In situ etching-induced self-assembly of metal cluster decorated one-dimensional semiconductors for solar-powered water splitting: unraveling cooperative synergy by photoelectrochemical investigations
Although recent years have witnessed considerable progress in the synthesis of metal clusters, there is still a paucity of reports on photoelectrochemical (PEC) properties of metal cluster/semiconductor systems for solar energy conversion. In this work, highly ordered glutathione (GSH)-protected gol...
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| Published in | Nanoscale Vol. 9; no. 43; pp. 17118 - 17132 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
01.01.2017
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 2040-3364 2040-3372 2040-3372 |
| DOI | 10.1039/C7NR06697J |
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| Abstract | Although recent years have witnessed considerable progress in the synthesis of metal clusters, there is still a paucity of reports on photoelectrochemical (PEC) properties of metal cluster/semiconductor systems for solar energy conversion. In this work, highly ordered glutathione (GSH)-protected gold (Au) cluster (Au
x
@GSH) enwrapped ZnO nanowire array (NW) heterostructures (Au
x
/ZnO NWs) were designed by a facile, green, simple yet efficient
in situ
etching-induced electrostatic self-assembly strategy by modulating the intrinsic surface charge properties of building blocks, which renders negatively charged Au
x
clusters spontaneously and uniformly self-assembles them on positively charged ZnO NWs framework with intimate interfacial integration. It was unraveled that such Au
x
/ZnO NWs heterostructures demonstrated significantly enhanced PEC water splitting performance in comparison with single ZnO NWs, Au nanoparticles (Au/ZnO NWs) and GSH-capped Ag
x
clusters (Ag
x
/ZnO NWs) decorated ZnO NWs counterparts under both simulated solar and visible light irradiation. The vitally important role of Au
x
clusters as photosensitizer was unambiguously revealed and the merits of Au
x
clusters in boosting charge transfer arising from their unique core–shell architecture were highlighted by systematic comparison under identical conditions, based on which Au
x
cluster-mediated PEC water splitting mechanism is delineated. It is anticipated that our work can highlight the possibility of harnessing metal clusters as efficient light-harvest antennas and open new avenues for rational construction of various highly energy efficient metal cluster/semiconductor heterostructures for widespread photocatalytic and PEC applications. |
|---|---|
| AbstractList | Although recent years have witnessed considerable progress in the synthesis of metal clusters, there is still a paucity of reports on photoelectrochemical (PEC) properties of metal cluster/semiconductor systems for solar energy conversion. In this work, highly ordered glutathione (GSH)-protected gold (Au) cluster (Aux@GSH) enwrapped ZnO nanowire array (NW) heterostructures (Aux/ZnO NWs) were designed by a facile, green, simple yet efficient in situ etching-induced electrostatic self-assembly strategy by modulating the intrinsic surface charge properties of building blocks, which renders negatively charged Aux clusters spontaneously and uniformly self-assembles them on positively charged ZnO NWs framework with intimate interfacial integration. It was unraveled that such Aux/ZnO NWs heterostructures demonstrated significantly enhanced PEC water splitting performance in comparison with single ZnO NWs, Au nanoparticles (Au/ZnO NWs) and GSH-capped Agx clusters (Agx/ZnO NWs) decorated ZnO NWs counterparts under both simulated solar and visible light irradiation. The vitally important role of Aux clusters as photosensitizer was unambiguously revealed and the merits of Aux clusters in boosting charge transfer arising from their unique core–shell architecture were highlighted by systematic comparison under identical conditions, based on which Aux cluster-mediated PEC water splitting mechanism is delineated. It is anticipated that our work can highlight the possibility of harnessing metal clusters as efficient light-harvest antennas and open new avenues for rational construction of various highly energy efficient metal cluster/semiconductor heterostructures for widespread photocatalytic and PEC applications. Although recent years have witnessed considerable progress in the synthesis of metal clusters, there is still a paucity of reports on photoelectrochemical (PEC) properties of metal cluster/semiconductor systems for solar energy conversion. In this work, highly ordered glutathione (GSH)-protected gold (Au) cluster (Au @GSH) enwrapped ZnO nanowire array (NW) heterostructures (Au /ZnO NWs) were designed by a facile, green, simple yet efficient in situ etching-induced electrostatic self-assembly strategy by modulating the intrinsic surface charge properties of building blocks, which renders negatively charged Au clusters spontaneously and uniformly self-assembles them on positively charged ZnO NWs framework with intimate interfacial integration. It was unraveled that such Au /ZnO NWs heterostructures demonstrated significantly enhanced PEC water splitting performance in comparison with single ZnO NWs, Au nanoparticles (Au/ZnO NWs) and GSH-capped Ag clusters (Ag /ZnO NWs) decorated ZnO NWs counterparts under both simulated solar and visible light irradiation. The vitally important role of Au clusters as photosensitizer was unambiguously revealed and the merits of Au clusters in boosting charge transfer arising from their unique core-shell architecture were highlighted by systematic comparison under identical conditions, based on which Au cluster-mediated PEC water splitting mechanism is delineated. It is anticipated that our work can highlight the possibility of harnessing metal clusters as efficient light-harvest antennas and open new avenues for rational construction of various highly energy efficient metal cluster/semiconductor heterostructures for widespread photocatalytic and PEC applications. Although recent years have witnessed considerable progress in the synthesis of metal clusters, there is still a paucity of reports on photoelectrochemical (PEC) properties of metal cluster/semiconductor systems for solar energy conversion. In this work, highly ordered glutathione (GSH)-protected gold (Au) cluster (Aux@GSH) enwrapped ZnO nanowire array (NW) heterostructures (Aux/ZnO NWs) were designed by a facile, green, simple yet efficient in situ etching-induced electrostatic self-assembly strategy by modulating the intrinsic surface charge properties of building blocks, which renders negatively charged Aux clusters spontaneously and uniformly self-assembles them on positively charged ZnO NWs framework with intimate interfacial integration. It was unraveled that such Aux/ZnO NWs heterostructures demonstrated significantly enhanced PEC water splitting performance in comparison with single ZnO NWs, Au nanoparticles (Au/ZnO NWs) and GSH-capped Agx clusters (Agx/ZnO NWs) decorated ZnO NWs counterparts under both simulated solar and visible light irradiation. The vitally important role of Aux clusters as photosensitizer was unambiguously revealed and the merits of Aux clusters in boosting charge transfer arising from their unique core-shell architecture were highlighted by systematic comparison under identical conditions, based on which Aux cluster-mediated PEC water splitting mechanism is delineated. It is anticipated that our work can highlight the possibility of harnessing metal clusters as efficient light-harvest antennas and open new avenues for rational construction of various highly energy efficient metal cluster/semiconductor heterostructures for widespread photocatalytic and PEC applications.Although recent years have witnessed considerable progress in the synthesis of metal clusters, there is still a paucity of reports on photoelectrochemical (PEC) properties of metal cluster/semiconductor systems for solar energy conversion. In this work, highly ordered glutathione (GSH)-protected gold (Au) cluster (Aux@GSH) enwrapped ZnO nanowire array (NW) heterostructures (Aux/ZnO NWs) were designed by a facile, green, simple yet efficient in situ etching-induced electrostatic self-assembly strategy by modulating the intrinsic surface charge properties of building blocks, which renders negatively charged Aux clusters spontaneously and uniformly self-assembles them on positively charged ZnO NWs framework with intimate interfacial integration. It was unraveled that such Aux/ZnO NWs heterostructures demonstrated significantly enhanced PEC water splitting performance in comparison with single ZnO NWs, Au nanoparticles (Au/ZnO NWs) and GSH-capped Agx clusters (Agx/ZnO NWs) decorated ZnO NWs counterparts under both simulated solar and visible light irradiation. The vitally important role of Aux clusters as photosensitizer was unambiguously revealed and the merits of Aux clusters in boosting charge transfer arising from their unique core-shell architecture were highlighted by systematic comparison under identical conditions, based on which Aux cluster-mediated PEC water splitting mechanism is delineated. It is anticipated that our work can highlight the possibility of harnessing metal clusters as efficient light-harvest antennas and open new avenues for rational construction of various highly energy efficient metal cluster/semiconductor heterostructures for widespread photocatalytic and PEC applications. Although recent years have witnessed considerable progress in the synthesis of metal clusters, there is still a paucity of reports on photoelectrochemical (PEC) properties of metal cluster/semiconductor systems for solar energy conversion. In this work, highly ordered glutathione (GSH)-protected gold (Au) cluster (Au x @GSH) enwrapped ZnO nanowire array (NW) heterostructures (Au x /ZnO NWs) were designed by a facile, green, simple yet efficient in situ etching-induced electrostatic self-assembly strategy by modulating the intrinsic surface charge properties of building blocks, which renders negatively charged Au x clusters spontaneously and uniformly self-assembles them on positively charged ZnO NWs framework with intimate interfacial integration. It was unraveled that such Au x /ZnO NWs heterostructures demonstrated significantly enhanced PEC water splitting performance in comparison with single ZnO NWs, Au nanoparticles (Au/ZnO NWs) and GSH-capped Ag x clusters (Ag x /ZnO NWs) decorated ZnO NWs counterparts under both simulated solar and visible light irradiation. The vitally important role of Au x clusters as photosensitizer was unambiguously revealed and the merits of Au x clusters in boosting charge transfer arising from their unique core–shell architecture were highlighted by systematic comparison under identical conditions, based on which Au x cluster-mediated PEC water splitting mechanism is delineated. It is anticipated that our work can highlight the possibility of harnessing metal clusters as efficient light-harvest antennas and open new avenues for rational construction of various highly energy efficient metal cluster/semiconductor heterostructures for widespread photocatalytic and PEC applications. |
| Author | Liu, Bin Xiao, Fang-Xing |
| Author_xml | – sequence: 1 givenname: Fang-Xing orcidid: 0000-0001-5673-5362 surname: Xiao fullname: Xiao, Fang-Xing organization: College of Materials Science and Engineering, Fuzhou University, Fuzhou, China – sequence: 2 givenname: Bin surname: Liu fullname: Liu, Bin organization: School of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore 637459, Singapore |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29087419$$D View this record in MEDLINE/PubMed |
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| Snippet | Although recent years have witnessed considerable progress in the synthesis of metal clusters, there is still a paucity of reports on photoelectrochemical... |
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| SubjectTerms | Charge transfer Etching Glutathione Gold Heterostructures Light irradiation Low dimensional semiconductors Metal clusters Nanoparticles Nanowires Photovoltaic cells Self-assembly Solar energy conversion Surface charge Water splitting Zinc oxide |
| Title | In situ etching-induced self-assembly of metal cluster decorated one-dimensional semiconductors for solar-powered water splitting: unraveling cooperative synergy by photoelectrochemical investigations |
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