Degradation of Chloramphenicol with Novel Metal Foam Electrodes in Bioelectrochemical Systems

• Published in: Electrochimica acta Vol. 240; pp. 136 - 145
• Main Authors: Wu, Dan, Sun, Faqian, Zhou, Yan
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 20.06.2017; Elsevier BV
• Subjects: Amines; Antibiotics; Bioelectrochemical systems; Carbon dioxide; Cathodes; Chloramphenicol; Chloromycetin; Copper; Degradation; Degradation mechanism; Electric potential; Electrodes; Metal foam electrodes; Metal foams; Pollutants; Water treatment; Chloramphenicol; Degradation mechanism; Bioelectrochemical systems; Metal foam electrodes
• ISSN: 0013-4686; 1873-3859; 1873-3859
• DOI: 10.1016/j.electacta.2017.04.059

[Display omitted] •Copper foam and nickel foam were evaluated as cathodes for CAP degradation.•Higher applied voltage contributed to faster degradation of CAP.•Copper foam can replace carbon based materials for recalcitrant organics degradation.•Oxygen in the catholyte benefited the complete degradation of CAP Bioelectrochemical system (BES) has been considered as one of the efficient methods for recalcitrant organic pollutant removal. This study compared three different cathodes, i.e. carbon rod (CR), copper foam (Cu), nickel foam (NF), for chloramphenicol (CAP) removal in BESs, while Cu and NF have not been used as cathodes for CAP degradation before. The results demonstrated that with 0.3V applied voltage, 100% removal of 32mgL−1 CAP was observed after 36h and 24h with CR and Cu electrodes respectively, while amines were the main intermediate products. The performance of Cu cathode was 15.13 times better than NF electrode under 0.3V applied voltage. When the applied voltage increased to 0.5V, CAP could be completely removed within 12h with Cu electrode, while complete CAP removal was found after 24hours for CR and more than 120hours for NF respectively. With 0.5V applied voltage in 24h degradation period, the final degradation products were found to be CO2 and H2O for Cu electrode, while nitrobenzene and 4-Nitrobenzyl alcohol were the main products for CR and NF electrodes respectively. The results demonstrated that Cu was the most efficient cathode for CAP degradation.