Optimization of decoloring conditions of crude fatty acids recovered from crude glycerol by acid-activated clay using response surface method

Crude glycerol, a by-product of the biodiesel production process, contains a high amount of fatty acids that cannot be used directly without removing the strong dark color. This study aims to remove the color impurities in crude fatty acids, prepared by acid-precipitation and hexane extraction, usin...

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Published inThe Korean journal of chemical engineering Vol. 31; no. 11; pp. 2070 - 2076
Main Authors Su, Hong, Wang, Xue, Kim, You Geun, Kim, Sung Bae, Seo, Yang-Gon, Kim, Jin Seog, Kim, Chang-Joon
Format Journal Article
LanguageEnglish
Published Boston Springer US 01.11.2014
한국화학공학회
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ISSN0256-1115
1975-7220
DOI10.1007/s11814-014-0158-4

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Abstract Crude glycerol, a by-product of the biodiesel production process, contains a high amount of fatty acids that cannot be used directly without removing the strong dark color. This study aims to remove the color impurities in crude fatty acids, prepared by acid-precipitation and hexane extraction, using acid-activated clay as an adsorbent. The effects of bleaching temperature, contact time, the amount of acid-activated clay, and concentration of color impurities were investigated. No significant effects of bleaching temperature or contact time were observed. In an optimization study using the central composite design, complete decolorization was achieved at an optimized condition, in which 3.5 g of clay was added to 10mL of crude fatty acid solution with an optical density at 373 nm of 20. Notably, more than 80% of the peroxides was concurrently removed. However, a 37% loss in fatty acids was observed during decolorization. The clay was repeatedly used without loss of adsorption capability if it was calcined at 600 °C after use.
AbstractList Crude glycerol, a by-product of the biodiesel production process, contains a high amount of fatty acids that cannot be used directly without removing the strong dark color. This study aims to remove the color impurities in crude fatty acids, prepared by acid-precipitation and hexane extraction, using acid-activated clay as an adsorbent. The effects of bleaching temperature, contact time, the amount of acid-activated clay, and concentration of color impurities were investigated. No significant effects of bleaching temperature or contact time were observed. In an optimization study using the central composite design, complete decolorization was achieved at an optimized condition, in which 3.5 g of clay was added to 10mL of crude fatty acid solution with an optical density at 373 nm of 20. Notably, more than 80% of the peroxides was concurrently removed. However, a 37% loss in fatty acids was observed during decolorization. The clay was repeatedly used without loss of adsorption capability if it was calcined at 600 °C after use.
Crude glycerol, a by-product of the biodiesel production process, contains a high amount of fatty acidsthat cannot be used directly without removing the strong dark color. This study aims to remove the color impuritiesin crude fatty acids, prepared by acid-precipitation and hexane extraction, using acid-activated clay as an adsorbent. The effects of bleaching temperature, contact time, the amount of acid-activated clay, and concentration of color im-purities were investigated. No significant effects of bleaching temperature or contact time were observed. In an opti-mization study using the central composite design, complete decolorization was achieved at an optimized condition,in which 3.5 g of clay was added to 10 mL of crude fatty acid solution with an optical density at 373 nm of20. Notably,more than 80% of the peroxides was concurrently removed. However, a 37% loss in fatty acids was observed duringdecolorization. The clay was repeatedly used without loss of adsorption capability if it was calcined at 600 oC after use. KCI Citation Count: 6
Author Wang, Xue
Kim, Chang-Joon
Su, Hong
Kim, Sung Bae
Seo, Yang-Gon
Kim, You Geun
Kim, Jin Seog
Author_xml – sequence: 1
  givenname: Hong
  surname: Su
  fullname: Su, Hong
  organization: Department of Chemical and Biological Engineering & ERI, Gyeongsang National University
– sequence: 2
  givenname: Xue
  surname: Wang
  fullname: Wang, Xue
  organization: Department of Chemical and Biological Engineering & ERI, Gyeongsang National University
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  givenname: You Geun
  surname: Kim
  fullname: Kim, You Geun
  organization: KB Cosmetics
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  givenname: Sung Bae
  surname: Kim
  fullname: Kim, Sung Bae
  organization: Department of Chemical and Biological Engineering & ERI, Gyeongsang National University
– sequence: 5
  givenname: Yang-Gon
  surname: Seo
  fullname: Seo, Yang-Gon
  organization: Department of Chemical and Biological Engineering & ERI, Gyeongsang National University
– sequence: 6
  givenname: Jin Seog
  surname: Kim
  fullname: Kim, Jin Seog
  organization: Department of Applied Statistics and Information Science, Dongguk University
– sequence: 7
  givenname: Chang-Joon
  surname: Kim
  fullname: Kim, Chang-Joon
  email: cj_kim@gnu.ac.kr
  organization: Department of Chemical and Biological Engineering & ERI, Gyeongsang National University
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Issue 11
Keywords Decolorization
Fatty Acid
Biodiesel
Crude Glycerol
Response Surface Design
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한국화학공학회
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Snippet Crude glycerol, a by-product of the biodiesel production process, contains a high amount of fatty acids that cannot be used directly without removing the...
Crude glycerol, a by-product of the biodiesel production process, contains a high amount of fatty acidsthat cannot be used directly without removing the strong...
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SubjectTerms Biotechnology
Catalysis
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Materials Science
Separation Technology
Thermodynamics
화학공학
Title Optimization of decoloring conditions of crude fatty acids recovered from crude glycerol by acid-activated clay using response surface method
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