involvement of amorphous calcium carbonate (ACC) in organisms, usually via a complicated non-classical crystallization pathway, has aroused interest in the scientific community. In recent years, a lot of work has been carried out for the preparation and application of ACC. In this paper, the effectiveness of ACC for the consolidation of calcareous matrix was evaluated. ACC was synthesized through direct carbonation of calcium oxide in ethanol and was introduced into simulated samples as consolidant. A comprehensive study for the assessment of protective effect was carried out by testing surface strength, chromaticity, compressive strength, water vapor permeability, water absorption and freezing–thawing resistance. The results showed that the addition of ACC could significantly improve the surface strength, compressive strength and weatherability of treated samples, while it had only a slight influence on color difference and water vapor permeability. It was confirmed that ACC could connect the loose calcite particles by ‘spot welding’ through heterogeneous nucleation and growth processes. As a consolidant, it demonstrated its merits in this study and could be proposed as an alternative for the protection of weathered calcareous stones.
AbstractList The popular involvement of amorphous calcium carbonate (ACC) in organisms, usually via a complicated non-classical crystallization pathway, has aroused interest in the scientific community. In recent years, a lot of work has been carried out for the preparation and application of ACC. In this paper, the effectiveness of ACC for the consolidation of calcareous matrix was evaluated. ACC was synthesized through direct carbonation of calcium oxide in ethanol and was introduced into simulated samples as consolidant. A comprehensive study for the assessment of protective effect was carried out by testing surface strength, chromaticity, compressive strength, water vapor permeability, water absorption and freezing–thawing resistance. The results showed that the addition of ACC could significantly improve the surface strength, compressive strength and weatherability of treated samples, while it had only a slight influence on color difference and water vapor permeability. It was confirmed that ACC could connect the loose calcite particles by ‘spot welding’ through heterogeneous nucleation and growth processes. As a consolidant, it demonstrated its merits in this study and could be proposed as an alternative for the protection of weathered calcareous stones.
Abstract The popular involvement of amorphous calcium carbonate (ACC) in organisms, usually via a complicated non-classical crystallization pathway, has aroused interest in the scientific community. In recent years, a lot of work has been carried out for the preparation and application of ACC. In this paper, the effectiveness of ACC for the consolidation of calcareous matrix was evaluated. ACC was synthesized through direct carbonation of calcium oxide in ethanol and was introduced into simulated samples as consolidant. A comprehensive study for the assessment of protective effect was carried out by testing surface strength, chromaticity, compressive strength, water vapor permeability, water absorption and freezing–thawing resistance. The results showed that the addition of ACC could significantly improve the surface strength, compressive strength and weatherability of treated samples, while it had only a slight influence on color difference and water vapor permeability. It was confirmed that ACC could connect the loose calcite particles by ‘spot welding’ through heterogeneous nucleation and growth processes. As a consolidant, it demonstrated its merits in this study and could be proposed as an alternative for the protection of weathered calcareous stones.
ArticleNumber 165
Author Luo, Hongjie
Wang, Shuzhe
Ji, Shidong
Wang, Wenwen
Zhu, Jianfeng
Wang, Xiaofei
Liu, Qiang
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  surname: Ji
  fullname: Ji, Shidong
  email: sdki@shu.edu.cn
  organization: Institute for the Conservation of Cultural Heritage, Shanghai University
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Calcareous matrix
Amorphous to crystal transformation
Amorphous calcium carbonate
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Snippet The popular involvement of amorphous calcium carbonate (ACC) in organisms, usually via a complicated non-classical crystallization pathway, has aroused...
Abstract The popular involvement of amorphous calcium carbonate (ACC) in organisms, usually via a complicated non-classical crystallization pathway, has...
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SubjectTerms Amorphous calcium carbonate
Amorphous to crystal transformation
Calcareous matrix
Calcite
Calcium carbonate
Calcium oxide
Carbonation
Chemistry and Materials Science
Chromaticity
Compressive strength
Crystallization
Efficacy of consolidation
Ethanol
Freezing
Lime
Materials Science
Nucleation
Permeability
Spot welding
Water absorption
Water vapor
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Title Study on the efficacy of amorphous calcium carbonate as a consolidant for calcareous matrix
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