Research progress of vanadium redox flow battery for energy storage in China
Principle and characteristics of vanadium redox flow battery (VRB), a novel energy storage system, was introduced. A research and development united laboratory of VRB was founded in Central South University in 2002 with the financial support of Panzhihua Steel Corporation. The laboratory focused the...
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| Published in | Renewable energy Vol. 33; no. 2; pp. 186 - 192 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article Conference Proceeding |
| Language | English |
| Published |
Oxford
Elsevier Ltd
01.02.2008
Elsevier Science |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0960-1481 1879-0682 |
| DOI | 10.1016/j.renene.2007.05.025 |
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| Abstract | Principle and characteristics of vanadium redox flow battery (VRB), a novel energy storage system, was introduced. A research and development united laboratory of VRB was founded in Central South University in 2002 with the financial support of Panzhihua Steel Corporation. The laboratory focused their research mainly on the selection and preparation of electrode materials, membrane material and modification, stable concentrated electrolyte producing approach, test cell configuration design and optimization. Some relevant foundation problems, such as state of vanadium in sulfurous acid with various additives, the difference of electrochemical reaction rate in anode and in cathode, the crossover of vanadium ions and so on, have been emphasized. The details of these studies have been given and discussed. A 5
kW VRB stack was fabricated in the laboratory and its performances, especially electrochemical performance such as voltage efficiencies, energy efficiencies, and durability, were fully tested. The results will be shown in the talk.
The key technologies of developing VRB, such as to improve the activity of its electrode materials, the stability of electrolyte and selectivity of separator, were also discussed. In addition, the research progresses in other laboratories in China were briefly introduced. |
|---|---|
| AbstractList | Research progress of vanadium redox flow battery (VRB) for energy storage in China was examined. In recent years, the volume of oil import and coal production increased rapidly by year with the economic growth, but a great deal of fossil energy consumption caused serious environmental pollution. The VRB with the low-cost poly (vinylidene fluoride)-graft-poly(styrene sulfuric acid) (PVDF-g-PSSA) membrane exhibited a higher performance than that with Nafion 117 under the same operating conditions, and its energy efficiency reached 75.8% at 30 mA cm super(-2). Open circuit voltage measurement with time of the proton-conducting composite membrane showed promising results compared with that of the untreated Daramic membrane when used in the VRB. It was found that crystalloid would appear in concentrated negative electrolyte stored under normal temperature, especially at a lower temperature. Principle and characteristics of vanadium redox flow battery (VRB), a novel energy storage system, was introduced. A research and development united laboratory of VRB was founded in Central South University in 2002 with the financial support of Panzhihua Steel Corporation. The laboratory focused their research mainly on the selection and preparation of electrode materials, membrane material and modification, stable concentrated electrolyte producing approach, test cell configuration design and optimization. Some relevant foundation problems, such as state of vanadium in sulfurous acid with various additives, the difference of electrochemical reaction rate in anode and in cathode, the crossover of vanadium ions and so on, have been emphasized. The details of these studies have been given and discussed. A 5 kW VRB stack was fabricated in the laboratory and its performances, especially electrochemical performance such as voltage efficiencies, energy efficiencies, and durability, were fully tested. The results will be shown in the talk. The key technologies of developing VRB, such as to improve the activity of its electrode materials, the stability of electrolyte and selectivity of separator, were also discussed. In addition, the research progresses in other laboratories in China were briefly introduced. Principles and characteristics of vanadium redox flow battery (VRB), a novel energy storage system, were introduced. Compared with other redox batteries namely zinc bromine battery, sodium sulfur battery and lead acid battery, the VRB performed higher energy efficiency, longer operation life as well as lower cost, which made it the most practical candidate for energy storage purposes. The VRB system showed prospect in peak shaving, uninterruptible power supply, voltage and frequency control, stabilization of wind turbine output, hybrid with photovoltaic cells and some other energy backup systems. The VRB system was the only redox flow battery using ions of the same metal in both the half-cells, which eliminated electrolyte cross-contamination as experienced by the Fe/Cr redox battery. Principle and characteristics of vanadium redox flow battery (VRB), a novel energy storage system, was introduced. A research and development united laboratory of VRB was founded in Central South University in 2002 with the financial support of Panzhihua Steel Corporation. The laboratory focused their research mainly on the selection and preparation of electrode materials, membrane material and modification, stable concentrated electrolyte producing approach, test cell configuration design and optimization. Some relevant foundation problems, such as state of vanadium in sulfurous acid with various additives, the difference of electrochemical reaction rate in anode and in cathode, the crossover of vanadium ions and so on, have been emphasized. The details of these studies have been given and discussed. A 5 kW VRB stack was fabricated in the laboratory and its performances, especially electrochemical performance such as voltage efficiencies, energy efficiencies, and durability, were fully tested. The results will be shown in the talk. The key technologies of developing VRB, such as to improve the activity of its electrode materials, the stability of electrolyte and selectivity of separator, were also discussed. In addition, the research progresses in other laboratories in China were briefly introduced. |
| Author | Liu, Su-qin Tan, Ning Li, Xiao-gang Huang, Ke-Long Chen, Li-quan |
| Author_xml | – sequence: 1 givenname: Ke-Long surname: Huang fullname: Huang, Ke-Long email: klhuang@mail.csu.edu.cn organization: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China – sequence: 2 givenname: Xiao-gang surname: Li fullname: Li, Xiao-gang organization: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China – sequence: 3 givenname: Su-qin surname: Liu fullname: Liu, Su-qin organization: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China – sequence: 4 givenname: Ning surname: Tan fullname: Tan, Ning organization: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China – sequence: 5 givenname: Li-quan surname: Chen fullname: Chen, Li-quan organization: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China |
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| Keywords | Energy storage system Vanadium redox flow battery Vanadium Electrolyte Renewable energy Battery Battery separators Electrode material Electric batteries Performance Research and development Energy storage |
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| Snippet | Principle and characteristics of vanadium redox flow battery (VRB), a novel energy storage system, was introduced. A research and development united laboratory... Principles and characteristics of vanadium redox flow battery (VRB), a novel energy storage system, were introduced. Compared with other redox batteries namely... Research progress of vanadium redox flow battery (VRB) for energy storage in China was examined. In recent years, the volume of oil import and coal production... |
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| SubjectTerms | Applied sciences Energy Energy storage system Energy. Thermal use of fuels Exact sciences and technology Natural energy Transport and storage of energy Vanadium Vanadium redox flow battery |
| Title | Research progress of vanadium redox flow battery for energy storage in China |
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